Coordinates: Alfredo Chaves is a municipality in the state of Espírito Santo, Brazil. It is 60 km southwest of the state capital, Vitória. Its population was 14,223 (2005) and its area is 615.59 km².
The municipality is mountainous, though not very high in general. Its highest peak is Trancenco Peak at 1,050 m above sea level. The town of Alfredo Chaves lies at 10 m above sea level.
The economy is mainly based on livestock, including cows (for milk) and chickens. In agriculture, coffee and banana plantations play an important role.