Glossary · History
In quantum mechanics, Bra–ket notation is a standard notation for describing quantum states, composed of angle brackets and vertical bars. It can also be used to denote abstract vectors and linear functionals in mathematics. It is so called because the inner product (or dot product on a complex vector space) of two states is denoted by a ⟨bra|c|ket⟩;
consisting of a left part, , called the bra (pron.: //), and a right part, , called the ket (pron.: //). The notation was introduced in 1939 by Paul Dirac and is also known as Dirac notation, though the notation has precursors in Grassmann's use of the notation for his inner products nearly 100 years previously.
Bra–ket notation is widespread in quantum mechanics: almost every phenomenon that is explained using quantum mechanics—including a large portion of modern physics — is usually explained with the help of bra–ket notation. The expression is typically interpreted as the probability amplitude for the state ψ to collapse into the state ϕ.
Vector spaces 
Background: Vector spaces 
In physics, basis vectors allow any Euclidean vector to be represented geometrically using angles and lengths, in different directions, i.e. in terms of the spatial orientations. It is simpler to see the notational equivalences between ordinary notation and bra–ket notation, so for now; consider a vector A as an element of 3-d Euclidean space using the field of real numbers, symbolically stated as .
The vector A can be written using any set of basis vectors and corresponding coordinate system. Informally basis vectors are like "building blocks of a vector", they are added together to make a vector, and the coordinates are the number of basis vectors in each direction. Two useful representations of a vector are simply a linear combination of basis vectors, and column matrices. Using the familiar Cartesian basis, a vector A is written;
respectively, where ex, ey, ez denotes the cartesian basis vectors (all are orthogonal unit vectors) and Ax, Ay, Az are the corresponding coordinates, in the x, y, z directions. In a more general notation, for any basis in 3d space we write;
Generalizing further, consider a vector A in an N dimensional vector space over the field of complex numbers , symbolically stated as . The vector A is still conventionally represented by a linear combination of basis vectors or a column matrix:
though the coordinates and vectors are now all complex-valued.
Even more generally, A can be a vector in a complex Hilbert space. Some Hilbert spaces, like , have finite dimension, while others have infinite dimension. In an infinite-dimensional space, the column-vector representation of A would be a list of infinitely many complex numbers.
Ket notation for vectors 
Rather than boldtype, over/under-arrows, underscores etc. conventionally used elsewhere; , Dirac's notation for a vector uses vertical bars and angular brackets; . When this notation is used, these vectors are called ket, read as "ket-A". This applies to all vectors, the resultant vector and the basis. The previous vectors are now written
or in a more easily generalized notation,
The last one may be written in short as
Notice how any symbols, letters, numbers, or even words — whatever serves as a convenient label — can be used as the label inside a ket. In other words, the symbol " " has a specific and universal mathematical meaning, but just the "A" by itself does not. Nevertheless, for convenience, there is usually some logical scheme behind the labels inside kets, such as the common practice of labeling energy eigenkets in quantum mechanics with a list of their quantum numbers.
Inner products and bras 
For example, in three-dimensional complex Euclidean space,
Bra–ket notation splits this inner product (also called a "bracket") into two pieces, the "bra" and the "ket":
where is called a bra, read as "bra-A", and is a ket as above.
The purpose of "splitting" the inner product into a bra and a ket is that both the bra and the ket are meaningful on their own, and can be used in other contexts besides within an inner product. There are two main ways to think about the meanings of separate bras and kets:
Bras and kets as row and column vectors 
Based on this, the bras and kets can be defined as:
and then it is understood that a bra next to a ket implies matrix multiplication.
The conjugate transpose (also called Hermitian conjugate) of a bra is the corresponding ket and vice-versa:
because if one starts with the bra
Bras as linear operators on kets 
A more abstract definition, which is equivalent but more easily generalized to infinite-dimensional spaces, is to say that bras are linear functionals on kets, i.e. operators that input a ket and output a complex number. The bra operators are defined to be consistent with the inner product.
Non-normalizable states and non-Hilbert spaces 
Bra–ket notation can be used even if the vector space is not a Hilbert space.
In quantum mechanics, it is common practice to write down kets which have infinite norm, i.e. non-normalisable wavefunctions. Examples include states whose wavefunctions are Dirac delta functions or infinite plane waves. These do not, technically, belong to the Hilbert space itself. However, the definition of "Hilbert space" can be broadened to accommodate these states (see the Gelfand–Naimark–Segal construction or rigged Hilbert spaces). The bra–ket notation continues to work in an analogous way in this broader context.
For a rigorous treatment of the Dirac inner product of non-normalizable states, see the definition given by D. Carfì in  and . For a rigorous definition of basis with a continuous set of indices and consequently for a rigorous definition of position and momentum basis, see . For a rigorous statement of the expansion of an S-diagonalizable operator, or observable, in its eigenbasis or in another basis, see .
Banach spaces are a different generalization of Hilbert spaces. In a Banach space B, the vectors may be notated by kets and the continuous linear functionals by bras. Over any vector space without topology, we may also notate the vectors by kets and the linear functionals by bras. In these more general contexts, the bracket does not have the meaning of an inner product, because the Riesz representation theorem does not apply.
Usage in quantum mechanics 
- Wave functions and other quantum states can be represented as vectors in a complex Hilbert space. (The exact structure of this Hilbert space depends on the situation.) In bra–ket notation, for example, an electron might be in "the state ". (Technically, the quantum states are rays of vectors in the Hilbert space, as corresponds to the same state for any nonzero complex number c.)
- Quantum superpositions can be described as vector sums of the constituent states. For example, an electron in the state is in a quantum superposition of the states and .
- Measurements are associated with linear operators (called observables) on the Hilbert space of quantum states.
- Dynamics is also described by linear operators on the Hilbert space. For example, in the Schrödinger picture, there is a linear time evolution operator U with the property that if an electron is in state right now, then in one second it will be in the state , the same U for every possible .
- Wave function normalization is scaling a wave function so that its norm is 1.
Since virtually every calculation in quantum mechanics involves vectors and linear operators, it can involve, and often does involve, bra–ket notation. A few examples follow:
Spinless position–space wave function 
The Hilbert space of a spin-0 point particle is spanned by a "position basis" , where the label r extends over the set of all points in position space. Since there are uncountably infinitely many vectors in the basis, this is an uncountably infinite-dimensional Hilbert space. The dimensions of the Hilbert space (usually infinite) and position space (usually 1, 2 or 3) are not to be conflated.
Starting from any ket in this Hilbert space, we can define a complex scalar function of r, known as a wavefunction:
On the left side, is a function mapping any point in space to a complex number; on the right side, is a ket.
It is then customary to define linear operators acting on wavefunctions in terms of linear operators acting on kets, by
For instance, the momentum operator p has the following form:
One occasionally encounters an expression like
though this is something of a (fairly common) abuse of notation. The differential operator must be understood to be an abstract operator, acting on kets, that has the effect of differentiating wavefunctions once the expression is projected into the position basis:
Overlap of states 
In quantum mechanics the expression is typically interpreted as the probability amplitude for the state to collapse into the state . Mathematically, this means the coefficient for the projection of onto .
Changing basis for a spin-1/2 particle 
where are complex numbers.
A different basis for the same Hilbert space is:
defined in terms of Sx rather than Sz.
Again, any state of the particle can be expressed as a linear combination of these two:
In vector form, you might write
depending on which basis you are using. In other words, the "coordinates" of a vector depend on the basis used.
There is a mathematical relationship between ; see change of basis.
Misleading uses 
There are a few conventions and abuses of notation that are generally accepted by the physics community, but which might confuse the non-initiated.
It is common among physicists to use the same symbol for labels and constants in the same equation. It supposedly becomes easier to identify that the constant is related to the labeled object, and is claimed that the divergent nature of each will eliminate any ambiguity and no further differentiation is required. For example: , where the symbol is used simultaneously as the name of the operator , its eigenvector and the associated eigenvalue .
Something similar occurs in component notation of vectors. While (uppercase) is traditionally associated with wavefunctions, (lowercase) may be used to denote a label, a wave function or complex constant in the same context, usually differentiated only by a subscript.
The main abuses are including operations inside the vector labels. This is usually done for a fast notation of scaling vectors. E.g. if the vector is scaled by , it might be denoted by , which makes no sense since is a label, not a function or a number, so you can't perform operations on it.
This is especially common when denoting vectors as tensor products, where part of the labels are moved outside the designed slot. E.g. . Here part of the labeling that should state that all three vectors are different was moved outside the kets, as subscripts 1 and 2. And a further abuse occurs, since is meant to refer to the norm of the first vector – which is a label is denoting a value.
Linear operators 
Linear operators acting on kets 
A linear operator is a map that inputs a ket and outputs a ket. (In order to be called "linear", it is required to have certain properties.) In other words, if A is a linear operator and is a ket, then is another ket.
Linear operators are ubiquitous in the theory of quantum mechanics. For example, observable physical quantities are represented by self-adjoint operators, such as energy or momentum, whereas transformative processes are represented by unitary linear operators such as rotation or the progression of time.
Linear operators acting on bras 
Operators can also be viewed as acting on bras from the right hand side. Specifically, if A is a linear operator and is a bra, then is another bra defined by the rule
If the same state vector appears on both bra and ket side,
then this expression gives the expectation value, or mean or average value, of the observable represented by operator A for the physical system in the state .
Outer products 
A convenient way to define linear operators on H is given by the outer product: if is a bra and is a ket, the outer product
denotes the rank-one operator that maps the ket to the ket (where is a scalar multiplying the vector ).
For a finite-dimensional vector space, the outer product can be understood as simple matrix multiplication:
The outer product is an N×N matrix, as expected for a linear operator.
Hermitian conjugate operator 
Just as kets and bras can be transformed into each other (making into ) the element from the dual space corresponding with is where A† denotes the Hermitian conjugate (or adjoint) of the operator A. In other words,
- if and only if .
If A is expressed as an N×N matrix, then A† is its conjugate transpose.
Self-adjoint operators, where A=A†, play an important role in quantum mechanics; for example, an observable is always described by a self-adjoint operator. If A is a self-adjoint operator, then is always a real number (not complex). This implies that expectation values of observables are real.
Bra–ket notation was designed to facilitate the formal manipulation of linear-algebraic expressions. Some of the properties that allow this manipulation are listed herein. In what follows, c1 and c2 denote arbitrary complex numbers, c* denotes the complex conjugate of c, A and B denote arbitrary linear operators, and these properties are to hold for any choice of bras and kets.
- Since bras are linear functionals,
Given any expression involving complex numbers, bras, kets, inner products, outer products, and/or linear operators (but not addition), written in bra–ket notation, the parenthetical groupings do not matter (i.e., the associative property holds). For example:
and so forth. The expressions on the right (with no parentheses whatsoever) are allowed to be written unambiguously because of the equalities on the left. Note that the associative property does not hold for expressions that include non-linear operators, such as the antilinear time reversal operator in physics.
Hermitian conjugation 
Bra–ket notation makes it particularly easy to compute the Hermitian conjugate (also called dagger, and denoted †) of expressions. The formal rules are:
- The Hermitian conjugate of a bra is the corresponding ket, and vice-versa.
- The Hermitian conjugate of a complex number is its complex conjugate.
- The Hermitian conjugate of the Hermitian conjugate of anything (linear operators, bras, kets, numbers) is itself—i.e.,
- Given any combination of complex numbers, bras, kets, inner products, outer products, and/or linear operators, written in bra–ket notation, its Hermitian conjugate can be computed by reversing the order of the components, and taking the Hermitian conjugate of each.
These rules are sufficient to formally write the Hermitian conjugate of any such expression; some examples are as follows:
- Inner products:
- Matrix elements:
- Outer products:
Composite bras and kets 
Two Hilbert spaces V and W may form a third space by a tensor product. In quantum mechanics, this is used for describing composite systems. If a system is composed of two subsystems described in V and W respectively, then the Hilbert space of the entire system is the tensor product of the two spaces. (The exception to this is if the subsystems are actually identical particles. In that case, the situation is a little more complicated.)
If is a ket in V and is a ket in W, the direct product of the two kets is a ket in . This is written in various notations:
The unit operator 
with the inner product on the Hilbert space. From the commutativity of kets with (complex) scalars now follows that
must be the unit operator, which sends each vector to itself. This can be inserted in any expression without affecting its value, for example
where in the last identity Einstein summation convention has been used.
In quantum mechanics it often occurs that little or no information about the inner product of two arbitrary (state) kets is present, while it is possible to say something about the expansion coefficients and of those vectors with respect to a chosen (orthonormalized) basis. In this case it is particularly useful to insert the unit operator into the bracket one time or more (for more information see Resolution of the identity, 1 = ∫dx |x⟩⟨x | = ∫dp |p⟩⟨p | , where |p⟩=∫dx eixp |x⟩/√2πħ).
Notation used by mathematicians 
Let be a Hilbert space and is a vector in . What physicists would denote as is the vector itself. That is
Let be the dual space of . This is the space of linear functionals on . The isomorphism is defined by where for all we have
where and are just different notations for expressing an inner product between two elements in a Hilbert space (or for the first three, in any inner product space). Notational confusion arises when identifying and with and respectively. This is because of literal symbolic substitutions. Let and let . This gives
One ignores the parentheses and removes the double bars. Some properties of this notation are convenient since we are dealing with linear operators and composition acts like a ring multiplication.
Moreover, mathematicians usually write the dual entity not at the first place, as the physicists do, but at the second one, and they don't use the *-symbol, but an overline (which the physicists reserve for averages) to denote conjugate-complex numbers, i.e. for scalar products mathematicians usually write
whereas physicists would write for the same quantity
References and notes 
- PAM Dirac (1939). "A new notation for quantum mechanics". Mathematical Proceedings of the Cambridge Philosophical Society 35 (3). pp. 416–418. doi:10.1017/S0305004100021162.
- H. Grassmann (1862). Extension Theory. History of Mathematics Sources. American Mathematical Society, London Mathematical Society, 2000 translation by Lloyd C. Kannenberg.
- Quantum Mechanics Demystified, D. McMahon, Mc Graw Hill (USA), 2006, ISBN(10-) 0-07-145546 9
- Carfì, David (April 2003). "Dirac-orthogonality in the space of tempered distributions". Journal of Computational and Applied Mathematics 153 (1–2): 99–107. Bibcode:2003JCoAM.153...99C. doi:10.1016/S0377-0427(02)00634-9.
- Carfì, David (April 2003). "Some properties of a new product in the space of tempered distributions". Journal of Computational and Applied Mathematics 153 (1–2): 109–118. Bibcode:2003JCoAM.153..109C. doi:10.1016/S0377-0427(02)00635-0.
- Carfì, David (2007). "TOPOLOGICAL CHARACTERIZATIONS OF S-LINEARITY". AAPP-PHYSICAL, MATHEMATICAL AND NATURAL SCIENCES 85 (2): 1–16. doi:10.1478/C1A0702005.
- Carfì, David (2005). "S-DIAGONALIZABLE OPERATORS IN QUANTUM MECHANICS". Glasnik Matematicki 40 (2): 261–301. doi:10.3336/gm.40.2.08.
- Lecture notes by Robert Littlejohn, eqns 12 and 13
Further reading 
- Feynman, Leighton and Sands (1965). The Feynman Lectures on Physics Vol. III. Addison-Wesley. ISBN 0-201-02115-3.
- Richard Fitzpatrick, "Quantum Mechanics: A graduate level course", The University of Texas at Austin.
- Robert Littlejohn, Lecture notes on "The Mathematical Formalism of Quantum mechanics", including bra–ket notation.