Isotopes of californium
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(Redirected from Californium-252)
| Actinides | Half-life | Fission products | ||||||
|---|---|---|---|---|---|---|---|---|
| 244Cm | 241Pu f | 250Cf | 243Cmf | 10–30 y | 137Cs | 90Sr | 85Kr | |
| 232U f | 238Pu | f is for fissile |
69–90 y | 151Sm nc➔ | ||||
| 4n | 249Cf f | 242Amf | 141–351 | No fission product has half-life 102 to 2×105 years |
||||
| 241Am | 251Cf f | 431–898 | ||||||
| 240Pu | 229Th | 246Cm | 243Am | 5–7 ky | ||||
| 4n | 245Cmf | 250Cm | 239Pu f | 8–24 ky | ||||
| 233U f | 230Th | 231Pa | 32–160 | |||||
| 4n+1 | 234U | 4n+3 | 211–290 | 99Tc | 126Sn | 79Se | ||
| 248Cm | 242Pu | 340–373 | Long-lived fission products | |||||
| 237Np | 4n+2 | 1–2 My | 93Zr | 135Cs nc➔ | ||||
| 236U | 4n+1 | 247Cmf | 6–23 My | 107Pd | 129I | |||
| 244Pu | 80 My | >7% | >5% | >1% | >.1% | |||
| 232Th | 238U | 235U f | 0.7–12 Gy | fission product yield | ||||
Californium (Cf) is a chemical element that is mainly produced synthetically, but trace quantities are found in nature from neutron capture by uranium atoms.[1]
It has no stable isotopes. The first isotope to be synthesized was 245Cf in 1950. There are 20 known radioisotopes ranging from 237Cf to 256Cf and one nuclear isomer, 249mCf. The longest-lived isotope is 251Cf with a half-life of 900 years.
Contents |
[edit] Californium-252
Fission neutrons of californium-252 have an energy range of 0 to 13 MeV with a mean value of 2.3 MeV and a most probable value of 1 MeV.[2]
[edit] Table
| nuclide symbol |
Z(p) | N(n) | isotopic mass (u) |
half-life | decay mode(s)[3][n 1] |
daughter isotope(s) |
nuclear spin |
|---|---|---|---|---|---|---|---|
| excitation energy | |||||||
| 237Cf | 98 | 139 | 237.06207(54)# | 2.1(3) s | SF | (various) | 5/2+# |
| β+ | 237Bk | ||||||
| α | 233Cm | ||||||
| 238Cf | 98 | 140 | 238.06141(43)# | 21.1(13) ms | SF | (various) | 0+ |
| β+ (rare) | 238Bk | ||||||
| α (rare) | 234Cm | ||||||
| 239Cf | 98 | 141 | 239.06242(23)# | 60(30) s [39(+37-12) s] |
α | 235Cm | 5/2+# |
| β+ (rare) | 239Bk | ||||||
| 240Cf | 98 | 142 | 240.06230(22)# | 1.06(15) min | α (98%) | 236Cm | 0+ |
| SF (2%) | (various) | ||||||
| β+ (rare) | 240Bk | ||||||
| 241Cf | 98 | 143 | 241.06373(27)# | 3.78(70) min | β+ (75%) | 241Bk | 7/2-# |
| α (25%) | 237Cm | ||||||
| 242Cf | 98 | 144 | 242.06370(4) | 3.49(15) min | α (80%) | 238Cm | 0+ |
| β+ (20%) | 242Bk | ||||||
| SF (.014%) | (various) | ||||||
| 243Cf | 98 | 145 | 243.06543(15)# | 10.7(5) min | β+ (86%) | 243Bk | (1/2+) |
| α (14%) | 239Cm | ||||||
| 244Cf | 98 | 146 | 244.066001(3) | 19.4(6) min | α (99%) | 240Cm | 0+ |
| EC (1%) | 244Bk | ||||||
| 245Cf | 98 | 147 | 245.068049(3) | 45.0(15) min | β+ (64%) | 245Bk | (5/2+) |
| α (36%) | 241Cm | ||||||
| 246Cf | 98 | 148 | 246.0688053(22) | 35.7(5) h | α | 242Cm | 0+ |
| EC (5×10−4%) | 246Bk | ||||||
| SF (2×10−4%) | (various) | ||||||
| 247Cf | 98 | 149 | 247.071001(9) | 3.11(3) h | EC (99.96%) | 247Bk | (7/2+)# |
| α (.04%) | 243Cm | ||||||
| 248Cf | 98 | 150 | 248.072185(6) | 333.5(28) d | α (99.99%) | 244Cm | 0+ |
| SF (.0029%) | (various) | ||||||
| 249Cf | 98 | 151 | 249.0748535(24) | 351(2) a | α | 245Cm | 9/2- |
| SF (5×10−7%) | (various) | ||||||
| 249mCf | 144.98(5) keV | 45(5) µs | 5/2+ | ||||
| 250Cf | 98 | 152 | 250.0764061(22) | 13.08(9) a | α (99.92%) | 246Cm | 0+ |
| SF (.077%) | (various) | ||||||
| 251Cf[n 2] | 98 | 153 | 251.079587(5) | 900(40) a | α | 247Cm | 1/2+ |
| 252Cf[n 3] | 98 | 154 | 252.081626(5) | 2.645(8) a | α (96.9%) | 248Cm | 0+ |
| SF (3.09%)[n 4] | (various) | ||||||
| 253Cf | 98 | 155 | 253.085133(7) | 17.81(8) d | β- (99.69%) | 253Es | (7/2+) |
| α (.31%) | 249Cm | ||||||
| 254Cf | 98 | 156 | 254.087323(13) | 60.5(2) d | SF (99.69%) | (various) | 0+ |
| α (.31%) | 250Cm | ||||||
| β-β- (rare) | 254Fm | ||||||
| 255Cf | 98 | 157 | 255.09105(22)# | 85(18) min | β- (99.99%) | 255Es | (7/2+) |
| SF (.001%) | (various) | ||||||
| α (10−5%) | 251Cm | ||||||
| 256Cf | 98 | 158 | 256.09344(32)# | 12.3(12) min | SF (99%) | (various) | 0+ |
| β- (1%) | 256Es | ||||||
| α (10−6%) | 252Cm | ||||||
| β-β- (rare) | 256Fm | ||||||
- ^ Abbreviations:
EC: Electron capture
SF: Spontaneous fission - ^ High neutron cross-section, tends to absorb neutrons
- ^ Most common isotope
- ^ High neutron emitter, average 3.7 neutrons per fission
[edit] Notes
- Values marked # are not purely derived from experimental data, but at least partly from systematic trends. Spins with weak assignment arguments are enclosed in parentheses.
- Uncertainties are given in concise form in parentheses after the corresponding last digits. Uncertainty values denote one standard deviation, except isotopic composition and standard atomic mass from IUPAC which use expanded uncertainties.
[edit] References
- ^ Emsley, John (2011). Nature's Building Blocks: An A-Z Guide to the Elements (New ed.). New York, NY: Oxford University Press. ISBN 978-0-19-960563-7.
- ^ Dicello, J. F.; Gross, W.; Kraljevic, U. (1972). "Radiation Quality of Californium-252". Physics in Medicine and Biology 17 (3): 345. Bibcode 1972PMB....17..345D. doi:10.1088/0031-9155/17/3/301.
- ^ http://www.nucleonica.net/unc.aspx
- Isotope masses from:
- G. Audi, A. H. Wapstra, C. Thibault, J. Blachot and O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties". Nuclear Physics A 729: 3–128. Bibcode 2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001. http://www.nndc.bnl.gov/amdc/nubase/Nubase2003.pdf.
- Isotopic compositions and standard atomic masses from:
- J. R. de Laeter, J. K. Böhlke, P. De Bièvre, H. Hidaka, H. S. Peiser, K. J. R. Rosman and P. D. P. Taylor (2003). "Atomic weights of the elements. Review 2000 (IUPAC Technical Report)". Pure and Applied Chemistry 75 (6): 683–800. doi:10.1351/pac200375060683. http://www.iupac.org/publications/pac/75/6/0683/pdf/.
- M. E. Wieser (2006). "Atomic weights of the elements 2005 (IUPAC Technical Report)". Pure and Applied Chemistry 78 (11): 2051–2066. doi:10.1351/pac200678112051. http://iupac.org/publications/pac/78/11/2051/pdf/. Lay summary.
- Half-life, spin, and isomer data selected from the following sources. See editing notes on this article's talk page.
- G. Audi, A. H. Wapstra, C. Thibault, J. Blachot and O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties". Nuclear Physics A 729: 3–128. Bibcode 2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001. http://www.nndc.bnl.gov/amdc/nubase/Nubase2003.pdf.
- National Nuclear Data Center. "NuDat 2.1 database". Brookhaven National Laboratory. http://www.nndc.bnl.gov/nudat2/. Retrieved September 2005.
- N. E. Holden (2004). "Table of the Isotopes". In D. R. Lide. CRC Handbook of Chemistry and Physics (85th ed.). CRC Press. Section 11. ISBN 978-0849304859.
- Other
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