Antimony(III) acetate
| Antimony(III) acetate | |
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Antimony(III) acetate |
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Other names
Antimony triacetate |
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| Identifiers | |
| CAS number | 6923-52-0 |
| PubChem | 16685080 |
| ChemSpider | 21839 |
| RTECS number | AF4200000 |
| Jmol-3D images | Image 1 Image 2 |
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| Properties | |
| Molecular formula | C6H9O6Sb |
| Molar mass | 298.89 g mol−1 |
| Appearance | White powder |
| Density | 1.22 g/cm³ (20 °C) |
| Melting point |
128.5 °C, 402 K, 263 °F |
| Hazards | |
| NFPA 704 | |
| LD50 | 4480 mg/kg (rat) |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) |
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| Infobox references | |
Antimony(III) acetate is the antimony salt of acetic acid with the chemical formula of Sb(CH3COO)3. It has the appearance of a white powder and is used as a catalyst in the production of synthetic fibers. It can be prepared by the reaction of antimony(III) oxide with acetic acid:
- Sb2O3 + 6 HC2H3O2 → 2 Sb(C2H3O2)3 + 3H2O
The crystal structure of antimony(III) acetate has been determined by X-ray crystallography. It consists of discrete Sb(OAc)3 monomers with monodentate acetate ligands. The monomers are linked together into chains by weaker C=O···Sb intermolecular interactions.[1]
[edit] References
- ^ Hall, M.; Sowerby, D. B. (1980). "Antimony(III) acetate and thioacetate: spectra and crystal structures". J. Chem. Soc., Dalton Trans. (8): 1292–1296. doi:10.1039/DT9800001292.
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