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Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Chlorous acid is an inorganic compound with the formula HClO2. It is a weak acid. Chlorine has oxidation state +3 in this acid. The pure substance is unstable, disproportionating to hypochlorous acid (Cl oxidation state +1) and chloric acid (Cl oxidation state +5):
- 2 HClO2 → HClO + HClO3
Although the acid is difficult to obtain in pure substance, the conjugate base, chlorite, derived from this acid is stable. One example of a salt of this anion is the well-known sodium chlorite. This and related salts are sometimes used in the production of chlorine dioxide.
HClO2 can be prepared through reaction of barium chlorite and dilute sulfuric acid:
- Ba(ClO2)2 + H2SO4 → BaSO4 + 2HClO2
Chlorous acid is a powerful oxidizing agent, although its tendency to disproportionation counteracts its oxidizing potential.
Chlorine is the only halogen to form an isolable acid of formula HXO2. Fluorine resists oxidation above the level of hypofluorous acid. Neither bromous acid nor iodous acid has ever been isolated. A few salts of bromous acid, bromites, are known, but no iodites.
Media related to Chlorous acid at Wikimedia Commons
- Egon Wiberg, Arnold Frederick Holleman (2001) Inorganic Chemistry, Elsevier ISBN 0-12-352651-5
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