Barium ferrate
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| Barium ferrate | |
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Barium ferrate(VI) |
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Other names
Barium ferrate(2-) |
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| Identifiers | |
| CAS number | 13773-23-4  |
| Jmol-3D images | Image 1 |
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| Properties | |
| Molecular formula | BaFeO4 |
| Molar mass | 257.17 g mol−1 |
| Appearance | Dark red, opaque crystals |
| Solubility in water | insoluble |
 (verify) (what is:  / ?)Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) |
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| Infobox references | |
Barium ferrate is the chemical compound of formula BaFeO4. This compound contains iron in the +6 oxidation state.[1] It is isostructural with BaSO4, and contains the tetrahedral [FeO4]2− anion.[2]
Preparation and chemistry [edit]
Anhydrous barium ferrate can be prepared by precipitation from a solution containing potassium ferrate and barium chloride.[3] Barium ferrate is an oxidising agent and has been proposed as an oxidising reagent for use in organic syntheses.[4]
References [edit]
- ^ J. G. R. Briggs (2005). Longman A-level course in chemistry (4th ed.). Pearson Education South Asia. p. 536. ISBN 981-4105-08-2.
- ^ Wells, A.F. (1986). Structural inorganic chemistry (5th ed. ed.). Oxford [Oxfordshire]: Clarendon Press. ISBN 0-19-855370-6.
- ^ Gump, J. R.; Wagner, W. F.; schreyer, J. M. (1 December 1954). Analytical Chemistry 26 (12): 1957–1957. doi:10.1021/ac60096a027.
- ^ Firouzabadi, H.; Mohajer, D.; Entezari-moghaddam, M. "Barium Ferrate Monohydrate BaFeO4·H2O, A Versatile Reagent for the Oxidation of Organic Compounds under Aprotic Condiiton". Synthetic Communications 16 (6): 723–731. doi:10.1080/00397918608057745.
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