Cohesion (chemistry)

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The cohesive character of water is clearly noticeable.

Cohesion (n. lat. cohaerere "stick or stay together") or cohesive attraction or cohesive force is the action or property of molecules sticking together, being mutually attractive. It is an intrinsic property of a substance that is caused by the shape and structure of its molecules, which makes the distribution of orbiting electrons irregular when molecules get close to one another, creating electrical attraction that can maintain a microscopic structure such as a water drop. In other words, cohesion allows for surface tension, creating a "solid-like" state upon which light (in weight) or low-density materials can be placed.

Mercury exhibits more cohesion than adhesion with glass.

Water, for example, is strongly cohesive as each molecule may make four hydrogen bonds to other water molecules in a tetrahedral configuration. This results in a relatively strong Coulomb force between molecules. In simple terms, the polarity (state of which a molecule is oppositely charged on its poles) of water molecules allows them to be attracted towards each other. In the case of a water molecule, the hydrogen atoms carry a relative positive charges in comparison to the oxygen atom. This charge polarization within the molecule allows it to align with adjacent molecules through strong intermolecular hydrogen bonding, rendering the bulk liquid cohesive. Van der Waals gases such as methane, however, have weak cohesion due only to Van der Waals forces that operate by induced polarity in non-polar molecules.

Cohesion, along with adhesion (attraction between unlike molecules), helps explain phenomena such as meniscus, surface tension and capillary action.

Mercury in a glass flask is a good example of the effects of the ratio between cohesive and adhesive forces. Because of its high cohesion and low adhesion to the glass, mercury does not spread out to cover the top of the flask, and if enough is placed in the flask to cover the bottom, it exhibits a strongly convex meniscus, whereas the meniscus of water is concave. Mercury will not wet the glass, unlike water and many other liquids,[1] and if the glass is tipped, it will 'roll' around inside.

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External links[edit]

  • The Bubble Wall (audio slideshow from the National High Magnetic Field Laboratory explaining cohesion, surface tension and hydrogen bonds)