|Jmol-3D images||Image 1
|Molar mass||25.01 g mol−1|
|Appearance||Colourless, vitreous crystals|
|Density||3.01 g cm−3|
|Melting point||2,507 °C (4,545 °F; 2,780 K)|
|Boiling point||3,900 °C (7,050 °F; 4,170 K)|
|Band gap||10.6 eV|
|Thermal conductivity||330 W K−1 m−1|
|Refractive index (nD)||1.7|
|13.73–13.81 J K−1 mol−1|
|Std enthalpy of
|–599 kJ mol−1|
|GHS signal word||DANGER|
|GHS hazard statements||H301, H315, H317, H319, H330, H335, H350, H372|
|GHS precautionary statements||P201, P260, P280, P284, P301+310, P305+351+338|
|R-phrases||R49, R25, R26, R36/37/38, R43, R48/23|
|LD50||2.062 mg kg−1 (mouse, oral)|
|Other anions||Beryllium telluride|
|Other cations||Magnesium oxide
|Supplementary data page|
|n, εr, etc.|
Solid, liquid, gas
|Spectral data||UV, IR, NMR, MS|
|Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)|
|(what is: / ?)|
Beryllium oxide (BeO), also known as beryllia, is an inorganic compound with the formula BeO. This colourless solid is a notable electrical insulator with a higher thermal conductivity than any other non-metal except diamond, and actually exceeds that of most metals. As an amorphous solid, beryllium oxide is white. Its high melting point leads to its use as a refractory. It occurs in nature as the mineral bromellite. Historically and in materials science, beryllium oxide was called glucina or glucinium oxide. Formation of BeO from beryllium and oxygen releases the highest energy per mass of reactants for any chemical reaction, close to 24MJ/kg.
Preparation and chemical properties
Beryllium oxide can be prepared by calcining (roasting) beryllium carbonate, dehydrating beryllium hydroxide or igniting the metal:
- BeCO3→ BeO + CO2
- Be(OH)2 → BeO + H2O
- 2 Be + O2 → 2 BeO
Beryllium oxide formed at high temperatures (>800 °C) is inert, but dissolves easily in hot aqueous ammonium bifluoride (NH4HF2) or a hot solution of concentrated sulfuric acid (H2SO4) and ammonium sulfate ((NH4)2SO4).
BeO crystallizes in the hexagonal wurtzite structure, featuring tetrahedral Be2+ and O2- centres, like lonsdaleite and w-BN (both of which it is isoelectronic with). In contrast, the oxides of the larger group 2 metals, i.e., MgO, CaO, SrO, BaO, crystallize in the cubic rock salt motif with octahedral geometry about the dications and dianions. At high temperature the structure transforms to a tetragonal form.
In the vapour phase, beryllium oxide is present as discrete diatomic molecules. In the language of valence bond theory, these molecules can be described as adopting sp orbital hybridisation, featuring two sigma and two pi bonds. The corresponding ground state is .. (2sσ)2(2sσ*)2(2pπ)4, where both degenerate π orbitals can be considered as dative bonds from oxygen towards beryllium.
High quality crystals may be grown hydrothermally, or otherwise by the Verneuil method. For the most part, beryllium oxide is produced as a white amorphous powder, sintered into larger shapes. Impurities like carbon, trapped with the crystals can give a variety of colours to the otherwise colourless host crystals.
Beryllium oxide is used in many high-performance semiconductor parts for applications such as radio equipment because it has good thermal conductivity while also being a good electrical insulator. It is used as a filler in some thermal interface materials such as thermal grease. Some power semiconductor devices have used beryllium oxide ceramic between the silicon chip and the metal mounting base of the package in order to achieve a lower value of thermal resistance than for a similar construction made with aluminium oxide. It is also used as a structural ceramic for high-performance microwave devices, vacuum tubes, magnetrons, and gas lasers.
BeO is carcinogenic and may cause chronic beryllium disease. Once fired into solid form, it is safe to handle as long as it is not subjected to any machining that generates dust. Beryllium oxide ceramic is not a hazardous waste under Federal law in the USA.
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- Zumdahl, Steven S. (2009). Chemical Principles 6th Ed. Houghton Mifflin Company. ISBN 0-618-94690-X.
- Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 0080379419.
- Raymond Aurelius Higgins (2006). Materials for Engineers and Technicians. Newnes. p. 301. ISBN 0-7506-6850-4.
- A.F. Wells (1984). Structural Inorganic Chemistry (5 ed.). Oxford Science Publications. ISBN 0-19-855370-6.
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- Günter Petzow, Fritz Aldinger, Sigurd Jönsson, Peter Welge, Vera van Kampen, Thomas Mensing, Thomas Brüning"Beryllium and Beryllium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry 2005, Wiley-VCH, Weinheim. doi:10.1002/14356007.a04_011.pub2
- Greg Becker, Chris Lee, and Zuchen Lin (2005). "Thermal conductivity in advanced chips — Emerging generation of thermal greases offers advantages". Advanced Packaging: 2–4. Retrieved 2008-03-04.[dead link]
- Beryllium Oxide Safety
- Beryllium Oxide MSDS from American Beryllia
- Beryllium Oxide Properties (solid form)
- IARC Monograph "Beryllium and Beryllium Compounds"
- International Chemical Safety Card 1325
- National Pollutant Inventory – Beryllium and compounds
- NIOSH Pocket guide to Chemical Hazards