Cobalt(III) oxide

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Cobalt(III) oxide[1]
Cobalt(III) oxide.JPG
Identifiers
CAS number 1308-04-9 YesY
PubChem 4110762
Properties
Molecular formula Co2O3
Molar mass 165.8646 g/mol
Appearance black powder
Density 5.18 g/cm3 [2]
Melting point 1900 °C
Structure
Crystal structure Trigonal, hR30
Space group R-3c, No. 167
Hazards
R-phrases R22 R40 R43
S-phrases S36/37
Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
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Infobox references

Cobalt (III) oxide is the inorganic compound with the formula Co2O3. Although only two oxides of cobalt are well characterized, CoO and Co3O4,[3] procedures claiming to give Co2O3 have been described. Thus treatment of Co(II) salts such as cobalt(II) nitrate with an aqueous solution of sodium hypochlorite (also known as bleach) gives a black solid.[4] Some formulations of the catalyst hopcalite contain "Co2O3".

References[edit]

  1. ^ Sigma-Aldrich product page
  2. ^ Lide, David R., ed. (2006). CRC Handbook of Chemistry and Physics (87th ed.). Boca Raton, FL: CRC Press. ISBN 0-8493-0487-3. 
  3. ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 0080379419. 
  4. ^ Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1963, NY. p. 1675.