Clair Cameron Patterson
|Clair Cameron Patterson|
Clair Cameron Patterson
|Born||June 2, 1922
Mitchellville, Iowa, USA
|Died||December 5, 1995
Sea Ranch, California, USA
|Institutions||California Institute of Technology|
|Thesis||The Isotopic Composition of Trace Quantities of Lead and Calcium (1951)|
|Doctoral advisor||Harrison Brown|
|Known for||uranium-lead dating, age of the Earth, lead contamination|
|Notable awards||Tyler Prize (1995)
V. M. Goldschmidt Award (1980)
J. Lawrence Smith Medal (1973)
Clair Cameron Patterson (June 2, 1922 – December 5, 1995) was a geochemist born in Mitchellville, Iowa, United States. He graduated from Grinnell College in Grinnell, Iowa, received his Ph.D. from the University of Chicago, and spent his entire professional career at the California Institute of Technology.
In collaboration with George Tilton, Patterson developed the uranium-lead dating method into lead-lead dating, and by using lead isotopic data from the Canyon Diablo meteorite, he calculated an age for the Earth of 4.55 billion years; a figure far more accurate than those that existed at the time and one that has remained largely unchanged since 1956.
Patterson had first encountered lead contamination in the late 1940s as a graduate student at the University of Chicago. His work on this led to a total re-evaluation of the growth in industrial lead concentrations in the atmosphere and the human body, and his subsequent campaigning was seminal in the banning of tetraethyllead in gasoline, and lead solder in food cans.
Clair (Pat) Patterson was born in Mitchellville, Iowa and graduated from Grinnell College in chemistry where he met his wife, Lorna (Laurie) McCleary. They both moved to the University of Iowa for graduate work where he did an M.A. in molecular spectroscopy. Both were then sent to work on the Manhattan Project, first at the University of Chicago and then at Oak Ridge, Tennessee where he encountered mass spectrometry.
After the war they returned to Chicago where Laurie took a research job as an infrared spectroscopist to support Pat whilst he did a Ph.D. at the University of Chicago under Harrison Brown. After a postdoctoral year at Chicago, Patterson moved with Brown to the Division of Geology (later the Division of Geological and Planetary Sciences) at the California Institute of Technology (Caltech) in 1952 as founding members of its geochemistry program. Pat remained at Caltech for the rest of his life. He and Laurie had four children.
Estimate of the Earth's age
Harrison Brown of the University of Chicago developed a new method for counting lead isotopes in igneous rocks, and assigned it to Patterson as a dissertation project in 1948. During this period Patterson operated under the assumption that meteorites are left-over materials from the formation of the Solar System, and thus by measuring the age of one of these rocks the age of the Earth would be revealed. Gathering the materials required time, and in 1953, Patterson had his final specimens from the Canyon Diablo meteorite. He took them to the Argonne National Laboratory, where he was granted time on a late model mass spectrometer.
In a meeting in Wisconsin soon afterward, Patterson revealed the results of his study. The definitive age of the Earth is 4.550 billion years (give or take 70 million years). The current estimate for the age of the earth is 4.54 ± 0.05 billion years (4.54 × 109 years ± 1%).
Tracing the geochemical evolution of the Earth
His ability to isolate microgram quantities of lead from ordinary rocks and determine their isotope composition led him to examining the lead in ocean sediment samples from the Atlantic and Pacific. Deriving from the different ages at which the landmasses had drained into the ocean, he was able to show that the amount of anthropogenic lead presently dispersed into the environment was about eighty times the amount being deposited in the ocean sediments: the geochemical cycle for lead appeared to be badly out of balance.
The limitations of the analytic procedures led to him using other approaches. He found that deep ocean water contained 3-10 times less lead than surface water, in contrast to similar metals such as barium. This led him to doubt the commonly held view that lead concentrations had only grown by a factor of two over naturally occurring levels.
Patterson returned to the problem of his initial experiment and the contamination he had found in the blanks used for sampling. He determined through ice-core samples from Greenland that atmospheric lead levels had begun to increase steadily and dangerously soon after tetraethyllead began to see widespread use in fuel, when it was discovered to reduce engine knock in internal combustion engines. Patterson subsequently identified this, along with the various other uses of lead in manufacturing, as the cause of the contamination of his samples, and because of the significant public-health implications of his findings, he devoted the rest of his life to removing as much introduced lead from the environment as possible.
Campaign against lead poisoning
Beginning in 1965, with the publication of Contaminated and Natural Lead Environments of Man, Patterson tried to draw public attention to the problem of increased lead levels in the environment and the food chain due to lead from industrial sources. Perhaps partly because he was criticizing the experimental methods of other scientists, he encountered strong opposition from recognized experts such as Robert A. Kehoe.
In his effort to ensure that lead was removed from gasoline (petrol), Patterson fought against the lobbying power of the Ethyl Corporation (which employed Kehoe), against the legacy of Thomas Midgley — which included tetraethyllead and chlorofluorocarbons — and against the lead additive industry as a whole. Following Patterson's criticism of the lead industry, he was refused contracts with many research organizations, including the supposedly neutral United States Public Health Service. In 1971 he was excluded from a National Research Council (NRC) panel on atmospheric lead contamination, even though he was the foremost expert on the subject at that time.
The United States mandated the use of unleaded gasoline to protect catalytic converters in all new cars starting with the 1975 model year, but Patterson's efforts accelerated the phaseout of lead from all standard, consumer, automotive gasoline in the United States by 1986. Lead levels within the blood of Americans are reported to have dropped by up to 80% by the late 1990s.
He then turned his attention to lead in food where similar experimental deficiencies had masked the increase. In one study he showed an increase in lead levels from 0.3 to 1400 nanograms per gram in certain canned fish compared with fresh, whilst the official laboratory had reported an increase of 400 ng/g to 700 ng/g. He compared the lead, barium and calcium levels in 1600 year-old Peruvian skeletons and showed a 700- to 1200-fold increase in lead levels in modern human bones with no comparable changes in the barium and calcium levels.
In 1978 he was appointed to a NRC panel which accepted many of the increases and the need for reductions – but, argued the need for more research. His opinions were expressed in a 78-page minority report which argued that control measures should start immediately; including gasoline, food containers, paint, glazes and water distribution systems. Thirty years later, most of these have been accepted and implemented in the United States and many other parts of the world.
- Biographical memoir by George R. Tilton
- Interview with Shirley Cohen from the Caltech Oral History archives
- Biographical Memoirs of the National Academy of Sciences (NAS) for Clair C. Patterson See p. 17.
- "Age of the Earth". U.S. Geological Survey. 1997. Archived from the original on 23 December 2005. Retrieved 2006-01-10.
- Dalrymple, G. Brent (2001). "The age of the Earth in the twentieth century: a problem (mostly) solved". Special Publications, Geological Society of London 190 (1): 205–221. Bibcode:2001GSLSP.190..205D. doi:10.1144/GSL.SP.2001.190.01.14.
- Manhesa, Gérard; Allègre, Claude J.; Dupréa, Bernard; and Hamelin, Bruno (1980). "Lead isotope study of basic-ultrabasic layered complexes: Speculations about the age of the earth and primitive mantle characteristics". Earth and Planetary Science Letters 47 (3): 370–382. Bibcode:1980E&PSL..47..370M. doi:10.1016/0012-821X(80)90024-2.
- The same (NAS) source as above See p. 14.
- The U.S. Experience with the Phasedown of Lead in Gasoline (PDF), 2003-06-15, retrieved 2014-12-12
- Blood Lead Levels Keep Dropping; New Guidelines Proposed for Those Most Vulnerable, 1997-02-20, retrieved 2007-07-31
- Settle, D. M.; Patterson, C. C. (1980), "Lead in albacore: guide to lead pollution in Americans", Science 207 (4436): 1167–76, Bibcode:1980Sci...207.1167S, doi:10.1126/science.6986654, PMID 6986654
- Ericson, J.E.; Shirahata, H.; Patterson, C.C. (1975), "Skeletal concentrations of lead in ancient Peruvians", N. Engl. J. Med. 300: 946–51, doi:10.1056/nejm197904263001703
- Lead in the Human Environment, Washington, D.C.: National Academy of Sciences, 1980
- Dicke, William "Clair C. Patterson, Who Established Earth's Age, Is Dead at 73"
- Patterson, C. (1956), "Age of meteorites and the Earth", Geochimica et Cosmochimica Acta 10 (4): 230–237, Bibcode:1956GeCoA..10..230P, doi:10.1016/0016-7037(56)90036-9
- Patterson, C.; Chow, T. J. (1962), "The occurrence and significance of lead isotopes in pelagic sediments", Geochimica et Cosmochimica Acta 26 (2): 263–308, Bibcode:1962GeCoA..26..263C, doi:10.1016/0016-7037(62)90016-9
- Patterson, C. (1965), "Contaminated and natural lead environments of man", Arch. Environ. Health 11: 344–360, doi:10.1080/00039896.1965.10664229, PMID 14334042
- Bryson, Bill (2004), A Short History of Nearly Everything, Broadway, pp. 149, 156–160, ISBN 978-0-7679-0818-4
- Davidson, Cliff I., ed. (1998), Clean Hands: Clair Patterson's Crusade against Environmental Lead Contamination, New York: Nova Science Publishers, pp. xxxiv+162, ISBN 1-56072-568-0
- McGrayne, S. Bertsch (2002), "Ch. 9: Lead-Free Gasoline and Clair C. Patterson", Prometheans in the Lab, New York: McGraw-Hill, ISBN 0-07-140795-2
- Tilton, George R., Clair Cameron Patterson, retrieved 2009-03-10
- Denworth, L. Toxic Truth: A Scientist, A Doctor, and the Battle over Lead, Beacon Press, 2009.
- Casanova, I (1998), "Clair C. Patterson (1922-1995), discoverer of the age of the Earth", Int. Microbiol. (Sep 1998) 1 (3): 231–2, PMID 10943366
- Flegal, A R (1998), "Clair Patterson's influence on environmental research", Environ. Res. (Aug 1998) 78 (2): 64–70, Bibcode:1998ER.....78...65F, doi:10.1006/enrs.1998.3861, PMID 9725987
- Needleman, H L (1998), "Clair Patterson and Robert Kehoe: two views of lead toxicity", Environ. Res. (Aug 1998) 78 (2): 79–85, Bibcode:1998ER.....78...79N, doi:10.1006/enrs.1997.3807, PMID 9719611
- Flegal, A (1998), "Clair Patterson's Influence on Environmental Research", Environ. Res. (Aug 1998) 78 (2): 65–185, PMID 9719609
- Nriagu, J O (1998), "Clair Patterson and Robert Kehoe's paradigm of "show me the data" on environmental lead poisoning", Environ. Res. (Aug 1998) 78 (2): 71–8, Bibcode:1998ER.....78...71N, doi:10.1006/enrs.1997.3808, PMID 9719610