Apparent molar property
where V0 is the molar volume of the solvent, n0 is the number of moles of solvent, is the apparent molar volume of solute i, and ni is the number of moles of solute i in the solution. (The apparent molar volume can also be denoted Vφ.) This equation applied to a single-solute solution serves as the definition of the apparent molar volume of the solute. For multicomponent solutions, the equation does not give an unambiguous definition of the apparent molar properties.
The sum of the extensive apparent quantities/volumes is given by:
where q is the number of the components of the mixture.
The apparent molar volume of a salt is usually less than the molar volume of the solid salt. For instance, solid NaCl has a volume of 27 cm3 per mole, but the apparent molar volume at low concentrations is only 16.6 cc/mole. In fact, some aqueous electrolytes have negative apparent molar volumes: NaOH -6.7, LiOH -6.0, and Na2CO3 -6.7 cm3/mole. This means that their solutions in a given amount of water have a smaller volume than the same amount of pure water. The physical reason is that nearby water molecules are strongly attracted to the ions so that they occupy less space.
- Volume fraction
- Ideal solution
- Regular solution
- Solvation shell
- Partial molar property
- Excess molar quantity
- Thermodynamic activity
- Apparent Molar Properties: Solutions: Background
- The (p,ρ,T) Properties and Apparent Molar Volumes of ethanol solutions of LiI or ZnCl2
- Apparent molar volumes and apparent molar heat capacities of Pr(NO3)3(aq), Gd(NO3)3(aq), Ho(NO3)3(aq), and Y(NO3)3(aq) at T = (288.15, 298.15, 313.15, and 328.15) K and p = 0.1 MPa