|calcite (calcium carbonate)|
Chalk // is a soft, white, porous sedimentary rock, a form of limestone composed of the mineral calcite. Calcite is calcium carbonate or CaCO3. It forms under reasonably deep marine conditions from the gradual accumulation of minute calcite plates (coccoliths) shed from micro-organisms called coccolithophores. It is common to find chert or flint nodules embedded in chalk. Chalk can also refer to other compounds including magnesium silicate and calcium sulfate.
Chalk has greater resistance to weathering and slumping than the clays with which it is usually associated, thus forming tall steep cliffs where chalk ridges meet the sea. Chalk hills, known as chalk downland, usually form where bands of chalk reach the surface at an angle, so forming a scarp slope. Because chalk is porous it can hold a large volume of ground water, providing a natural reservoir that releases water slowly through dry seasons. Due to its porosity chalk is studied in numerous geophysical experiments (reflection seismology). In the North Sea, experiments have been performed for “evaluating 4D seismic for the correct pore pressure prediction”, through the “stress coefficient of chalk”.
The Chalk Group is a European stratigraphic unit deposited during the late Cretaceous Period. It forms the famous White Cliffs of Dover in Kent, England, as well as their counterparts of the Cap Blanc Nez on the other side of the Dover Strait. The Champagne region of France is mostly underlain by chalk deposits, which contain artificial caves used for wine storage. Some of the highest chalk cliffs in the world occur at Jasmund National Park in Germany and at Møns Klint in Denmark - both once formed a single island.
Ninety million years ago the chalk downland of Northern Europe was ooze accumulating at the bottom of a great sea. Protozoans such as foraminifera lived on the marine debris that showered down from the upper layers of the ocean. Their shells were made of calcite extracted from the rich sea-water. As they died a deep layer gradually built up and eventually, through the weight of overlying sediments, became consolidated into rock. Later earth movements related to the formation of the Alps raised these former sea-floor deposits above sea level.
Chalk is composed mostly of calcium carbonate with minor amounts of silt and clay. It is normally formed underwater, commonly on the sea bed, then consolidated and compressed during diagenesis into the form commonly seen today. During diagenesis silica accumulates to form chert or flint nodules within the carbonate rock.
Chalk is a source of quicklime by thermal decomposition, or slaked lime following quenching with water. In southeast England, Deneholes are a notable example of ancient chalk pits. Such bell pits may also mark the sites of ancient flint mines, where the prime object was to remove flint nodules for stone tool manufacture. The surface remains at Cissbury are one such example, but perhaps the most famous is the extensive complex at Grimes Graves in Norfolk. Woodworking joints may be fitted by chalking one of the mating surfaces. A trial fit will leave a chalk mark on the high spots of the corresponding surface. Chalk transferring to cover the complete surface indicates a good fit. Builder's putty also mainly contains chalk as a filler in linseed oil.
Chalk may be used for its properties as a base. In agriculture, chalk is used for raising pH in soils with high acidity. The most common forms are CaCO3 (calcium carbonate) and CaO (calcium oxide). Small doses of chalk can also be used as an antacid. Additionally, the small particles of chalk make it a substance ideal for cleaning and polishing. For example, toothpaste commonly contains small amounts of chalk, which serves as a mild abrasive. Polishing chalk is chalk prepared with a carefully controlled grain size, for very fine polishing of metals. Chalk can also be used as fingerprint powder.
The traditional uses of chalk have in some cases been replaced by other substances, although the word "chalk" is often still applied to the usual replacements. Blackboard chalk is a substance used for drawing on rough surfaces, as it readily crumbles leaving particles that stick loosely to these surfaces. Although traditionally composed of natural chalk, modern blackboard chalk is generally made from the mineral gypsum (calcium sulfate), often supplied in sticks of compressed powder about 10 cm (4 in) long. Sidewalk chalk is similar to blackboard chalk, but it is shaped into larger sticks and often colored. It is used to draw on sidewalks, streets, and driveways. Tailor's chalk is traditionally a hard chalk used to make temporary markings on cloth, mainly by tailors. However, it is now usually made from talc (magnesium silicate).
Chalk was also traditionally used in recreation. In field sports, such as tennis played on grass, powdered chalk was used to mark the boundary lines of the playing field or court. If a ball hits the line, a cloud of chalk or pigment dust will be visible. In recent years, powdered chalk has been replaced with titanium dioxide. In gymnastics, rock-climbing, weight-lifting and tug of war, chalk — now usually magnesium carbonate — is applied to the hands and feet to remove perspiration and reduce slipping.
- Static and dynamic effective stress coefficient of chalk, M. Monzurul Alam, Ida Lykke Fabricius, and Helle Foged Christensen, GEOPHYSICS, VOL. 77, NO. 2 (MARCH-APRIL 2012); P. L1–L11, 8 FIGS., 2 TABLES.10.1190/GEO2010-0414.1
- Blount, Bertram (1990). Chemistry for Engineers and Manufacturers: Chemistry of manufacturing processes. University of Wisconsin - Madison.
- Information on polishing powders, from the 1879 book "The Workshop Companion"
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