Antitaenite

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Antitaenite is a meteoritic metal alloy mineral composed of iron and nickel, 20-40% Ni (and traces of other elements) that has a face centered cubic crystal structure.

Its existence as a new mineral species occurring in both iron meteorites and in chondrites was first recognized in 1995[1] but the IMA didn't approve paramagnetic antitaenite (a variety of taenite now). Gamma (fcc) Fe-Ni alloys with low-Ni (c. 25% Ni) are probably inhomogeneous on a nanometer scale.[2]

There are three other known Fe-Ni meteoritic minerals: kamacite, taenite, and tetrataenite.

The pair of minerals antitaenite and taenite constitute the first example in nature of two minerals that have the same crystal structure (face centered cubic) and can have the same chemical composition (same proportions of Fe and Ni) - but differ in their electronic structures: taenite has a high magnetic moment whereas antitaenite has a low magnetic moment.

This unique difference in electronic structure was first established in 1999[3] and arises from a high-magnetic-moment to low-magnetic-moment transition occurring in the Fe-Ni bi-metallic alloy series.[4] The same electronic structure transition is believed to be a causal factor in Invar behaviour.

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References[edit]

  1. ^ D.G. Rancourt and R.B. Scorzelli. Low Spin γ-Fe-Ni (γLS) Proposed as a New Mineral in Fe-Ni-Bearing Meteorites: Epitaxial Intergrowth of γLS and Tetrataenite as Possible Equilibrium State at ~20-40 at % Ni. Journal of Magnetism and Magnetic Materials 150 (1995) 30-36
  2. ^ Yassir Ahmed Mohamed Abdu (2004). Mössbauer Spectroscopy of Meteoritic and Synthetic Fe-Ni Alloys (Thesis). University of Uppsala. Retrieved 4 December 2012. 
  3. ^ D.G. Rancourt, K. Lagarec, A. Densmore, R.A. Dunlap, J.I. Goldstein, R.J. Reisener, and R.B. Scorzelli. Experimental Proof of the Distinct Electronic Structure of a New Meteoritic Fe-Ni Alloy Phase. Journal of Magnetism and Magnetic Materials 191 (1999) L255-L260
  4. ^ K. Lagarec, D.G. Rancourt, S.K. Bose, B. Sanyal, and R.A. Dunlap. Observation of a composition-controlled high-moment/low-moment transition in the face centered cubic Fe-Ni system: Invar effect is an expansion, not a contraction. Journal of Magnetism and Magnetic Materials 236 (2001) 107-130.

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