Chloro(triphenylphosphine)gold(I)

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Chloro(triphenylphosphine)gold(I)
PPh3AuCl.png
Identifiers
CAS number !14243-64-2 YesY
Properties
Molecular formula C18H15AuClP
Molar mass 494.71 g mol−1
Appearance Colorless solid
Melting point 236-237 °C
Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
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Infobox references

Chloro(triphenylphosphine)gold(I) is the coordination complex with the formula (Ph3P)AuCl. This colorless solid is the complex of triphenylphosphine and gold(I) chloride.

Preparation and structure[edit]

The complex is prepared by reducing chloroauric acid with triphenylphosphine in 95% ethanol:[1]

HAuCl4 + H2O + 2 PPh3 → (Ph3P)AuCl + Ph3PO + 3 HCl

The complex adopts a linear coordination geometry, which is typical of most gold(I) compounds.[2][3]

Reactivity[edit]

It is a common reagent in gold chemistry. Many related gold complexes (often incorrectly called salts) can be prepared including the trifluoromethanesulfonate and the nitrate.[4]

Triphenylphosphine gold triflate (Ph3PAuOTf) catalyzes certain rearrangement reactions in organic synthesis.

Reaction scheme of Au(I) and Au(III) organometallic compounds, with (Ph3P)AuCl as the precursor.

References[edit]

  1. ^ Pierre Braunstein, Hans Lehner, Dominique Matt "A Platinum-Gold Cluster: Chloro-1κCl-Bis(Triethylphosphine-1κP)Bis(Triphenyl- Phosphine)-2κP, 3κP-Triangulo- Digold-Platinum(1 +) Trifluoromethanesulfonate" Inorganic Syntheses, 1990, Volume 27, Pages 218–221. doi: 10.1002/9780470132586.ch42
  2. ^ Baenziger, N. C.; Bennett, W. E.; Soborofe, D. M. (1976). "Chloro(triphenylphosphine)gold(I)". Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry 32 (3): 962. doi:10.1107/S0567740876004330. 
  3. ^ Borissova, Alexandra O.; Korlyukov, Alexander A.; Antipin, Mikhail Yu.; Lyssenko, Konstantin A. (2008). "Estimation of Dissociation Energy in Donor−Acceptor Complex AuCl·PPh3via Topological Analysis of the Experimental Electron Density Distribution Function". The Journal of Physical Chemistry A 112 (46): 11519–22. doi:10.1021/jp807258d. PMID 18959385. 
  4. ^ A. M. Mueting, B. D. Alexander, P. D. Boyle, A. L. Casalnuovo, L. N. Ito, B. J. Johnson, L. H. Pignolet "Mixed-Metal-Gold Phosphine Cluster Compounds" Inorganic Syntheses, 1992, Volume 29, Pages 279–298, 2007. doi:10.1002/9780470132609.ch63