Conservation of energy
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The law of conservation of energy, first formulated in the nineteenth century, is a law of physics. It states that the total amount of energy in an isolated system remains constant over time. The total energy is said to be conserved over time. For an isolated system, this law means energy is localized and can change its location within the system, and it can change form within the system, for instance, chemical energy can become kinetic energy but it can be neither created nor destroyed. Furthermore, two initially isolated systems, that have no external or mutual interaction, can be logically composed into a single isolated system, and then the total amount of energy of the composite system is equal to the sum of the respective total amounts of energy of the two component systems. In this sense, the energy of a system is said to be additive. Likewise, for a homogeneous system in its own internal thermodynamic equilibrium, the internal energy is said to be an extensive quantity.
In the twentieth century, the definition of energy was broadened. Material particles, also called ponderable matter, that have rest mass, were recognized as having equivalent amounts of energy. They are not conserved, and can perish into forms of energy, including kinetic and potential energy, that lack rest mass. For example an electron and a positron can perish together into photons of electromagnetic radiation. Likewise, non-material forms of energy can perish into ponderable matter.
In such a transformation process within an isolated system, neither the total mass nor the total energy changes over time, although the matter content may change. Therefore, conservation of energy, and conservation of mass, each still holds as a law in its own right (indeed they are restatements of the same law, when mass and energy are recognized to be equivalent). When stated alternatively, in terms of mass and of energy, they appear as the apparently distinct laws of the nineteenth century.
A consequence of the law of conservation of energy is that no intended "perpetual motion machine" can perpetually deliver energy to its surroundings. Any delivery of energy by such a device would result in delivery of mass also, and the machine would lose mass continually until it eventually disappeared.
Ancient philosophers as far back as Thales of Miletus c.~550 BCE had inklings of the conservation of some underlying substance of which everything is made. However, there is no particular reason to identify this with what we know today as "mass-energy" (for example, Thales thought it was water). Empedocles (490–430 BCE) wrote that in his universal system, composed of four roots (earth, air, water, fire), "nothing comes to be or perishes", but these elements suffer continual rearrangement.
In 1638, Galileo published his analysis of several situations—including the celebrated "interrupted pendulum"—which can be described (in modern language) as conservatively converting potential energy to kinetic energy and back again. However, Galileo did not state the process in modern terms and again cannot be credited with the crucial insight.
It was Gottfried Wilhelm Leibniz during 1676–1689 who first attempted a mathematical formulation of the kind of energy which is connected with motion (kinetic energy). Leibniz noticed that in many mechanical systems (of several masses, mi each with velocity vi ),
was conserved so long as the masses did not interact. He called this quantity the vis viva or living force of the system. The principle represents an accurate statement of the approximate conservation of kinetic energy in situations where there is no friction. Many physicists at that time held that the conservation of momentum, which holds even in systems with friction, as defined by the momentum:
was the conserved vis viva. It was later shown that, under the proper conditions, both quantities are conserved simultaneously such as in elastic collisions.
It was largely engineers such as John Smeaton, Peter Ewart, Carl Holtzmann, Gustave-Adolphe Hirn and Marc Seguin who objected that conservation of momentum alone was not adequate for practical calculation and made use of Leibniz's principle. The principle was also championed by some chemists such as William Hyde Wollaston. Academics such as John Playfair were quick to point out that kinetic energy is clearly not conserved. This is obvious to a modern analysis based on the second law of thermodynamics but in the 18th and 19th centuries, the fate of the lost energy was still unknown. Gradually it came to be suspected that the heat inevitably generated by motion under friction, was another form of vis viva. In 1783, Antoine Lavoisier and Pierre-Simon Laplace reviewed the two competing theories of vis viva and caloric theory. Count Rumford's 1798 observations of heat generation during the boring of cannons added more weight to the view that mechanical motion could be converted into heat, and (as importantly) that the conversion was quantitative and could be predicted (allowing for a universal conversion constant between kinetic energy and heat). Vis viva now started to be known as energy, after the term was first used in that sense by Thomas Young in 1807.
The recalibration of vis viva to
which can be understood as finding the exact value for the kinetic energy to work conversion constant, was largely the result of the work of Gaspard-Gustave Coriolis and Jean-Victor Poncelet over the period 1819–1839. The former called the quantity quantité de travail (quantity of work) and the latter, travail mécanique (mechanical work), and both championed its use in engineering calculation.
In a paper Über die Natur der Wärme, published in the Zeitschrift für Physik in 1837, Karl Friedrich Mohr gave one of the earliest general statements of the doctrine of the conservation of energy in the words: "besides the 54 known chemical elements there is in the physical world one agent only, and this is called Kraft [energy or work]. It may appear, according to circumstances, as motion, chemical affinity, cohesion, electricity, light and magnetism; and from any one of these forms it can be transformed into any of the others."
Mechanical equivalent of heat 
A key stage in the development of the modern conservation principle was the demonstration of the mechanical equivalent of heat. The caloric theory maintained that heat could neither be created nor destroyed but conservation of energy entails the contrary principle that heat and mechanical work are interchangeable.
In 1798 Count Rumford (Benjamin Thompson) performed measurements of the frictional heat generated in boring cannons and developed the idea that heat is a form of kinetic energy; his measurements refuted caloric theory, but were imprecise enough to leave room for doubt.
The mechanical equivalence principle was first stated in its modern form by the German surgeon Julius Robert von Mayer in 1842. Mayer reached his conclusion on a voyage to the Dutch East Indies, where he found that his patients' blood was a deeper red because they were consuming less oxygen, and therefore less energy, to maintain their body temperature in the hotter climate. He discovered that heat and mechanical work were both forms of energy and in 1845, after improving his knowledge of physics, he published a monograph that stated a quantitative relationship between them.
Meanwhile, in 1843 James Prescott Joule independently discovered the mechanical equivalent in a series of experiments. In the most famous, now called the "Joule apparatus", a descending weight attached to a string caused a paddle immersed in water to rotate. He showed that the gravitational potential energy lost by the weight in descending was equal to the thermal energy (heat) gained by the water by friction with the paddle.
Both Joule's and Mayer's work suffered from resistance and neglect but it was Joule's that eventually drew the wider recognition.
- For the dispute between Joule and Mayer over priority, see Mechanical equivalent of heat: Priority
In 1844, William Robert Grove postulated a relationship between mechanics, heat, light, electricity and magnetism by treating them all as manifestations of a single "force" (energy in modern terms). In 1874 Grove published his theories in his book The Correlation of Physical Forces. In 1847, drawing on the earlier work of Joule, Sadi Carnot and Émile Clapeyron, Hermann von Helmholtz arrived at conclusions similar to Grove's and published his theories in his book Über die Erhaltung der Kraft (On the Conservation of Force, 1847). The general modern acceptance of the principle stems from this publication.
In 1877, Peter Guthrie Tait claimed that the principle originated with Sir Isaac Newton, based on a creative reading of propositions 40 and 41 of the Philosophiae Naturalis Principia Mathematica. This is now regarded as an example of Whig history.
Mass–energy equivalence 
In the nineteenth century, mass and energy were considered to be of quite different natures. Then Albert Einstein's theory of special relativity showed that mass and energy are related by an equivalence. Energy has an equivalent mass, and mass has an equivalent energy. Physicists now speak of a unified law of conservation of mass-energy. This is a recognition that the two nineteenth century conservation laws are restricted versions of one and the same more general law. While matter can be actually converted into non-matter, the relation between mass and energy is a simply theoretical equivalence, so that it makes no sense to think of their "actual interconversion". Thus, the modern view is that conservation of energy and conservation of mass are simply the same conservation law, stated differently, in different units. Einstein's E = mc2 and other equations serve to convert one unit to the other.
First law of thermodynamics 
For a closed thermodynamic system, the first law of thermodynamics may be stated as:
where is the amount of energy added to the system by a heating process, is the amount of energy lost by the system due to work done by the system on its surroundings and is the change in the internal energy of the system.
The δ's before the heat and work terms are used to indicate that they describe an increment of energy which is to be interpreted somewhat differently than the increment of internal energy (see Inexact differential). Work and heat are processes which add or subtract energy, while the internal energy is a particular form of energy associated with the system. Thus the term "heat energy" for means "that amount of energy added as the result of heating" rather than referring to a particular form of energy. Likewise, the term "work energy" for means "that amount of energy lost as the result of work". The most significant result of this distinction is the fact that one can clearly state the amount of internal energy possessed by a thermodynamic system, but one cannot tell how much energy has flowed into or out of the system as a result of its being heated or cooled, nor as the result of work being performed on or by the system. In simple terms, this means that energy cannot be created or destroyed, only converted from one form to another.
Entropy is a function of the state of a system which tells of the possibility of conversion of heat into work.
For a simple compressible system, the work performed by the system may be written:
For a simple open system (in which mass may be exchanged with the environment), containing a single type of particle, the first law is written:
where is the added mass and is the internal energy per unit mass of the added mass. The addition of mass may be accompanied by a volume change which is not associated with work (e.g. for a liquid-vapor system, the volume of the vapor system may increase due to volume lost by the evaporating liquid). In the reversible case, the work will be given by where v is the specific volume of the added mass.
Noether's theorem 
The conservation of energy is a common feature in many physical theories. From a mathematical point of view it is understood as a consequence of Noether's theorem, which states every continuous symmetry of a physical theory has an associated conserved quantity; if the theory's symmetry is time invariance then the conserved quantity is called "energy". The energy conservation law is a consequence of the shift symmetry of time; energy conservation is implied by the empirical fact that the laws of physics do not change with time itself. Philosophically this can be stated as "nothing depends on time per se". In other words, if the physical system is invariant under the continuous symmetry of time translation then its energy (which is canonical conjugate quantity to time) is conserved. Conversely, systems which are not invariant under shifts in time (an example, systems with time dependent potential energy) do not exhibit conservation of energy – unless we consider them to exchange energy with another, external system so that the theory of the enlarged system becomes time invariant again. Since any time-varying system can be embedded within a larger time-invariant system, conservation can always be recovered by a suitable re-definition of what energy is. Conservation of energy for finite systems is valid in such physical theories as special relativity and quantum theory (including QED) in the flat space-time.
With the discovery of special relativity by Albert Einstein, energy was proposed to be one component of an energy-momentum 4-vector. Each of the four components (one of energy and three of momentum) of this vector is separately conserved across time, in any closed system, as seen from any given inertial reference frame. Also conserved is the vector length (Minkowski norm), which is the rest mass for single particles, and the invariant mass for systems of particles (where momenta and energy are separately summed before the length is calculated—see the article on invariant mass).
The relativistic energy of a single massive particle contains a term related to its rest mass in addition to its kinetic energy of motion. In the limit of zero kinetic energy (or equivalently in the rest frame) of a massive particle; or else in the center of momentum frame for objects or systems which retain kinetic energy, the total energy of particle or object (including internal kinetic energy in systems) is related to its rest mass or its invariant mass via the famous equation .
Thus, the rule of conservation of energy over time in special relativity continues to hold, so long as the reference frame of the observer is unchanged. This applies to the total energy of systems, although different observers disagree as to the energy value. Also conserved, and invariant to all observers, is the invariant mass, which is the minimal system mass and energy that can be seen by any observer, and which is defined by the energy–momentum relation.
In general relativity conservation of energy-momentum is expressed with the aid of a stress-energy-momentum pseudotensor. The theory of general relativity leaves open the question of whether there is a conservation of energy for the entire universe.
Quantum theory 
In quantum mechanics, energy of a quantum system is described by a self-adjoint (Hermite) operator called Hamiltonian, which acts on the Hilbert space (or a space of wave functions ) of the system. If the Hamiltonian is a time independent operator, emergence probability of the measurement result does not change in time over the evolution of the system. Thus the expectation value of energy is also time independent. The local energy conservation in quantum field theory is ensured by the quantum Noether's theorem for energy-momentum tensor operator. Note that due to the lack of the (universal) time operator in quantum theory, the uncertainty relations for time and energy are not fundamental in contrast to the position momentum uncertainty principle, and merely holds in specific cases (See Uncertainty principle). Energy at each fixed time can be precisely measured in principle without any problem caused by the time energy uncertainty relations. Thus the conservation of energy in time is a well defined concept even in quantum mechanics.
See also 
- Conservation law
- Conservation of mass
- Energy quality
- Energy transformation
- Groundwater energy balance
- Laws of thermodynamics
- Principles of energetics
- Walter Lewin (October 4, 1999). Work, Kinetic Energy, and Universal Gravitation. MIT Course 8.01: Classical Mechanics, Lecture 11. (ogg) (videotape) (in English). Cambridge, MA USA: MIT OCW. Event occurs at 45:35–49:11. Retrieved December 23, 2010. "150 Joules is enough to kill you."
- C. Carathéodory (1909). "Untersuchungen über die Grundlagen der Thermodynamik". Mathematische Annalen 67: 355–386. doi:10.1007/BF01450409. A mostly reliable translation is to be found at Kestin, J. (1976). The Second Law of Thermodynamics, Dowden, Hutchinson & Ross, Stroudsburg PA.
- Giles, R. (1964). Mathematical Foundations of Thermodynamics, Macmillan, New York, pp. 2, 97.
- Tisza, L. (1966). Generalized Thermodynamics, M.I.T. Press, Cambridge MA, pp. 50, 109, 123.
- Landsberg, P.T. (1978). Thermodynamics and Statistical Mechanics, Oxford University Press, Oxford UK, ISBN 0-19-851142-6, p. 79.
- Planck, M. (1923/1927). Treatise on Thermodynamics, third English edition translated by A. Ogg from the seventh German edition, Longmans, Green & Co., London, page 40.
- Janko, Richard (2004). "Empedocles, "On Nature"". Zeitschrift für Papyrologie und Epigraphik.
- Lavoisier, A.L. & Laplace, P.S. (1780) "Memoir on Heat", Académie Royale des Sciences pp. 4–355
- von Mayer, J.R. (1842) "Remarks on the forces of inorganic nature" in Annalen der Chemie und Pharmacie, 43, 233
- Mayer, J.R. (1845). Die oraganische Bewegung in ihrem Zusammenhange mit dem Stoffwchsel. Ein Beitrag zur Naturkunde, Dechsler, Heilbronn.
- Grove, W. R. (1874). The Correlation of Physical Forces (6th ed.). London: Longmans, Green.
- Hadden, Richard W. (1994). On the shoulders of merchants: exchange and the mathematical conception of nature in early modern Europe. SUNY Press. p. 13. ISBN 0-7914-2011-6., Chapter 1, p. 13
- Smith, D. A. (1980). "Definition of Heat in Open SYstems". Aust. J. Phys 33: 95–105. Retrieved 8 March 2013.
Modern accounts 
- Goldstein, Martin, and Inge F., 1993. The Refrigerator and the Universe. Harvard Univ. Press. A gentle introduction.
- Kroemer, Herbert; Kittel, Charles (1980). Thermal Physics (2nd ed.). W. H. Freeman Company. ISBN 0-7167-1088-9.
- Nolan, Peter J. (1996). Fundamentals of College Physics, 2nd ed. William C. Brown Publishers.
- Oxtoby & Nachtrieb (1996). Principles of Modern Chemistry, 3rd ed. Saunders College Publishing.
- Papineau, D. (2002). Thinking about Consciousness. Oxford: Oxford University Press.
- Serway, Raymond A.; Jewett, John W. (2004). Physics for Scientists and Engineers (6th ed.). Brooks/Cole. ISBN 0-534-40842-7.
- Stenger, Victor J. (2000). Timeless Reality. Prometheus Books. Especially chpt. 12. Nontechnical.
- Tipler, Paul (2004). Physics for Scientists and Engineers: Mechanics, Oscillations and Waves, Thermodynamics (5th ed.). W. H. Freeman. ISBN 0-7167-0809-4.
- Lanczos, Cornelius (1970). The Variational Principles of Mechanics. Toronto: University of Toronto Press. ISBN 0-8020-1743-6.
History of ideas 
- Brown, T.M. (1965). "Resource letter EEC-1 on the evolution of energy concepts from Galileo to Helmholtz". American Journal of Physics 33 (10): 759–765. Bibcode:1965AmJPh..33..759B. doi:10.1119/1.1970980.
- Cardwell, D.S.L. (1971). From Watt to Clausius: The Rise of Thermodynamics in the Early Industrial Age. London: Heinemann. ISBN 0-435-54150-1.
- Guillen, M. (1999). Five Equations That Changed the World. New York: Abacus. ISBN 0-349-11064-6.
- Hiebert, E.N. (1981). Historical Roots of the Principle of Conservation of Energy. Madison, Wis.: Ayer Co Pub. ISBN 0-405-13880-6.
- Kuhn, T.S. (1957) “Energy conservation as an example of simultaneous discovery”, in M. Clagett (ed.) Critical Problems in the History of Science pp.321–56
- Sarton, G.; Joule, J. P.; Carnot, Sadi (1929). "The discovery of the law of conservation of energy". Isis 13: 18–49. doi:10.1086/346430.
- Smith, C. (1998). The Science of Energy: Cultural History of Energy Physics in Victorian Britain. London: Heinemann. ISBN 0-485-11431-3.
- Mach, E. (1872). History and Root of the Principles of the Conservation of Energy. Open Court Pub. Co., IL.
- Poincaré, H. (1905). Science and Hypothesis. Walter Scott Publishing Co. Ltd; Dover reprint, 1952. ISBN 0-486-60221-4., Chapter 8, "Energy and Thermo-dynamics"