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Acrylic paint is fast drying paint containing pigment suspension in acrylic polymer emulsion. Acrylic paints can be diluted with water, but become water-resistant when dry. Depending on how much the paint is diluted (with water) or modified with acrylic gels, media, or pastes, the finished acrylic painting can resemble a watercolor or an oil painting, or have its own unique characteristics not attainable with other media.
As early as 1934 the first usable acrylic resin dispersion was developed by German chemical company BASF, which was patented by Rohm and Haas. Between 1946 and 1949, Leonard Bocour and Sam Golden invented a solution acrylic paint under the brand Magna paint. These were mineral spirit-based paints. Acrylics were made commercially available in the 1950s. A waterborne acrylic paint called "Aquatec" would soon follow. Otto Rohm invented acrylic resin, which quickly transformed into acrylic paint. In 1953, the year that Rohm and Haas developed the first acrylic emulsions, Jose L. Gutierrez produced Politec Acrylic Artists' Colors in Mexico, and Permanent Pigments Co. of Cincinnati, Ohio, produced Liquitex colors. These two product lines were the very first acrylic emulsion artists' paints. Water-based acrylic paints were subsequently sold as latex house paints, as latex is the technical term for a suspension of polymer microparticles in water. Interior latex house paints tend to be a combination of binder (sometimes acrylic, vinyl, pva, and others), filler, pigment, and water. Exterior latex house paints may also be a co-polymer blend, but the best exterior water-based paints are 100% acrylic, due to elasticity and other factors, but vinyl costs half of what 100 percent acrylic resins cost, and PVA (polyvinyl acetate) is even cheaper, so paint companies make many combinations of them to match the market.
Soon after the water-based acrylic binders were introduced as house paints, artists and companies alike began to explore the potential of the new binders. Water-soluble artists' acrylic paints became commercially available in the 1950s, offered by Liquitex, with high-viscosity paints similar to those made today becoming available in the early 1960s. In 1963, Rowney (now part of Daler-Rowney since 1983) was the first manufacturer to introduce an artist’s acrylic color in Europe, under the brand name Cryla.
Acrylic artist paints may be thinned with water and used as washes in the manner of watercolor paints, but the washes are not re-hydratable once dry. For this reason, acrylics do not lend themselves to color lifting techniques as do gum arabic based watercolor paints.
Acrylic paints with gloss or matte finishes are common, although a satin (semi-matte) sheen is most common; some brands exhibit a range of finish (e.g., heavy-body paints from Golden, Liquitex, Winsor & Newton and Daler-Rowney). Politec acrylics are fully matte. As with oils, pigment amounts and particle size or shape can naturally affect the paint sheen. Matting agents can also be added during manufacture to dull the finish. The artist can mix media with their paints and use topcoats or varnishes to alter or unify sheen if desired.
When dry, acrylic paint is generally non-removable from a solid surface. Water or mild solvents do not re-solubilize it, although isopropyl alcohol can lift some fresh paint films off. Toluene and acetone can remove paint films, but they do not lift paint stains very well and are not selective. The use of a solvent to remove paint may result in removal of all of the paint layers, acrylic gesso, etc. Oils can remove acrylic paint from skin.
Only a proper, artist-grade acrylic gesso should be used to prime canvas in preparation for painting with acrylic (however, acrylic paint can be applied to raw canvas if so desired without any negative effect or chemical reaction as would be the case with oils). It is important to avoid adding non-stable or non-archival elements to the gesso upon application. However, the viscosity of acrylic can successfully be reduced by using suitable extenders that maintain the integrity of the paint film. There are retarders to slow drying and extend workability time and flow releases to increase color-blending ability.
Painters and acrylic
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Prior to the 19th century, artists mixed their own paints, which allowed them to achieve the desired color and thickness and to control the use of fillers, if any. While suitable media and raw pigments are available for the individual production of acrylic paint, hand mixing may not be practical due to the fast drying time and other technical issues.
Acrylic painters can modify the appearance, hardness, flexibility, texture, and other characteristics of the paint surface by using acrylic media or simply by adding water. Watercolor and oil painters also use various media, but the range of acrylic media is much greater. Acrylics have the ability to bond to many different surfaces, and media can be used to adjust their binding characteristics. Acrylics can be used on paper, canvas and a range of other materials. However, their use on engineered woods such as medium-density fiberboard can be problematic because of the porous nature of those surfaces. In these cases it is recommended that the surface first be sealed with an appropriate sealer. Acrylics can be applied in thin layers or washes to create effects that resemble watercolors and other water-based media. They can also be used to build thick layers of paint—gel and molding paste media are sometimes used to create paintings with relief features that are literally sculptural. Acrylic paints are also used in hobbies such as train, car, house, and human models. People who make such models use acrylic paint to build facial features on dolls or raised details on other types of models. Acrylic paint is easily removed from paint brushes and skin with water, unlike oil paints that require the use of a hydrocarbon.
Acrylic paints are the most common paints used in grattage. Grattage is a surrealist technique that became popular with the release of acrylic paint. Acrylics are used for this purpose because they easily scrape or peel from a surface.
Commercial Acrylic paints come in three grades: "Artist" (or "Professional"), "Student" (or "studio"), and "Scholastic".
- Artist Acrylics are designed with the professional artist in mind. Highly pigmented with a focus on single pigment colors for the cleanest mixing results, they tend to have viscosity similar to oil paints and can thus hold a brush stroke for impasto applications. Acrylics can be applied to canvas, boards, paper, panels, wood, and a number of other prepared surfaces.
- Student Acrylics have working characteristics similar to professional artist acrylics, but with lower pigment concentrations, less expensive formulas, and a smaller range of colors. More expensive pigments are generally replicated by hues. Colors are designed to be mixed, although color strength is lower. Hues may not have the exact mixing characteristics of full-strength colors.
- Scholastic Acrylics use less expensive pigments as well as dyes in formulations that are safe for younger artists, and economical for classroom use. The color range is limited to common primary and secondary colors, and the actual pigments are unspecified. Because scholastic acrylics use dyes as well as pigments, lightfastness may be poor.
- Craft acrylics can be used on surfaces besides canvas, such as wood, metal, fabrics, and ceramics. They are used in decorative painting techniques and faux finishes, often to decorate objects of ordinary life. Although colors can be mixed, pigments are often not specified. Each color line is formulated instead to achieve a wide range of pre-mixed colors.
- Heavy body acrylics are typically found in the Artist and Student Grade paints, they are the best choice for impasto or heavier paint applications. Heavy Body refers to the viscosity or thickness of the paint. They will hold a brush or knife stroke and even a medium stiff peak. Gel Mediums are also available in Heavy and Super Heavy Body to help stiffen thinner viscosity paints.
- Interactive and open acrylics were created to address the one major difference between oil and acrylic paints, the shortened open time of acrylic paints. Designed with a retarder, slow drying medium, or other proprietary mediums that allow the paints to be reopened, these paints can take anywhere from a few hours to a few days, or even a few weeks to dry completely.
- Fluid acrylics, or flow, soft body acrylics, have a lower viscosity but generally have the same heavy pigmentation of the heavy body acrylics. Available in either Artist quality or Craft quality, there is a fluid acrylic for every level of art and budget. These paints are good for watercolor techniques, airbrush application, or when smooth coverage is desired. Mix the fluid acrylics with any of the mediums to thicken them for impasto work or thin them for glazing applications.
- Iridescent, pearl and interference acrylic colors combine conventional pigments with powdered mica (aluminium silicate) or powdered bronze to achieve complex effects. Colors have shimmering or reflective characteristics, depending on the coarseness or fineness of the powder. Iridescent colors are used in both fine arts and crafts.
- Acrylic gouache is like traditional gouache in that dries to a matte finish and is opaque. However, unlike traditional gouache, the acrylic binder in the acrylic gouache makes it water resistant once dry. Like craft acrylics, it will stick to a variety of surfaces other than canvas and paper. This paint is typically used by watercolorists, cartoonists, illustrators, and for decorative or folk art applications.
- Exterior acrylics are paints that can withstand outdoor conditions. Like craft acrylics, they adhere to many surfaces. They are more resistant to both water and ultraviolet light. This makes them the acrylic of choice for architectural murals, outdoor signs, and many faux finishing techniques.
Differences between acrylic and oil paint
The vehicle and binder of oil paints is linseed oil or another drying oil, whereas water serves as the vehicle for an emulsion (suspension) of acrylic polymer that is the binder in acrylic paint. Thus, oil paint is said to be "oil-based", while acrylic paint is "water-based" (or sometimes "water-borne").
The main practical difference between most acrylics and oil paints is the inherent drying time. Oils allow for more time to blend colors and apply even glazes over underpaintings. This slow drying aspect of oil can be seen as an advantage for certain techniques, but in other regards it impedes the artist trying to work quickly. The fast evaporation of water from regular acrylic paint films can be slowed with the use of acrylic retarders. Retarders are generally glycol or glycerin-based additives. The addition of a retarder slows the evaporation rate of the water.
Oil paints may require the use of solvents such as mineral spirits or turpentine to thin the paint and clean up; these generally have some level of toxicity and are often found objectionable. (Relatively recently, water-miscible oil paints have been developed for artists' use.) Oil paint films can become increasingly yellow and brittle with time and lose much of their flexibility in a few decades. Additionally, the rules of "fat over lean" must be employed to ensure the paint films are durable.
Oil paint has a higher pigment load than acrylic paint. As linseed oil has a smaller molecule than acrylic, oil paint is able to absorb substantially more pigment. Oil provides a different (less clear) refractive index than acrylic dispersions, imparting a unique "look and feel" to the resultant paint film. Not all pigments in oil are available in acrylic. Prussian blue has been recently added to the acrylic colors. Acrylic paints, unlike oil, may also be fluorescent.
Due to acrylic's more flexible nature and more consistent drying time between colors, the painter does not have to follow the "fat over lean" rule of oil painting, where more medium must be applied to each layer to avoid cracking. While canvas needs to be properly sized and primed before painting with oil (otherwise it will eventually rot the canvas), acrylic can be safely applied to raw canvas. The rapid drying of the paint tends to discourage the blending of color and use of wet-in-wet technique as in oil painting. While acrylic retarders can slow drying time to several hours, it remains a relatively fast-drying medium, and the addition of too much acrylic retarder can prevent the paint from ever drying properly.
Meanwhile, acrylic paint is very elastic, which prevents cracking from occurring. Acrylic paint's binder is acrylic polymer emulsion; as this binder dries the paint remains flexible.
Another difference between oil and acrylic paints is the versatility offered by acrylic paints - acrylic is very useful in mixed media, allowing use of pastel (oil & chalk), charcoal, pen, etc. on top of the dried acrylic painted surface. Mixing other bodies into the acrylic is possible - sand, rice, even pasta may be incorporated in the artwork. Mixing artist or student quality acrylic paint with household acrylic emulsions is possible, allowing the use of pre-mixed tints straight from the tube or tin, so presenting the painter with a vast color range at his or her disposal. This versatility is also illustrated in the wide variety of additional artistic uses that acrylics afford the artist. Specialist acrylics have been manufactured and used for lino block printing (acrylic block printing ink produced by Derivan since the early 1980s), face painting, airbrushing, water color techniques, and fabric screen printing.
- Terry Fenton online essay about Kenneth Noland, and acrylic paint, accessed April 30th, 2007
- "A History of GOLDEN Artist Colors, Inc.". Golden Artist Colors, Inc.
- Painting With Acrylics (Watson-Guptill publications)
- "Water-based Alchemy by Dean Sickler". Retrieved August 11, 2012.
- The History of Liquitex Acrylic Art Materials  History Timeline of Liquitex, accessed December 06, 2010
- "Art Materials". Daler Rowney. 2012-02-15. Retrieved 2013-02-05.
- Removing Acrylic Paint From Skin  Instructions accessed December 08, 2010
- Sealing, Staining, and Filling  Wood Finishing and Refinishing accessed December 08, 2010
- Grattage  Art Techniques accessed December 08, 2010
- What is Acrylic Paint?  History and Techniques, accessed December 08, 2010
- Acrylic Paint Common Questions  Technical Summary of Acrylic Paint accessed December 06, 2010