|Molar mass||55.06 g/mol|
|Appearance||yellow or white powder|
2240 °C (decomp)
|Solubility in water||hydrolyzes|
|Crystal structure||Cubic, cI80, SpaceGroup = Ia-3, No. 106 (α form)|
| (what is: / ?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Beryllium nitride, Be3N2, is a nitride of beryllium. It can be prepared from the elements at high temperature (1100–1500 °C), different Beryllium azide or BeN6,it decomposes in vacuum into beryllium and nitrogen. It is readily hydrolysed forming beryllium hydroxide and ammonia. It has two polymorphic forms cubic α-Be3N2 with a defect anti-fluorite structure, and hexagonal β-Be3N2. It reacts with silicon nitride, Si3N4 in a stream of ammonia at 1800–1900°C to form BeSiN2.
Beryllium nitride is prepared by heating beryllium metal powder with dry nitrogen in an oxygen-free atmosphere in temperatures between 700 and 1400 °C.
Beryllium nitride reacts with mineral acids producing ammonia and the corresponding salts of the acids:
- Be3N2 + 6 HCl → 3 BeCl2 + 2 NH3
In strong alkali solutions, a beryllate forms, with evolution of ammonia:
- Be3N2 + 6 NaOH → 3 Na2BeO2 + 2 NH3
Both the acid and alkali reactions are brisk and vigorous. Reaction with water, however, is very slow:
- Be3N2 + 6 H2O → 3 Be(OH)2 + 2 NH3
Reactions with oxidizing agents are likely to be violent. It is oxidized when heated at 600°C in air.
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