(1,1'-Bis(diphenylphosphino)ferrocene)palladium(II) dichloride

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The correct title of this article is [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) dichloride. The substitution or omission of any < > [ ] { } is because of technical restrictions.
(1,1'-Bis(diphenylphosphino)ferrocene)palladium(II) dichloride
Bis(diphenylphosphino)ferrocene palladium(II) dichloride.svg
Identifiers
72287-26-4 YesY
95464-05-4 complex with DCM YesY
ChemSpider 24602493
Properties
C34H28Cl2FeP2Pd
Molar mass 731.70 g·mol−1
Except where noted otherwise, data is given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
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Infobox references

[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) dichloride is an palladium complex containing the iron-containing dppf ligand. Commercially available, this compound is popularly used for palladium-catalyzed coupling reactions.

Commercially available, this compound may be prepared from dppf and nitrile complexes of palladium dichloride:[1]

dppf + PdCl2(RCN)2 → (dppf)PdCl2 + 2 RCN (RCN = acetonitrile or benzonitrile)

References[edit]

  1. ^ Nataro, Chip; Fosbenner, Stephanie M. (2009). "Synthesis and Characterization of Transition-Metal Complexes Containing 1,1’-Bis(diphenylphosphino)ferrocene". J. Chem. Ed. 86: 1412. doi:10.1021/ed086p1412.