Ammonium nitrite

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Ammonium nitrite
Ammonium Nitrite 2D.jpg
Ammonium Nitrite 3D.JPG
Identifiers
CAS number 13446-48-5 YesY
ChemSpider 24223 YesY
Jmol-3D images Image 1
Properties
Molecular formula NH4NO2
Molar mass 64.06 g/mol
Appearance pale yellow crystals, slowly decomposes to nitrogen and water
Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
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Infobox references

Ammonium nitrite, NH4NO2, is the ammonia salt of nitrous acid. It is used as a rodenticide, microbiocide and agricultural pesticide, and is acutely toxic to both humans and aquatic organisms.[1]

Preparation[edit]

Ammonium nitrite forms naturally in the air and can be prepared by the absorption of equal parts nitrogen dioxide and nitric oxide upon aqueous ammonia.[2]

It can also be prepared by oxidizing ammonia with ozone or hydrogen peroxide, or in a precipitation reaction of barium or lead nitrite with ammonium sulfate, or silver nitrite with ammonium chloride, or ammonium perchlorate with potassium nitrite. The precipitate is filtered off and the solution concentrated. It forms colorless crystals which are soluble in water and decompose on heating or in the presence of acid, with the formation of nitrogen.[3] Ammonium nitrite solution is stable at higher pH and lower temperature. If there is any decrease in pH lower than 7.0, It may lead to explosion. It is desirable to maintain pH by adding ammonia solution. The mole ratio of Ammonium Nitrite to Ammonia must be above 10% mole ratio.

NH4NO2 → N2 + 2 H2O

Properties[edit]

Ammonium nitrite may explode at a temperature of 60–70 °C.[2] It decomposes more quickly when a concentrated solution than when it is a dry crystal.

References[edit]

  1. ^ "Ammonium nitrite - Identification, toxicity, use, water pollution potential, ecological toxicity and regulatory information". PAN Pesticides Database - Chemicals. Retrieved 2006-07-26. 
  2. ^ a b Thomas Scott; Mary Eagleson (1994). Concise encyclopedia chemistry. Walter de Gruyter. p. 66. ISBN 3-11-011451-8. 
  3. ^ "VIAS Encyclopedia: Ammonium Nitrite".