Aluminium antimonide

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Aluminium antimonide
Identifiers
CAS number 25152-52-7 YesY
PubChem 91307
ChemSpider 82452 YesY
Jmol-3D images Image 1
Properties
Molecular formula AlSb
Molar mass 148.742 g/mol
Appearance black crystals
Density 4.26 g/cm3
Melting point

1060 °C

Boiling point

2467 °C

Solubility in water insoluble
Band gap 1.58 eV
Refractive index (nD) 3.3
Structure
Crystal structure Zinc blende
Space group T2d-F-43m
Coordination
geometry
Tetrahedral
Hazards
MSDS MSDS
NFPA 704
NFPA 704.svg
3
0
1
Autoignition
temperature
590 °C
 YesY (verify) (what is: YesY/N?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Aluminium antimonide (AlSb) is a semiconductor of the group III-V family containing aluminium and antimony. The lattice constant is 0.61 nm. The indirect bandgap is approximately 1.6 eV at 300 K, whereas the direct band gap is 2.22 eV.

Its electron mobility is 200 cm²·V−1·s−1 and hole mobility 400 cm²·V−1·s−1 at 300 K. Its refractive index is 3.3 at a wavelength of 2 µm, and its dielectric constant is 10.9 at microwave frequencies [1].

AlSb can be alloyed with other III-V materials to produce the following ternary materials: AlInSb, AlGaSb and AlAsSb.

Aluminum antimonide is rather flammable because of the reducing tendency of the antimonide (Sb3-) ion. It burns to produce aluminum oxide and antimony trioxide.

[edit] See also

[edit] References

  1. ^ K Seeger and E Schonherr "Microwave dielectric constant of aluminium antimonide" Semicond. Sci. Technol. 6 (1991) 301 doi:10.1088/0268-1242/6/4/013


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