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The terms atomic battery, nuclear battery, tritium battery and radioisotope generator are used to describe a device which uses energy from the decay of a radioactive isotope to generate electricity. Like nuclear reactors they generate electricity from atomic energy, but differ in that they do not use a chain reaction. Compared to other batteries they are very costly, but have extremely long life and high energy density, and so they are mainly used as power sources for equipment that must operate unattended for long periods of time, such as spacecraft, pacemakers, underwater systems and automated scientific stations in remote parts of the world.
Nuclear battery technology began in 1913, when Henry Moseley first demonstrated the beta cell. The field received considerable in-depth research attention for applications requiring long-life power sources for space needs during the 50s and 60s. In 1954 RCA researched a small atomic battery for small radio receivers and hearing aids. Since RCA's initial research and development in the early '50s, many types and methods have been designed to extract electrical energy from nuclear sources. The scientific principles are well known, but modern nano-scale technology and new wide bandgap semiconductors have created new devices and interesting material properties not previously available.
Batteries using the energy of radioisotope decay to provide long-lived power (10–20 years) are being developed internationally. Conversion techniques can be grouped into two types: thermal and non-thermal. The thermal converters (whose output power is a function of a temperature differential) include thermoelectric and thermionic generators. The non-thermal converters (whose output power is not a function of a temperature difference) extract a fraction of the incident energy as it is being degraded into heat rather than using thermal energy to run electrons in a cycle. Atomic batteries usually have an efficiency of 0.1–5%. High efficiency betavoltaics have 6–8%.
 Thermal converters
- Thermionic converter
- A thermionic converter consists of a hot electrode which thermionically emits electrons over a space charge barrier to a cooler electrode, producing a useful power output. Caesium vapor is used to optimize the electrode work functions and provide an ion supply (by surface contact ionization) to neutralize the electron space charge.
- Radioisotope thermoelectric generator
- A thermoelectric converter connects pairs of thermocouples in series. Each thermocouple is formed by the junction of two dissimilar materials. One of each pair is heated and the other cooled. Metal thermocouples have low thermal-to-electrical efficiency. However, the carrier density and charge can be adjusted in semiconductor materials such as bismuth telluride and silicon germanium to achieve much higher conversion efficiencies.
- Thermophotovoltaic cells
- Thermophotovoltaic cells work by the same principles as a photovoltaic cell, except that they convert infrared light (rather than visible light) emitted by a hot surface, into electricity. Thermophotovoltaic cells have an efficiency slightly higher than thermoelectric couples and can be overlaid on thermoelectric couples, potentially doubling efficiency. The University of Houston TPV Radioisotope Power Conversion Technology development effort is aiming at combining thermophotovoltaic cells concurrently with thermocouples to provide a 3 to 4-fold improvement in system efficiency over current thermoelectric radioisotope generators.
- Alkali-metal thermal to electric converter
- The alkali-metal thermal to electric converter (AMTEC) is an electrochemical system which is based on the electrolyte used in the sodium-sulfur battery, sodium beta-alumina. The device is a sodium concentration cell which uses a ceramic, polycrystalline β-alumina solid electrolyte (BASE), as a separator between a high pressure region containing sodium vapor at 900 - 1300 K and a low pressure region containing a condenser for liquid sodium at 400 - 700 K. Efficiency of AMTEC cells has reached 16% in the laboratory and is predicted to approach 20%.
- Stirling radioisotope generator
- A Stirling engine driven by the temperature difference produced by a radioisotope.
 Non-thermal converters
Non-thermal converters extract a fraction of the nuclear energy as it is being degraded into heat. Their outputs are not functions of temperature differences as are thermoelectric and thermionic converters. Non-thermal generators can be grouped into three classes.
 Direct charging generators
In the first type, the primary generator consists of a capacitor which is charged by the current of charged particles from a radioactive layer deposited on one of the electrodes. Spacing can be either vacuum or dielectric. Negatively charged beta particles or positively charged alpha particles, positrons or fission fragments may be utilized. Although this form of nuclear-electric generator dates back to 1913, few applications have been found in the past for the extremely low currents and inconveniently high voltages provided by direct charging generators. Oscillator/transformer systems are employed to reduce the voltages, then rectifiers are used to transform the AC power back to direct current.
English physicist H.G.J. Moseley constructed the first of these. Moseley’s apparatus consisted of a glass globe silvered on the inside with a radium emitter mounted on the tip of a wire at the center. The charged particles from the radium created a flow of electricity as they moved quickly from the radium to the inside surface of the sphere. As late as 1945 the Moseley model guided other efforts to build experimental batteries generating electricity from the emissions of radioactive elements.
Betavoltaics are generators of electrical current, in effect a form of battery, which use energy from a radioactive source emitting beta particles (electrons). A common source used is the hydrogen isotope, tritium. Unlike most nuclear power sources, which use nuclear radiation to generate heat, which then generates electricity (thermoelectric and thermionic sources), betavoltaics use a non-thermal conversion process, using a semiconductor p-n junction.
Betavoltaics are particularly well-suited to low-power electrical applications where long life of the energy source is needed, such as implantable medical devices or military and space applications.
An optolectric nuclear battery has also been proposed by researchers of the Kurchatov Institute in Moscow. A beta-emitter (such as technetium-99) would stimulate an excimer mixture, and the light would power a photocell. The battery would consist of an excimer mixture of argon/xenon in a pressure vessel with an internal mirrored surface, finely-divided Tc-99, and an intermittent ultrasonic stirrer, illuminating a photocell with a bandgap tuned for the excimer. The advantage of this design is that precision electrode assemblies are not needed, and most beta particles escape the finely-divided bulk material to contribute to the battery's net power.
 Reciprocating Electromechanical Atomic Batteries
Electromechanical atomic batteries use the build up of charge between two plates to pull one bendable plate towards the other, until the two plates touch, discharge, equalizing the electrostatic buildup, and spring back. The mechanical motion produced can be used to produce electricity through flexing of a piezoelectric material or through a linear generator. Milliwatts of power are produced in pulses depending on the charge rate, in some cases multiple times per second (35 Hz).
 Radioisotopes used
Atomic batteries use radioisotopes that produce low energy beta particles or sometimes alpha particles of varying energies. Low energy beta particles are needed to prevent the production of high energy penetrating Bremsstrahlung radiation that would require heavy shielding. Radioisotopes such as tritium, nickel-63, promethium-147, and technetium-99 have been tested. Plutonium-238, curium-242, curium-244 and strontium-90 have been used.
 See also
- Radioisotope thermoelectric generator
- Induced gamma emission from long-lived excited nuclei of specific nuclear isomers.
- "A nuclear battery the size and thickness of a penny." Gizmag, October 9th 2009
- "Tiny 'nuclear batteries' unveiled." BBC News, Thursday 8th October 2009
- "Atomic Battery Converts Radioactivity Directly Into Electricity." Popular Mechanics, April 1954, p. 87.
- NASA Glenn Research Center, Alpha- and Beta-voltaics (accessed Oct. 4, 2011)
- Sheila G. Bailey, David M. Wilt, Ryne P. Raffaelle, and Stephanie L. Castro, Alpha-Voltaic Power Source Designs Investigated, Research and Technology 2005, NASA TM-2006-214016, (accessed Oct. 4, 2011)
- Lal, Amit; Rajesh Duggirala, Hui Li (2005). "Pervasive Power:A Radioisotope-Powered Piezoelectric Generator". IEEE Pervasive Computing.[dead link]