Cacodyl oxide

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Cacodyl oxide
Identifiers
CAS number 503-80-0
Jmol-3D images Image 1
Properties
Molecular formula C4H12As2O
Molar mass 255.98 g/mol
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Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Cacodyl oxide is a chemical compound of the formula [(CH3)2As]2O. This organoarsenic compound is primarily of historical significance as it is sometimes considered to be the first organometallic compound synthesized in relatively pure form.[1][2]

"Cadet's fuming liquid", which is composed of cacodyl and cacodyl oxide, was originally synthesized by heating sodium acetate with arsenic trioxide. It has a disagreeable odor and is toxic. It has been used as a denaturing and warning agent.[citation needed]

[edit] See also

[edit] References

  1. ^ Elschenbroich, C. ”Organometallics” (2006) Wiley-VCH: Weinheim. ISBN 978-3-29390-6
  2. ^ Seyferth, Dietmar (2001). "Cadet's Fuming Arsenical Liquid and the Cacodyl Compounds of Bunsen". Organometallics 20 (8): 1488–1498. doi:10.1021/om0101947. http://pubs.acs.org/cgi-bin/abstract.cgi/orgnd7/2001/20/i08/abs/om0101947.html. 
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