Celluloids are a class of compounds created from nitrocellulose and camphor, with added dyes and other agents. Generally considered the first thermoplastic, it was first created as Parkesine in 1856 and as Xylonite in 1869, before being registered as Celluloid in 1870. Celluloid is easily molded and shaped, and it was first widely used as an ivory replacement. The main purpose was movie and photography film industries, that used only celluloid films prior to acetate films that were introduced in the fifties. Celluloid is highly flammable, difficult and expensive to produce and is no longer widely used. Its most common uses today are in table tennis balls, musical instruments and guitar picks.
Nitrocellulose-based plastics slightly predate celluloid. Collodion, invented in 1848 and used as a wound dressing and an emulsion for photographic plates, is dried to a celluloid-like film.
The first celluloid as a bulk material for forming objects was made in 1855 in Birmingham, England, by Alexander Parkes, who was never able to see his invention reach full fruition, after his firm went bankrupt due to scale-up costs. Parkes patented his discovery after realising a solid residue remained after evaporation of the solvent from photographic collodion.
Parkes patented it as a clothing waterproofer for woven fabrics in the same year. Later in 1862, Parkes showcased Parkesine at the Great Exhibition in London, where he was awarded a bronze medal for his efforts. The introduction of Parkesine is generally regarded as the birth of the plastics industry.
John Wesley Hyatt
In the 1860s, an American, John Wesley Hyatt, acquired Parkes's patent and began experimenting with cellulose nitrate with the intention of manufacturing billiard balls, which until that time were made from ivory. He used cloth, ivory dust, and shellac, and on April 6, 1869, patented a method of covering billiard balls with the addition of collodion. With assistance from Peter Kinnear and other investors, Hyatt formed the Albany Billiard Ball Company (1868–1986) in Albany, New York, to manufacture the product. In 1870, John and his brother Isaiah patented a process of making a "horn-like material" with the inclusion of cellulose nitrate and camphor. Alexander Parkes and Daniel Spill (see below) listed camphor during their earlier experiments, calling the resultant mix "xylonite", but it was the Hyatt brothers who recognized the value of camphor and its use as a plasticizer for cellulose nitrate. Isaiah Hyatt dubbed his material "celluloid" in 1872.
Daniel Spill and legal disputes
English inventor Daniel Spill had worked with Parkes and formed the Xylonite Co. to take over Parkes' patents, describing the new plastic products as Xylonite. He took exception to the Hyatts' claims and pursued the brothers in a number of court cases between 1877 and 1884. Initially the judge found in Spill's favour, but ultimately it was judged that neither party held an exclusive claim and the true inventor of celluloid/xylonite was Alexander Parkes, due to his mention of camphor in his earlier experiments and patents. The judge ruled all manufacturing of celluloid could continue both in Spill's British Xylonite Company and Hyatts' Celluloid Manufacturing Company.
The name Celluloid actually began as a trademark of the Celluloid Manufacturing Company, first of Albany, NY, and later of Newark, New Jersey, which manufactured the celluloids patented by John Wesley Hyatt. Hyatt used heat and pressure to simplify the manufacture of these compounds. Over the years, celluloid has become the normal term used for this type of plastic. In 1878 Hyatt was able to patent a process for injection moulding thermoplastics, although it took another 50 years before it could be realised commercially, and in later years celluloid was used as the base for photographic film.
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English photographer John Carbutt founded the Keystone Dry Plate Works in 1879 with the intention of producing gelatin dry plates. The Celluloid Manufacturing Company was contracted for this work by means of thinly slicing layers out of celluloid blocks and then removing the slice marks with heated pressure plates. After this, the celluloid strips were coated with a photosensitive gelatin emulsion. It is not certain exactly how long it took for Carbutt to standardize his process, but it occurred no later than 1888. A 15-inch-wide (380 mm) sheet of Carbutt's film was used by William Dickson for the early Edison motion picture experiments on a cylinder drum Kinetograph. However, the celluloid film base produced by this means was still considered too stiff for the needs of motion picture photography.
By 1889, more flexible celluloids for photographic film were developed, and both Hannibal Goodwin and the Eastman Kodak Company obtained patents for a film product (Ansco, which purchased Goodwin's patent when he died, was eventually successful in an infringement suit against Kodak). This ability to produce photographic images on a flexible material (as opposed to a glass or metal plate) was a crucial step toward the advent of motion pictures.
All movie and photography films prior to acetate films in the fifties were made of celluloid. Its high flammability was legendary since it self explodes when exposed to temperatures over 150°C in front of a hot movie projector beam.
Celluloid was useful for creating cheaper jewellery, jewellery boxes, hair accessories and many items that would earlier have been manufactured from ivory, horn or other expensive animal products. It was often referred to as "Ivorine" or "French Ivory". It was also used for dressing table sets, dolls, picture frames, charms, hat pins, buttons, buckles, stringed instrument parts, accordions, fountain pens, cutlery handles and kitchen items. The main disadvantage the material had was that it was flammable. Items made in celluloid are collectible today and increasingly rare in good condition. It was soon overtaken by Bakelite and Catalin. Table tennis balls are also made from celluloid.
Celluloid remains in use for musical instruments, especially accordions. Celluloid is very robust, easy to mold in difficult forms and has great acoustic performance. Instruments covered with celluloid can easily be recognized of the typical nacre like flaming pattern. Thick celluloid panels are cooked in a bain-marie which turns them into leather like substance. Panels are then turned on a mold and left to harden up to three months.
A typical formulation of celluloid might contain 70 to 80 parts nitrocellulose, nitrated to 11% nitrogen, 30 parts camphor, 0 to 14 parts dye, 1 to 5 parts ethyl alcohol, plus stabilizers and other agents to increase stability and reduce flammability.
- Stephen Fenichell, Plastic: The Making of a Synthetic Century, p. 17
- Andrea Picks: The Saga of Cellulose[dead link]
- Painter authorlink1=Paul C. Painter eat dump, Paul C.; Coleman, Michael M. (2008). "The Early History of Polymers". Essentials of Polymer Science and Engineering. DEStech>. pp. 7–9.
- Bassett, Fred (ed.) (2009). "Albany Billiard Ball Company Records, 1894-1944; Bulk 1915-1944". NYSL.NYSED.gov. Albany, NY, US: New York State Library, NYS Education Dept. "Manuscripts and Special Collections" section. Archived from the original on January 5, 2013. Retrieved January 5, 2013.
- "US patent #105,338 issued July 12, 1870". Google.com. Retrieved 2014-05-07.
- Daniel Spill, Celluloid Manufacturing Company, United States. Circuit Court (New York : Southern District) Spill vs. Celluloid Manufacturing Company litigation documents
- "Plastics Historical Society". Plastiquarian.com. Retrieved 2014-05-07.
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