Composition and preparation
Clinker consists of various calcium silicates, including tricalcium silicate (Ca3SiO5, also written CaO.Ca2SiO4) and dicalcium silicate (Ca2SiO4). Tricalcium aluminate and calcium aluminoferrite are other common components. These components are often generated in situ by heating various clays and limestone.
Portland cement clinker is made by heating in a rotary kiln at high temperature a homogeneous mixture of raw materials. The products of the chemical reaction aggregate together as molten minerals at the sintering temperature. The sintering temperature for modern cements is about 1450 °C. Aluminium oxide and iron oxide are present as a flux and contribute little to the cement strength. For special cements, such as Low Heat (LH) and Sulfate Resistant (SR) types, it is necessary to limit the amount of tricalciumaluminate (3 CaO·Al2O3) formed. The major raw material for the clinker-making is usually limestone (CaCO3) mixed with a second material containing clay as source of alumino-silicate. Normally, an impure limestone which contains clay or SiO2 is used. The CaCO3 content of these limestones can be as low as 80%. Second raw materials (materials in the rawmix other than limestone) depend on the purity of the limestone. Some of the second raw materials used are: clay, shale, sand, iron ore, bauxite, fly ash and slag. The clinker surface and its reactions in different electrolytic solutions are investigated by Scanning electron microscope and Atomic force microscopy.
Clinker, if stored in dry conditions, can be kept for several months without appreciable loss of quality. Because of this, and because it can easily be handled by ordinary mineral handling equipment, clinker is traded internationally in large quantities. Cement manufacturers purchasing clinker usually grind it as an addition to their own clinker at their cement plants. Manufacturers also ship clinker to grinding plants in areas where cement-making raw materials are not available.
Gypsum is added to clinker primarily as an additive preventing the flash settings of cement, but it is also very effective to facilitate the grinding of clinker by preventing agglomeration and coating of the powder at the surface of balls and mill wall.
Organic compounds are also often added as grinding aids to avoid powder agglomeration. Triethanolamine (TEA) is commonly used at 0.1 wt. % and is proved to be very effective. Other additives are sometimes used, such as ethylene glycol, oleic acid, dodecyl-benzene sulfonate, ... . 
Conversion to cement paste
Upon treatment with water, clinker reacts to form a hydrate called cement paste. Upon standing the paste polymerizes as indicated by its hardening.
- Siegbert Sprung "Cement" in Ullmann's Encyclopedia of Industrial Chemistry, 2012 Wiley-VCH, Weinheim. doi:10.1002/14356007.a05_489.pub2
- Ferrari, L. (2012). "Reaction of clinker surfaces investigated with atomic force microscopy". Construction and Building Materials 35: 92–96. doi:10.1016/j.conbuildmat.2012.02.089.
- Sohoni, S.; R. Sridhar, G. Mandal (1991). "Effect of grinding aids on the fine grinding of limestone, quartz and portland cement clinker". Powder Technology 67 (3): 277–286. doi:10.1016/0032-5910(91)80109-V.