Barium hydroxide

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Barium hydroxide
Ba(OH)2monohydrate.tif
Ba(OH)2 octahydrate.JPG
Identifiers
17194-00-2 YesY

22326-55-2 (monohydrate)
12230-71-6 (octahydrate)
ChEBI CHEBI:32592 YesY
ChemSpider 26408 YesY
Jmol-3D images Image
PubChem 28387
RTECS number CQ9200000
Properties
Ba(OH)2
Molar mass 171.34 g/mol (anhydrous)
189.39 g/mol (monohydrate)
315.46 g/mol (octahydrate)
Appearance white solid
Density 3.743 g/cm3 (monohydrate)
2.18 g/cm3 (octahydrate, 16 °C)
Melting point 78 °C (172 °F; 351 K) (octahydrate)
300 °C (monohydrate)
407 °C (anhydrous)
Boiling point 780 °C (1,440 °F; 1,050 K)
mass of BaO (not Ba(OH)2):
1.67 g/100 mL (0 °C)
3.89 g/100 mL (20 °C)
4.68 g/100 mL (25 °C)
5.59 g/100 mL (30 °C)
8.22 g/100 mL (40 °C)
11.7 g/100 mL (50 °C)
20.94 g/100 mL (60 °C)
101.4 g/100 mL (100 °C)
Solubility in other solvents low
Basicity (pKb) -2.02
1.50 (octahydrate)
Structure
Crystal structure octahedral
Thermochemistry
−944.7 kJ/mol
Hazards
MSDS External MSDS
EU Index 056-002-00-7
EU classification Harmful (Xn)
R-phrases R20/22
S-phrases (S2), S28
NFPA 704
Flammability code 0: Will not burn. E.g., water Health code 3: Short exposure could cause serious temporary or residual injury. E.g., chlorine gas Reactivity code 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g., liquid nitrogen Special hazards (white): no codeNFPA 704 four-colored diamond
Flash point Non-flammable
Related compounds
Other anions
Barium oxide
Barium peroxide
Other cations
Calcium hydroxide
Strontium hydroxide
Supplementary data page
Refractive index (n),
Dielectric constantr), etc.
Thermodynamic
data
Phase behaviour
solid–liquid–gas
UV, IR, NMR, MS
Except where noted otherwise, data is given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
 YesY verify (what isYesY/N?)
Infobox references

Barium hydroxide are chemical compounds with the formulae Ba(OH)2(H2O)x. The monohydrate (x =1) is known as baryta, or baryta-water, it is one of the principal compounds of barium. This white granular monohydrate is the usual commercial form.

Preparation and structure[edit]

Barium hydroxide can be prepared by dissolving barium oxide (BaO) in water:

BaO + 9 H2O → Ba(OH)2·8H2O

It crystallises as the octahydrate, which converts to the monohydrate upon heating in air. At 100 °C in a vacuum, the monohydrate gives BaO.[1] The monohydrate adopts a layered structure (see picture above). The Ba2+ centers adopt a square anti-prismatic geometry. Each Ba2+ center is bound by two water ligands and six hydroxide ligands, which are respectively doubly and triply bridging to neighboring Ba2+ centers. sites.[2] In the octahydrate, the individual Ba2+ centers are again eight coordinate but do not share ligands.[3]

Coordination sphere about an individual barium ion in Ba(OH)2.H2O.

Uses[edit]

Industrially, barium hydroxide is used as the precursor to other barium compounds. The monohydrate is used to dehyrate and remove sulfate from various products.[4] This application exploits the very low solubility of barium sulfate. This industrial application is also applied to laboratory uses.

Laboratory uses[edit]

Barium hydroxide is used in analytical chemistry for the titration of weak acids, particularly organic acids. Its clear aqueous solution is guaranteed to be free of carbonate, unlike those of sodium hydroxide and potassium hydroxide, as barium carbonate is insoluble in water. This allows the use of indicators such as phenolphthalein or thymolphthalein (with alkaline colour changes) without the risk of titration errors due to the presence of carbonate ions, which are much less basic.[5]

Barium hydroxide is occasionally used in organic synthesis as a strong base, for example for the hydrolysis of esters.[6] and nitriles.[7][8][9]

Barium hydroxide-catalyzed 2-carboxy-1,3-dihydroxynaphthalene preparation.svg
Barium hydroxide-catalyzed methylsuccinic acid preparation.svg

It has been used to hydrolyse one of the two equivalent ester groups in dimethyl hendecanedioate.[10]

Barium hydroxide is used, as well, in the decarboxylation of amino acids liberating barium carbonate in the process. [11]

It is also used in the preparation of cyclopentanone,[12] diacetone alcohol[13] and D-Gulonic γ-lactone.[14]

Barium hydroxide-catalyzed diacetone alcohol preparation.svg

Reactions[edit]

Barium hydroxide decomposes to barium oxide when heated to 800 °C. Reaction with carbon dioxide gives barium carbonate. Its aqueous solution, being highly alkaline, undergoes neutralization reactions with acids. Thus, it forms barium sulfate and barium phosphate with sulfuric and phosphoric acids, respectively. Reaction with hydrogen sulfide produces barium sulfide. Precipitation of many insoluble, or less soluble barium salts, may result from double replacement reaction when a barium hydroxide aqueous solution is mixed with many solutions of other metal salts. [15]

Reactions of barium hydroxide with ammonium salts are strongly endothermic. The reaction of barium hydroxide octahydrate with ammonium chloride[16] [17] or[18] ammonium thiocyanate[18][19] is often used as a classroom chemistry demonstration, producing temperatures cold enough to freeze water and enough water to dissolve the resulting mixture.

Safety[edit]

Barium hydroxide presents the same hazards as other strong bases and as other water-soluble barium compounds: it is corrosive and toxic.

See also[edit]

References[edit]

  1. ^ (1960). Gmelins Handbuch der anorganischen Chemie (8. Aufl.), Weinheim: Verlag Chemie, p. 289.
  2. ^ Kuske, P.; Engelen, B.; Henning, J.; Lutz, H.D.; Fuess, H.; Gregson, D. "Neutron diffraction study of Sr(OH)2(H2O) and beta-Ba(OH)2*(H2O)" Zeitschrift fuer Kristallographie (1979-2010) 1988, vol. 183, p319-p325.
  3. ^ Manohar, H.; Ramaseshan, S. "The crystal structure of barium hydroxide octahydrate Ba (OH)2(H2O)8" Zeitschrift fuer Kristallographie, Kristallgeometrie, Kristallphysik, Kristallchemie 1964. vol. 119, p357-p374
  4. ^ Robert Kresse, Ulrich Baudis, Paul Jäger, H. Hermann Riechers, Heinz Wagner, Jochen Winkler, Hans Uwe Wolf, "Barium and Barium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2007 Wiley-VCH, Weinheim. doi:10.1002/14356007.a03_325.pub2
  5. ^ Mendham, J.; Denney, R. C.; Barnes, J. D.; Thomas, M. J. K. (2000), Vogel's Quantitative Chemical Analysis (6th ed.), New York: Prentice Hall, ISBN 0-582-22628-7 
  6. ^ Meyer, K.; Bloch, H. S. (1945). "Naphthoresorcinol". Org. Synth. 25: 73; Coll. Vol. 3: 637.
  7. ^ Brown, G. B. (1946). "Methylsuccinic acid". Org. Synth. 26: 54; Coll. Vol. 3: 615.
  8. ^ Ford, Jared H. (1947). "β-Alanine". Org. Synth. 27: 1; Coll. Vol. 3: 34.
  9. ^ Anslow, W. K.; King, H.; Orten, J. M.; Hill, R. M. (1925). "Glycine". Org. Synth. 4: 31; Coll. Vol. 1: 298.
  10. ^ Durham, L. J.; McLeod, D. J.; Cason, J. (1958). "Methyl hydrogen hendecanedioate". Org. Synth. 38:55; Coll. Vol. 4:635.
  11. ^ [1]
  12. ^ Thorpe, J. F.; Kon, G. A. R. (1925). "Cyclopentanone". Org. Synth. 5: 37; Coll. Vol. 1: 192.
  13. ^ Conant, J. B.; Tuttle, Niel. (1921). "Diacetone alcohol". Org. Synth. 1: 45; Coll. Vol. 1: 199.
  14. ^ Karabinos, J. V. (1956). "D-Gulonic γ-lactone". Org. Synth. 36: 38; Coll. Vol. 4: 506.
  15. ^ Pradyot Patnaik. Handbook of Inorganic Chemicals. McGraw-Hill, 2002, ISBN 0-07-049439-8
  16. ^ "Endothermic Reactions of Hydrated Barium Hydroxide and Ammonium Chloride". UC San Diego. Retrieved 2 April 2014. 
  17. ^ Endothermic Solid-Solid Reactions
  18. ^ a b Camp, Eric. "Endothermic Reaction". Univertist of Washington. Retrieved 2 April 2014. 
  19. ^ "Endothermic solid-solid reactions". Classic Chemistry Demonstrations. The Royal Society of Chemistry. Retrieved 2 April 2014. 

External links[edit]