Afwillite

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Afwillite
Afwillite 2 on rock Hydrous calcium silicate Crestmore Quarry Riverside California 2068.jpg
Afwillite from Crestmore Quarry, Riverside County, California
General
Category Nesosilicates
Formula
(repeating unit)
Ca3(SiO3OH)2.2H2O
Strunz classification 09.AG.75
Crystal symmetry Monoclinic sphenoidal
H-M symbol: (2)
Space group: P 21
Unit cell a = 16.278(1) Å, b = 5.6321(4) Å, c = 13.236(1) Å; β = 134.9°; Z=4
Identification
Color Colorless, white
Crystal habit Prismatic (striated), tabular, radial fibrous, massive
Crystal system Monoclinic
Cleavage Perfect along [101], good along [100]
Fracture Conchoidal
Tenacity Brittle
Mohs scale hardness 3–4
Luster Vitreous
Streak White
Diaphaneity Transparent to translucent
Specific gravity 2.630
Optical properties Biaxial (+)
Refractive index nα = 1.617 nβ = 1.620 nγ = 1.634
Birefringence δ = 0.0167
2V angle Measured: 50° to 56°
Dispersion r < v
Other characteristics Piezoelectric
References [1][2][3]

Afwillite is a calcium hydroxide nesosilicate mineral with formula Ca3(SiO3OH)2·2H2O. It occurs as glassy, colorless to white prismatic monoclinic crystals. Its Mohs scale hardness is between 3 and 4. It occurs as an alteration mineral in contact metamorphism of limestone.[3] It occurs in association with apophyllite, natrolite, thaumasite, merwinite, spurrite, gehlenite, ettringite, portlandite, hillebrandite, foshagite, brucite and calcite.[3]

It was first described in 1925 for an occurrence in the Dutoitspan Mine, Kimberley, South Africa and was named for Alpheus Fuller Williams (1874–1953), a past official of the De Beers diamond company.[2]

Afwillite is typically found in veins of spurrite and it belongs to the nesosilicate sub-class. It is monoclinic, its space group is P2 and its point group is 2.

Formation of afwillite[edit]

It is suggested that afwillite forms in fractured veins of the mineral spurrite. Jennite, afwillite, oyelite and calcite are all minerals that form in layers within spurrite veins. It appears that the afwillite, as well as the calcite, forms from precipitated fluids. The jennite is actually an alteration of the afwillite, but both formed from calcium silicates through hydration. Laboratory studies determined that afwillite forms at a temperature below 200 °C, usually around 100 °C.[4] Afwillite and spurrite are formed through contact metamorphism of limestone.[5] Contact metamorphism is caused by the interaction of rock with heat and/or fluids from a nearby crystallizing silicate magma.[6]

Structure and properties[edit]

Afwillite has a complex monoclinic structure, and the silicon tetrahedra in the crystal structure are held together by hydrogen bonds.[7] It has perfect cleavage parallel to its (101) and poor cleavage parallel to its (100) faces.[8] It is biaxial and its 2V angle, the measurement from one optical axis to the other optical axis, is 50 – 56 degrees. When viewed under crossed polarizers in a petrographic microscope, it displays first-order orange colors, giving a maximum birefringence of 0.0167 (determined by using the Michel- Levy chart). Afwillite is optically positive. Additionally, it has a prismatic crystal habit.[4] Under a microscope afwillite looks like wollastonite, which is in the same family as afwillite.

Awfillite is composed of double chains that consist of calcium and silicon polyhedral connected to each other by sharing corners and edges. This causes continuous sheets to form parallel to its miller index [-101] faces. The sheets are bonded together by hydrogen bonds and are all connected by Ca-Si-O bonds (Malik and Jeffery 1976). Each calcium atom is in 6-fold octahedral coordination with the oxygen, and the silicon is in 4-fold tetrahedral coordination around the oxygen. Around each silicon there is one OH group and there are three oxygens that neighbor them.[7] The silicon tetrahedra are arranged so that they share an edge with calcium(1), and silicon(2) shares edges with the calcium(2) and calcium(3) polyhedral.[7] The silicon tetrahedra are held together by the OH group and hydrogen bonding occurs between the hydrogen in the OH and the silicon tetrahedra. Hydrogen bonding is caused because the positive ion, hydrogen, is attracted to negatively charge ions which, in this case, are the silicon tetrahedra.[6]

Occurrence in concrete[edit]

Afwillite is one of the calcium silicates that form when Portland cement sets to form concrete. [9] The cement gets its strength from the hydration of its di- and tri- calcium silicates.

See also[edit]

References[edit]

  1. ^ Mindat with location data
  2. ^ a b Webmineral data
  3. ^ a b c Handbook of Mineralogy
  4. ^ a b Kusachi, I, Henmi, C. And Henmi K. (1989) Afwillite and jennite from Fuka, Okayama Prefecture. Japan. Miner J. 14, 279-292.
  5. ^ Barthemy, D. (2000) Afwillite Mineral Data, (http://webmineral.com/data/Afwillite.shtml)
  6. ^ a b Klein, C. and Dutrow, K. (2007) Manual of Mineral Science. 23rd Edition, 63, 596
  7. ^ a b c Malik, K. M. A & Jeffery J. W. (1976) A Re-investigation of the Structure of Afwillite. Acta Cryst. B32, 475
  8. ^ Megaw H. D. (1952). The structure of Afwilltie. Acta Cryst. 5, 477
  9. ^ http://www.minersoc.org/pages/Archive-MM/Volume_29/29-216-838.pdf Moody, K. M., 1952, The thermal decomposition of afwillite, The Mineralogical Society