Alunite
| Alunite | |
|---|---|
 Alunite from Utah - USGS |
|
| General | |
| Category | Sulfate minerals |
| Formula (repeating unit) |
KAl3(SO4)2(OH)6 |
| Strunz classification | 07.BC.10 |
| Crystal symmetry | Trigonal 3m or 32/m |
| Unit cell | a = 6.98 Å, c = 17.32 Å; Z=3 |
| Identification | |
| Color | Yellow, red, to reddish brown, colorless if pure; may be white, pale shades of gray, |
| Crystal habit | fibrous to columnar, porcelaneous, commonly granular to dense massive |
| Crystal system | Trigonal |
| Cleavage | On {0001}, perfect |
| Fracture | Conchoidal |
| Tenacity | Brittle |
| Mohs scale hardness | 3.5 - 4 |
| Luster | Vitreous, somewhat pearly on {0001} for crystals, earthy if massive |
| Streak | White |
| Diaphaneity | Transparent to translucent |
| Specific gravity | 2.6 - 2.9 |
| Optical properties | Uniaxial (+) |
| Refractive index | nω = 1.572 nε = 1.592 |
| Birefringence | δ = 0.020 |
| Other characteristics | Strongly pyroelectric |
| References | [1][2][3][4] |
Alunite is a sulfate mineral that was first observed in the 15th century in Monti della Tolfa, north of Rome, where it was mined for the manufacture of alum. First called aluminilite by J.C. Delamétherie in 1797, this name was contracted by François Beudant in 1824 to alunite.
Distinct crystals of alunite are rarely found in cavities in the massive material. Alunite crystallizes in the hexagonal system with crystals forming trigonal pyramids that resemble rhombohedra with interfacial angles of 90° 50', so that they resemble cubes in appearance. Minute glistening crystals have also been found loose in cavities in altered rhyolite. Alunite varies in color from white to yellow gray. The hardness is 4 and the specific gravity is between 2.6 and 2.8. The mineral is a hydrated aluminium potassium sulfate, KAl3(SO4)2(OH)6. Sodium substitutes for potassium and when high in sodium it is called natroalunite. It is insoluble in water or weak acids, but soluble in sulfuric acid. Jarosite is an iron analogue in which Fe3+ replaces the aluminium. It occurs as a secondary mineral on iron sulfate ores.
Alunite occurs as veins and replacement masses in trachyte, rhyolite, and similar potassium rich volcanic rocks. It is formed by the action of sulfuric acid bearing solutions on these rocks during the oxidation and leaching of metal sulfide deposits. Alunite also is found near volcanic fumaroles. The white, finely granular masses closely resemble finely granular limestone, dolomite, anhydrite, and magnesite in appearance. The more compact kinds from Hungary are so hard and tough that they have been used for millstones.
Historically extensive deposits were mined in Tuscany and Hungary, and at Bulahdelah, Australia. Currently found at Tolfa, Italy. In the United States it is found in the San Juan district of Colorado; Goldfield, Nevada; the ghost town of Alunite, Utah near Marysvale; and Red Mountain near Patagonia, Arizona. The Arizona occurrence lies appropriately above a canyon named Alum Gulch. Alunite is mined as an ore of both potassium and aluminium at Marysvale.[4] Some of the ore deposits were located by airborne and satellite multispectral imaging.
See also [edit]
References [edit]
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Wikimedia Commons has media related to: Alunite |
- ^ http://rruff.geo.arizona.edu/doclib/hom/alunite.pdf Handbook of Mineralogy
- ^ http://www.mindat.org/min-161.html Mindat.org
- ^ http://webmineral.com/data/Alunite.shtml Webmineral data
- ^ a b Hurlbut, Cornelius S.; Cornelis Klein (1985). Manual of Mineralogy (20th ed. ed.). ISBN 0-471-80580-7.
- Hurlbut, Cornelius S. (1966). Dana's Manual of Mineralogy (17th ed. ed.). ISBN 0-471-03288-3.
