Bromo(tetrahydrothiophene)gold(I)

From Wikipedia, the free encyclopedia
Jump to: navigation, search
Bromo(tetrahydrothiophene)gold(I)
Bromo(tetrahydrothiophene)gold(I).svg
Identifiers
CAS number 39929-22-1 YesY
Jmol-3D images Image 1
Properties
Molecular formula C4H8AuBrS
Molar mass 365.04 g mol−1
Related compounds
Related compounds chloro(tetrahydrothiophene)gold(I), chloro(dimethyl sulfide)gold(I)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
 YesY (verify) (what is: YesY/N?)
Infobox references

Bromo(tetrahydrothiophene)gold(I) is a coordination complex of gold. It is related to the more commonly used chloro(tetrahydrothiophene)gold(I). Similarly, the tetrahydrothiophene ligand is labile and is readily substituted with other stronger ligands, to give linear gold bromide complexes.

This compound may be prepared by reaction of tetrabromoauric acid (formed from tetrachloroauric acid and hydrobromic acid) with tetrahydrothiophene.[1]

References[edit]

  1. ^ Eiter, Lauren C.; Hall, Nathan W.; Day, Cynthia S.; Saluta, Gilda; Kucera, Gregory L.; Bierbach, Ulrich (2009). "Gold(I) Analogues of a Platinum–Acridine Antitumor Agent are only Moderately Cytotoxic but Show Potent Activity Against Mycobacterium Tuberculosis". Journal of Medicinal Chemistry 52 (21): 6519–22. doi:10.1021/jm9012856. PMC 3176588. PMID 19803526.