Cadmium telluride photovoltaics
Cadmium telluride (CdTe) photovoltaics describes a photovoltaic (PV) technology that is based on the use of cadmium telluride, a thin semiconductor layer designed to absorb and convert sunlight into electricity. Cadmium telluride PV is the only thin film technology with lower costs than conventional solar cells made of crystalline silicon in multi-kilowatt systems.
CdTe PV is a solution to key ecological issues including climate change, energy security, and water scarcity, across a range of application scenarios (e.g. commercial rooftop applications or large scale ground mount applications).
On a lifecycle basis, CdTe PV has the smallest carbon footprint, lowest water use and shortest energy payback time of all solar technologies. CdTe's short energy payback time of less than a year enables for faster carbon reductions without short-term energy deficits. With about 5 percent of worldwide PV production, CdTe technology accounted for more than half of the thin film market in 2013. A prominent manufacturer of CdTe thin film technology is the company First Solar, based in Tempe, Arizona.
- 1 Background
- 2 History
- 3 Technology
- 4 Market viability
- 5 See also
- 6 References and notes
- 7 Further reading
The dominant PV technology has always been based on crystalline silicon wafers. Thin films and concentrators were early attempts to lower costs. Thin films are based on using thinner semiconductor layers to absorb and convert sunlight. Concentrators lower the number of panels by using lenses or mirrors to put more sunlight on each panel.
The first thin film technology to be extensively developed was amorphous silicon. However, this technology suffers from low efficiencies and slow deposition rates (leading to high capital costs). Instead, the PV market reached some 4 gigawatts in 2007 with crystalline silicon comprising almost 90% of sales. The same source estimated that about 3 gigawatts were installed in 2007.
During this period cadmium telluride and copper indium diselenide or CIS-alloys remained under development. The latter is beginning to be produced in volumes of 1–30 megawatts per year due to very high, small-area cell efficiencies approaching 20% in the laboratory. CdTe cell efficiency is approaching 20% in the laboratory with a record of 19.6% as of 2013.
Research in CdTe dates back to the 1950s, after its band gap (~1.5 eV) almost perfectly matched to the distribution of photons in the solar spectrum in terms of conversion to electricity. A simple heterojunction design evolved in which p-type CdTe was matched with n-type cadmium sulfide (CdS). The cell was completed by adding top and bottom contacts. Early leaders in CdS/CdTe cell efficiencies were GE in the 1960s, and then Kodak, Monosolar, Matsushita, and AMETEK.
By 1981, Kodak used close spaced sublimation (CSS) and made the first 10% cells and first multi-cell devices (12 cells, 8% efficiency, 30 cm2). Monosolar and AMETEK used electrodeposition, a popular early method. Matsushita started with screen printing but shifted in the 1990s to CSS. Cells of about 10% sunlight-to-electricity efficiency were produced by the early 1980s at Kodak, Matsushita, Monosolar and AMETEK.
An important step forward occurred when cells were scaled-up in size to make larger area products called modules. These products required higher currents than small cells and it was found that an additional layer, called a transparent conducting oxide (TCO), could facilitate the movement of current across the top of the cell (instead of a metal grid). One such TCO, tin oxide, was available for other uses (thermally reflective windows). Made more conductive for PV, tin oxide became and remains the norm in CdTe PV modules.
CdTe cells achieved above 15% in 1992 by adding a buffer layer to the TCO/CdS/CdTe stack and then thinned the CdS to admit more light. Chu used resistive tin oxide as the buffer layer and then thinned the CdS from several micrometres to under half a micrometre in thickness. Thick CdS, as it was used in prior devices, blocked about 5 mA/cm2 of light, or about 20% of the light usable by a CdTe device. The additional layer did not compromise the device's other properties.
In the early 1990s, other players experienced mixed results. Golden Photon held the record for a short period for the best CdTe module measured at NREL at 7.7% using a spray deposition technique. Matsushita claimed an 11% module efficiency using CSS and then dropped the technology. A similar efficiency and fate eventually occurred at BP Solar. BP used electrodeposition (inherited from Monosolar by a circuitous route when it purchased SOHIO, Monosolar's acquirer). BP Solar dropped CdTe in the early 2000s. Antec was able to make about 7%-efficient modules, but went bankrupt when it started producing commercially during a short, sharp market downturn in 2002. However, as of 2014 Antec still made CdTe PV modules.
CdTe start-ups include Q-Cells' Calyxo (Germany), GE’s PrimeStar Solar (Arvada, Colorado), Arendi (Italy), and Abound Solar (Fort Collins, Colorado). Including Antec, their total production represents less than 70 megawatts per year.
In 2009, EMPA, the Swiss Federal Laboratories for Materials Testing and Research, demonstrated a 12.4% efficient solar cell on flexible polyimide substrate.
SCI and First Solar
The major commercial success was Solar Cells Incorporated (SCI). It switched from amorphous silicon to CdTe as a better alternative to the higher-cost silicon. McMaster championed CdTe for its high-rate, high-throughput processing. SCI shifted from an adaptation of the CSS method then shifted to vapor transport. In February 1999, McMaster sold the company to True North Partners, who named it First Solar.
In its early years First Solar suffered setbacks, and initial module efficiencies were modest, about 7%. Commercial product became available in 2002. Production reached 25 megawatts in 2005. The company manufactured in Perrysburg, Ohio and Germany.
In 2013, First Solar acquired GE's thin film solar panel technology in exchange for a 1.8% stake in the company.
Recently, First Solar announced in February 2014, a device with 20.4% efficiency. In 2014, the record module efficiency was also from First Solar, at 17.0%, up from 16.1%. By 2017, the company projected average production line module efficiency for its CdTe PV to be 17%. Since CdTe has the optimal band gap for single-junction devices, efficiencies close to 20% (such as already shown in CIS alloys) may be achievable in practical CdTe cells.
Process optimization improved throughput and lowered costs. Improvements included broader substrates (since capital costs scale sublinearly and installation costs can be reduced), thinner layers (to save material, electricity, and processing time), and better material utilization (to save material and cleaning costs). 2014 CdTe module costs are about $72 square metres (780 sq ft).
Module efficiencies are measured in laboratories at standard testing temperatures of 25 °C, however in the field modules are often exposed to much higher temperatures. CdTe’s relatively low temperature coefficient protects performance at higher temperatures. CdTe PV modules experience half the reduction of crystalline silicon modules, resulting in an increased annual energy output of 5-9%.
Almost all thin film photovoltaic module systems to-date have been non-solar tracking, because module output was too low to offset tracker capital and operating costs. But relatively inexpensive single-axis tracking systems can add 25% output per installed watt. In addition, depending on the Tracker Energy Gain, the overall eco-efficiency of the PV system can be enhanced by lowering both system costs and environmental impacts. This is climate-dependent. Tracking also produces a smoother output plateau around midday, better matching afternoon peaks.
Cadmium, a heavy metal considered a hazardous substance, is a waste byproduct of zinc refining therefore its production does not depend on PV market demand. CdTe PV modules provide a beneficial and safe use for cadmium that would otherwise be stored for future use or disposed of in landfills as hazardous waste. Mining byproducts can be converted into a stable CdTe compound and safely encapsulated inside CdTe PV solar modules for years. A large growth in the CdTe PV sector has the potential to reduce global cadmium emissions by displacing coal and oil power generation.
Tellurium (Te) production and reserves estimates are subject to uncertainty and vary considerably. Tellurium is primarily used as a machining additive to steel. Te is almost exclusively obtained as a by-product of copper refining, with smaller amounts from lead and gold production. Only a small amount, estimated to be about 800 metric tons per year, is available. According to USGS, global production in 2007 was 135 metric tons. One gigawatt (GW) of CdTe PV modules would require about 93 metric tons (at current efficiencies and thicknesses). Through improved material efficiency and increased PV recycling, the CdTe PV industry has the potential to fully rely on tellurium from recycled end-of-life modules by 2038. In the last decade[when?], new supplies have been located, e.g., in Xinju, China as well as in Mexico and Sweden. In 1984 astrophysicists identified tellurium as the universe's most abundant element having an atomic number over 40. Certain undersea ridges are rich in tellurium.
Cadmium chloride/magnesium chloride
The manufacture of a CdTe cell includes a thin coating with cadmium chloride (CdCl
2) to increase the cell's overall efficiency. Cadmium chloride is toxic, relatively expensive and highly soluble in water, posing a potential environmental threat during manufacture. In 2014 research discovered that abundant and harmless magnesium chloride (MgCl
2) performs as well as cadmium chloride. This research may lead to cheaper and safer CdTe cells.
The glass plates surrounding CdTe material sandwiched between them (as in all commercial modules) seal during a fire and do not allow any cadmium release. All other uses and exposures related to cadmium are minor and similar in kind and magnitude to exposures from other materials in the broader PV value chain, e.g., to toxic gases, lead solder, or solvents (most of which are not used in CdTe manufacturing).
As of 2009 over 100 GW of solar PV modules had been installed worldwide. First Solar established the first global and comprehensive recycling program in the PV industry. Its recycling facilities operate at each of First Solar’s manufacturing plants and recover up to 95% of semiconductor material for reuse in new modules and 90% of glass for reuse in new glass products.
Success of cadmium telluride PV has been due to the low cost achievable with the CdTe technology, made possible by combining adequate efficiency with lower module area costs. Direct manufacturing cost for CdTe PV modules reached $0.57 per watt in 2013, and capital cost per new watt of capacity is near $0.9 per watt (including land and buildings).
Utility-scale CdTe PV solutions were claimed to be able to compete with peaking fossil fuel generation sources depending on irradiance levels, interest rates and other factors such as development costs. Recent installations of large First Solar CdTe PV systems were claimeed to be competitive with other forms of solar energy:
- First Solar’s 290 MW Agua Caliente project in Arizona is the world’s largest PV plant. Agua Caliente features First Solar’s plant control, forecasting and energy scheduling capabilities that contribute to grid reliability and stability.
- The 550-MW Topaz Solar Farm under construction in California represents the world’s largest renewable energy bond.
- First Solar’s 13 MW project in Dubai, operated by the Dubai Electricity and Water Authority, is the largest PV power plant in the region.
- A 40MW system installed by Juwi group in Waldpolenz Solar Park, Germany, at the time of its announcement, was the world's largest and lowest cost planned PV system. The price was 3.25 euros.
- A 21-megawatt system installed in Blythe, CA, used a 12 US cent per kWh power purchase agreement (after the application of all incentives). Defined in California as the "Market Referent Price," this set the price the PUC would pay for any daytime peaking power source, e.g., natural gas. Although PV systems are intermittent and not dispatchable the way natural gas is, natural gas generators have an ongoing fuel price risk that PV does not have.
- A contract for two megawatts of rooftop installations with Southern California Edison. The SCE program is designed to install 250 megawatts at a total cost of $875M (averaging $3.5/watt), after incentives.
References and notes
- "Publications, Presentations, and News Database: Cadmium Telluride". National Renewable Energy Laboratory.
- K. Zweibel, J. Mason, V. Fthenakis, "A Solar Grand Plan", Scientific American, Jan 2008. CdTe PV is the cheapest example of PV technologies and prices are about 16¢/kWh with US Southwest sunlight.
- Further mention of cost competitiveness: "Solar Power Lightens Up with Thin-Film Technology", Scientific American, April 2008.
- Mariska de Wild-Scholten and Martin Schottler (24 April 2009). "Solar as an environmental product: Thin-film modules – production processes and their environmental assessment". Presented at Thin Film Industry Forum. ECN and M+W Zander FE GmbH.
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- de Wild-Scholten, Mariska (2013). "Energy payback time and carbon footprint of commercial photovoltaic systems". Solar Energy Materials & Solar Cells 119: 296–305. doi:10.1016/j.solmat.2013.08.037.
- Fraunhofer ISE Photovoltaics Report, July 28, 2014, pages 18,19
- Various estimates of world module production in 2007
- 19.9% CIGS cell made at NREL:
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- D. A. Jenny and R. H. Bube (1954). "Semiconducting CdTe". Phys. Rev. 96 (5): 1190. doi:10.1103/PhysRev.96.1190.
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- D. A. Cusano (1963). "CdTe Solar Cells and PV Heterojunctions in II-VI Compounds". Solid State Electronics 6 (3): 217. doi:10.1016/0038-1101(63)90078-9.
- B. Goldstein (1958). "Properties of PV Films of CdTe". Phys. Rev 109 (2): 601. doi:10.1103/PhysRev.109.601.2.
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- R. Colman, July 28, 1964 U.S. Patent 3,142,586
- Y. S. Tyan, 1978, Polycrystalline thin film CdS/CdTe photovoltaic cell, Kodak, U.S. Patent 4,207,119 (EP0006025); Y. S. Tyan and E. A. Perez-Albuerne, 1982, Integrated array of photovoltaic cells having minimized shorting losses, Kodak, U.S. Patent 4,315,096. Tyan especially published both patents and papers of significance at Kodak and helped to establish CdTe as an important thin film option.
- B. Basol, E. Tseng, R.L. Rod, 1981, Thin film heterojunction photovoltaic cells and methods of making the same, Monosolar U.S. Patent 4,388,483. B. Basol patented numerous aspects of electrodeposition and CdTe contacting for Monosolar. Monosolar was subsequently bought by SOHIO, which was then absorbed by British Petroleum. Electrodeposition continued at BP Solar until about 2002 when it was canceled along with all thin film work at BP.
- Peter Meyers, originally of Ametek, provides a thread stretching from Ametek through Solar Cells Inc. to First Solar. He is on Ametek patents U.S. Patent 4,260,427, 1981; U.S. Patent 4,710,589, 1987; and SCI/First Solar patents
- K. Zweibel (1995). "Thin Films Past Present and Future". Nrel/tp-413-7486.R. Noufi and K. Zweibel (2006). High-Efficiency CdTe and CIGS Thin-Film Solar Cells: Highlights and Challenges. National Renewable Energy Laboratory, Golden, CO 80401, USA.
- "While First Solar keeps on trucking, others in CdTe thin-film PV pack keep on muddling". Fabtech.org. 2008-08-21. \
- Flexible CdTe thin-film solar cells reach efficiency of 12.4% http://www.worldofrenewables.com/renewables_news/photovoltaics/thin_film_pv/flexible_cdte_thin-film_solar_cells_reach_efficiency_of_12_4.html
- Harold McMaster envisioned the opportunity for low-cost thin films made on a large scale. After trying amorphous silicon, he shifted to CdTe at the urging of Jim Nolan and founded Solar Cells inc., the precursor of First Solar; After long wait, McMaster to join hall of fame, April 29, 2008
- SCI CSS patent: Foote et al. Process for making photovoltaic devices and resultant product, United States Patent 5248349; and their vapor transport patent, featuring the movement of vaporized cadmium and tellurium atoms through a closed, silicon carbide distributor: Apparatus and method for depositing a semiconductor material, United States Patent 6037241. Both are now owned by First Solar.
- D. H. Rose et al. (October 1999). Technology Support of High-Throughput Processing of Thin Film CdTe Panels. NREL SR-520-27149. p. Viii (preface).
- "First Solar annual manufacturing levels". FirstSolar.com. 2008.
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- First Solar Gives GE 1.8% Stake in Thin-Film Partnership. bloomberg.com. 2013-08-07
- Sinha, P. (2013). "Life cycle materials and water management for CdTe photovoltaics". Solar Energy Materials & Solar Cells 119: 271–275. doi:10.1016/j.solmat.2013.08.022.
- M. Gloeckler, I. Sankin, Z. Zhao (2013). "CdTe Solar Cells at the Threshold to 20%". IEEE Journal of Photovoltaics 3 (4): 1389–1393. doi:10.1109/jphotov.2013.2278661.
- This number is calculated by multiplying efficiency (12.6%) by 1000 to get output watts per square meter (126 W/m2), and then multiplying power by the stated cost of $0.57 per watt to get $72/m2
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- P. Sinha and S. Dailey (November 2013). "Tracking systems boost eco-efficiency". Solar Industry.
- M. Raugei and V. Fthenakis (2010). "Cadmium flows and emissions from CdTe PV: future expectations". Energy Policy: 5223–5228. doi:10.1016/j.enpol.2010.05.007.
- "Assessment of critical thin film resources" (.doc file).
- "Tellurium". Mineral Commodity Summaries. United States Geological Survey. January 2008.
- Max Marwede and Armin Reller (2012). "Future recycling flows of tellurium from cadmium telluride photovoltaic waste". Resources, Conservation, & Recycling 69: 35–49. doi:10.1016/j.resconrec.2012.09.003. PMID 19636069.
- Publications of the Sichuan Xinju Mineral Resource Development Co., China
- Zweibel, K. (2010). "The Impact of Tellurium Supply on Cadmium Telluride Photovoltaics". Science 328 (5979): 699–701. doi:10.1126/science.1189690. PMID 20448173.
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- J. Hein (2004). "Chapter 5 from Workshop on Minerals other than Polymetallic Nodules of the International Seabed Area". Cobalt-Rich Ferromanganese Crusts: Global Distribution, Composition, Origin and Research Activities. Kingston, Jamaica: Office of Resource and Environmental Monitoring, International Seabed Authority. ISBN 976-610-647-9. "It has been suggested that Te is unique in the universe in that its cosmic abundance is as great or greater than any of other element with an atomic number higher than 40 (http://www.webelements.com), yet it is one of the least abundant elements in the Earth’s crust and in ocean water.""
- J. Hein, A. Koschinsky, and A. Halliday (2003). "Global Occurrence of tellurium-rich ferromanganese crusts and a model for enrichment of tellurium". Geochimica et Cosmochimica Acta 67: 1117–1127. doi:10.1016/S0016-7037(00)01279-6. "The ridges occur at 400-4000 m depths where currents have kept the rocks swept clean of sediments for millions of years. Crusts…forming pavements up to 250 mm thick"
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- V. Fthenakis, M. Fuhrmann, J. Heiser, W. Wang (2004). "Experimental Investigation of Emissions and Redistribution of Elements in CdTe PV Modules during Fires.". 19th European PV Solar Energy Conference. Paris, France.
- Beckmann and Mennenga (2011). Calculation of emissions when there is a fire in a photovoltaic system made of cadmium telluride modules. Bavarian Environmental Protection Agency.
- V. Fthenakis, H. C. Kim (2006). "CdTe Photovoltaics: Life Cycle Environmental Profile and Comparisons". European Material Research Society Meeting, Symposium for environmental issues.
- D. H. Rose et al. (1999). Technology Support of High-Throughput Processing of Thin Film CdTe Panels. NREL.
- Held, M. Held (2009). "Life Cycle Assessment of CdTe Module Recycling". 24th EU PVSEC Conference. Hamburg, Germany.
- Pacific Crest Presentation, August 3–5, 2008
- "Grid-connected bulk power systems". website. First Solar.
- "Agua Caliente". First Solar.
- "Projects". First Solar.
- PDF (401 KB)
- "First Solar announces two solar projects with Southern California Edison". Semiconductor-Today.com. 2008-07-17.
- "California Utility to Install 250MW of Roof-Top Solar". SustainableBusiness.com. 2008-03-27.
- V. Fthenakis, H. C. Kim, 2007, "CdTe photovoltaics: Life cycle environmental profile and comparisons," Thin Solid Films, Volume 515, Issue 15, 31 May 2007, Pages 5961-5963, doi:10.1016/j.tsf.2006.12.138; article at http://www.clca.columbia.edu/papers/CdTe_Photovoltaics_Life_Cycle_Environmental_Profile.pdf
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