In the 2013 AFL season Hill switched to the number 10 guernsey and cemented his spot in the starting line-up, playing 24 out of 25 games and kicking 18 goals. The performance that won him a 2013 AFL Rising Star nomination was his 17 disposal and two goal effort in Hawthorn’s thrilling win against the Crows at AAMI Stadium in round 6.
The Hill brothers became the first siblings to play against each other in a Grand Final since the 1912 VFL Grand Final, when Fremantle faced Minor Premiers Hawthorn in the 2013 AFL Grand Final at the M.C.G. in front of 100,007 people. In the first quarter Hill passed the ball from the boundary to Jack Gunston in front of goals, which then provided Hawthorn with the first goal of the game. He then repeated the trick in the 3rd quarter when Gunston pounced upon the spilt ball to spin around and kick his 4th goal to re-establish Hawthorn's lead going into the final stanza. Hill also kicked the sealer halfway through the final quarter, running into an open goal to ensure Paul Puopolo's bouncing kick went through, thus giving Hawthorn a 5 goal lead which Fremantle could not overcome.