He was one of the most prolific and important writers in Old Bulgarian (the Bulgarian recension of Old Church Slavonic). His most significant literary work was Учително евангелие (The Didactic Gospel), usually dated to the first years of the reign of Bulgarian tsarSimeon I, 893 – 894. The work represents a compilation of lectures about a number of church holidays and is the first systematic work treating sermons in Slavic literature. The compilation also features the poetic preface Азбучна молитва (Alphabet Prayer), the first original poetry in Old Church Slavonic.
In 894 Constantine of Preslav wrote the historical work Историкии (Histories), the first historical chronicle in Slavic literature. In 906, by commission from Simeon I, the author translated Четири слова против арианите (Four Epistles against the Arians) by Saint Athanasius of Alexandria, as a response to the beginning of the spread of heresies in medieval Bulgaria. Constantine is also the alleged author of Служба на Методия (Service for Methodius), in which he relates the struggle of Saint Methodius for the recognition of Old Church Slavonic, as well as of Проглас към евангелието (Proclamation of the Holy Gospels) in which he rejects and admonishes the admiration of the foreign language (mean. Greek) and champions Old Bulgarian for the development and elevation of Bulgarian culture.
None of the original works of Constantine of Preslav has survived the burning of Preslav by Byzantine Emperor John I Tzimisces in 972 and the period of Ottoman rule (1396 – 1878). All of his works are known from copies, the earliest of which date back to the 12th and the 13th century.
^The authorship of Histories is questioned by some historiographers - Проданов, Николай. Проблеми на историческата текстология. Върху материал от българската историопис VII–ХХ век, Велико Търново 2006, с. 30–34.