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| Butanethiol | |
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Butane-1-thiol |
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Other names
Butyl mercaptan |
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| Identifiers | |
| CAS number | 109-79-5  |
| PubChem | 8012 |
| ChemSpider | 7721 |
| UNII | 77OY909F30 |
| Jmol-3D images | Image 1 |
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| Properties | |
| Molecular formula | C4H10S |
| Molar mass | 90.19 g mol−1 |
| Appearance | Nauseating clear liquid |
| Density | 0.83679 g/mL |
| Melting point |
-115.8 °C, 157 K, -176 °F |
| Boiling point |
98.2 °C, 371 K, 209 °F |
| Solubility in water | Slightly soluble |
| Hazards | |
| NFPA 704 |
 3
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0
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 (verify) (what is:  / ?)Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) |
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| Infobox references | |
Butanethiol, also known as butyl mercaptan, is a volatile, clear to yellowish liquid with a fetid (extremely foul-smelling) odor, commonly described as "skunk" odor. In fact, butanethiol is structurally similar to several major constituents of a skunk's defensive spray. The scent of butanethiol is so strong that the human nose can easily detect it in the air at concentrations as low as 10 parts per billion.
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[edit] Chemistry
Butanethiol is chemically classified among the thiols, which are organic compounds with molecular formulas and structural formulas similar to alcohols, except that sulfur-containing sulfhydryl group (-SH) replaces the oxygen-containing hydroxyl group in the molecule. Butanethiol's basic molecular formula is C4H9SH, and its structural formula is similar to that of the alcohol n-butanol. Butanethiol is a thiol of low molecular weight, and it is highly flammable.
[edit] Uses
Butanethiol is used as an industrial solvent, as an odorant for natural gas (which is odorless), and as an intermediate for insecticides and herbicides. It is sometimes placed in the "stink bombs" and "stink perfumes" for pranksters.
[edit] Safety
Butanethiol is a very noxious and caustic chemical compound, and at sufficiently high concentrations, it produces serious health effects in both humans and animals, especially as a result of prolonged exposure. Higher concentrations can lead to unconsciousness and coma after prolonged exposure. Contact with the skin and mucous membranes causes burns, and contact with the eyes can lead to blurred vision or complete blindness.[citation needed]
Inhalation may cause weakness, confusion, cough, dizziness, drowsiness, headache, nausea, vomiting, and shortness of breath. The substance irritates the eyes, the skin, and the respiratory tract. It may cause effects on the thyroid and the nervous system and could cause lowering of consciousness.[1]
[edit] See also
- tert-Butylthiol (tert-butyl mercaptan)
[edit] Notes
- ^ "n-BUTYL MERCAPTAN". International Chemical Safety Cards. National Institute for Occupational Safety and Health. http://www.cdc.gov/niosh/ipcsneng/neng0018.html. Retrieved January 11, 2012.
