Boron monoxide

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Boron monoxide
Identifiers
CAS number 12045-60-2 YesY
Properties
Molecular formula B2O
Molar mass 37.621 g/mol
Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
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Infobox references

Boron monoxide (B2O) is a chemical compound of boron and oxygen. Two experimental studies have proposed existence of diamond-like [1] and graphite-like [2] B2O, as for boron nitride and carbon solids. However, a later, systematic, experimental study of boron oxide phase diagram suggests that B2O is unstable.[3] The instability of the graphite-like B2O phase was also predicted theoretically.[4]

See also[edit]

References[edit]

  1. ^ Endo, T.; Sato, T.; Shimada, M. (1987). "High-pressure synthesis of B2O with diamond-like structure". Journal of Materials Science Letters 6 (6): 683. doi:10.1007/BF01770925. 
  2. ^ Hall, H. T.; Compton, L. A. (1965). "Group IV Analogs and High Pressure, High Temperature Synthesis of B2O". Inorganic Chemistry 4 (8): 1213. doi:10.1021/ic50030a027. 
  3. ^ Solozhenko, V. L.; Kurakevych, O. O.; Turkevich, V. Z.; Turkevich, D. V. (2008). "Phase Diagram of the B−B2O2 System at 5 GPa: Experimental and Theoretical Studies". Journal of Physical Chemistry B 112 (21): 6683–7. doi:10.1021/jp800625s. PMID 18457447. 
  4. ^ Grumbach, M.; Sankey, O.; McMillan, P. (1995). "Properties of B2O: An unsymmetrical analog of carbon". Physical Review B 52 (22): 15807. Bibcode:1995PhRvB..5215807G. doi:10.1103/PhysRevB.52.15807.