Cryogenic energy storage
Cryogenic energy storage (CES) is the use of low temperature (cryogenic) liquids such as liquid air or liquid nitrogen as energy storage. Both cryogens have been used to power cars. The inventor Peter Dearman initially developed a liquid air car, and then used the technology he developed for grid energy storage. The technology is being piloted at a UK power station.
A liquid air powered car called Liquid Air was built between 1899 and 1902. More recently, a liquid nitrogen vehicle was built. Peter Dearman, a garage inventor in Hertfordshire, UK who had initially developed a liquid air powered car, then put the technology to use as grid energy storage. The Dearman engine differs from former nitrogen engine designs in that the nitrogen is heated by combining it with the heat exchange fluid inside the cylinder of the engine.
Grid energy storage
When it is cheaper (usually at night), electricity is used to cool air from the atmosphere to -195 °C using the Claude Cycle to the point where it liquefies. The liquid air, which takes up one-thousandth of the volume of the gas, can be kept for a long time in a large vacuum flask at atmospheric pressure. At times of high demand for electricity, the liquid air is pumped at high pressure into a heat exchanger, which acts as a boiler. Air from the atmosphere at ambient temperature, or hot water from an industrial heat source, is used to heat the liquid and turn it back into a gas. The massive increase in volume and pressure from this is used to drive a turbine to generate electricity.
In isolation the process is only 25% efficient, but this is greatly increased (to around 50%) when used with a low-grade cold store, such as a large gravel bed, to capture the cold generated by evaporating the cryogen. The cold is re-used during the next refrigeration cycle.
Efficiency is further increased when used in conjunction with a power plant or other source of low-grade heat that would otherwise be lost to the atmosphere. Highview Power Storage claims an AC to AC round-trip efficiency of 70%, by using an otherwise waste heat source at 115°C. The IMechE (Institution of Mechanical Engineers) agrees that these estimates for a commercial-scale plant are realistic. However this number was not checked or confirmed by independent professional institutions.
Currently surplus gaseous nitrogen is produced as a byproduct in the production of oxygen. Oxygen can be used in oxy-combustion coal power plants, enabling CO2 capture and sequestration. This gaseous nitrogen can be liquefied by available liquiefacton capacities for further use. Cryogenic distillation of air is currently the only commercially viable technology for large scale oxygen production.
A 300 kW, 2.5MWh storage capacity pilot cryogenic energy system developed by researchers at the University of Leeds and Highview Power Storage, that uses liquid air (with the CO2 and water removed as they would turn solid at the storage temperature) as the energy store, and low-grade waste heat to boost the thermal re-expansion of the air, has been operating at a 80MW biomass power station in Slough, UK, since 2010. the efficiency is less than 15% because of low efficiency hardware components used, but the engineers are targeting an efficiency of about 60 percent for the next generation of CES based on operation experiences of this system.
The system is based on proven technology, used safely in many industrial processes, and does not require any particularly rare elements or expensive components to manufacture. Dr Tim Fox, the head of Energy at the IMechE says "it uses standard industrial components...., it will last for decades, and it can be fixed with a spanner."
In April 2014 the UK government announced it had given them £8 million to fund the next stage of the demonstration 
- "The 2011 Energy & Environment Winner -CES". The Engineer. 2011-12-02. Retrieved 2012-10-25.
- Rebecca Boyle (2010-08-11). "Grid Could Meet Sudden Energy Demands By Storing Power As Liquid Oxygen". Popsci.
- "Electricity Storage". Institution of Mechanical Engineers. May 2012. Retrieved 2012-10-22.
- Roger Harrabin, BBC Environment analyst (2012-10-01). "Liquid air 'offers energy storage hope'". BBC News, Science and Environment. BBC. Retrieved 2012-10-02.
- Raili Leino (2012-10-22). "Mullistava idea: Tulevaisuuden auto voi kulkea typpimoottorilla". Tekniikka&Talous (in Finnish).
- "The Technology". Dearman Engine Company. 2012.
- "Process". company website. Highview Power Storage. Retrieved 2012-10-07.
- "Cryo Energy System". company website. Highview Power Storage. Retrieved 2012-10-07.
- "Air separation units for coal power plants". Carbon Capture Journal. June 22, 2011.
- Darius Snieckus (2011-12-06). "Liquid air energy-storage set for the big time after German deal". www.rechargenews.com. Retrieved 2012-10-25.
- "Energy storage project wins major award". University of Leeds. 2011-12-06. Retrieved 2012-10-25.