(2,4,6-Trimethylphenyl)gold

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(2,4,6-Trimethylphenyl)gold
Stereo, Kekulé skeletal formula of (2,4,6-trimethylphenyl)gold
Identifiers
CAS number 89359-21-7 monomer N, 89340-02-3 pentamer
PubChem 19877937
ChemSpider 14451398 YesY
Jmol-3D images Image 1
Image 2
Properties
Molecular formula Au
5
C
45
H
55
Molar mass 316.15 g mol−1
Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
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Infobox references

(2,4,6-Trimethylphenyl)gold is a member of a special group of compounds where an aryl carbon atom acts as a bridge between two gold atoms. This compound is formed in a reaction between Au(CO)Cl and mesityl Grignard.[1] It crystallizes as a cyclical pentamer.[1]

References[edit]

  1. ^ a b Gambarotta, Sandro; Floriani, Carlo; Chiesi-Villa, Angiola; Guastini, Carlo (1983). "A homoleptic arylgold(I) complex: Synthesis and structure of pentanuclear mesitylgold(I)". Journal of the Chemical Society, Chemical Communications (22): 1304. doi:10.1039/C39830001304.