2, see Bromite.
|Jmol-3D images||Image 1|
|Molar mass||111.903 g/mol|
|Appearance||unstable yellow crystals|
|Melting point||decomposes around 0°C|
|Other anions||Bromine monoxide
|Other cations||Oxygen difluoride
|Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)|
|(what is: / ?)|
Bromine dioxide is the chemical compound composed of bromine and oxygen with the formula BrO2. It forms unstable yellow to yellow-orange crystals. It was first isolated by R. Schwarz and M. Schmeißer in 1937 and is hypothesized to be important in the atmospheric reaction of bromine with ozone. It is similar to chlorine dioxide, the dioxide of its halogen neighbor one period higher on the periodic table.
Bromine dioxide is formed when an electrical current is passed through a mixture of bromine and oxygen gases at low temperature and pressure.
- Perry, Dale L.; Phillips, Sidney L. (1995), Handbook of Inorganic Compounds, CRC Press, p. 74, ISBN 0-8493-8671-3, retrieved 17 March 2009
- Lide, David R. (1998), Handbook of Chemistry and Physics (87 ed.), Boca Raton, FL: CRC Press, p. 447, ISBN 0-8493-0594-2
- Muller, Holger S.P.; Charles E. Miller, Edward A. Cohen (November 22, 1997), "Rotational spectrum and molecular properties of bromine dioxide, OBrO", Journal of Chemical Physics 107 (20): 82–92, doi:10.1063/1.475030, ISSN 0021-9606, retrieved 17 March 2009
- Arora, M.G. (1997), P-Block Elements, New Delhi: Anmol Publications, p. 256, ISBN 978-81-7488-563-0, retrieved 17 March 2009
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