|Molar mass||180.05 g/mol|
|Appearance||Dark red to black liquid|
|Melting point||−22 °C (−8 °F; 251 K)|
|Boiling point||139 to 140 °C (282 to 284 °F; 412 to 413 K) (710 mmHg)
37-38.5 °C (2 mmHg)
|R-phrases||R10 R23/24/25 R42/43 R53|
|S-phrases||S23 S36/37 S45|
|Flash point||26.7 °C (80.1 °F; 299.8 K)|
Except where noted otherwise, data is given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
|what is: / ?)(|
Cyclopentadienylcobalt dicarbonyl is an organocobalt compound with formula (C5H5)Co(CO)2, abbreviated CpCo(CO)2. It is an example of a half-sandwich complex. It is a dark red air sensitive liquid. This compound features one cyclopentadienyl ring that is bound in an η5-manner and two carbonyl ligands. The compound is soluble in common organic solvents and it is best stored under nitrogen.
- Co2(CO)8 + 2 C5H6 → 2 C5H5Co(CO)2 + H2 + 4 CO
- Co(C5H5)2 + 2 CO → C5H5Co(CO)2 + "C5H5"
- CpCo(CO)2 + 2 R2C2 → CpCo(R2C2)2 + 2 CO
This reaction proceeds by coordination of one alkyne, followed by dissociation of the second CO. Although monoalkyne complexes CpCo(CO)(R1C2R2) have not been isolated, their analogs, CpCo(PPh3)(R1C2R2) are known. They are accessible, inter alia, by the following reactions:
- CpCo(CO)2 + PR3 → CO + CpCo(CO)(PR3)
- CpCoL(PR3) + R2C2 → L + CpCo(PR3)(R2C2) (where L = CO or PR3)
CpCo(CO)2 catalyzes the formation of pyridines from a mixture of alkynes and nitriles. Reduction of CpCo(CO)2 with sodium yields the dinuclear radical [Cp2Co2(CO)2]−, which reacts with alkyl halides to give the dialkyl complexes [Cp2Co2(CO)2R2]. Ketones are produced by carbonylation of these dialkyl complexes, regenerating CpCo(CO)2.
- King, R.B.; Stone, F.G.A (1963). "Cyclopentadienyl Metal Carbonyls and Some Derivatives". Inorg. Synth. 7: 99. doi:10.1002/9780470132388.ch31.
- Piper, T.S.; Cotton, F.A.; Wilkinson, G. (1955). "Cyclopentadienyl-carbon monoxide and related compounds of some transitional metals.". Journal of Inorganic and Nuclear Chemistry 1 (3): 165. doi:10.1016/0022-1902(55)80053-X.
- Staeb, T.H.; Chavez, J.; Gleiter, R.; Nuber, Bernhard (2005). "The Role of [η2-Bis(tert-butylsulfonyl)acetylene](carbonyl)(η5-cyclopentadienyl) cobalt(I) as an Intermediate in the Alkyne Dimerisation". Eur. J. Inorg. Chem. 2005 (20): 4090. doi:10.1002/ejic.200500394.
- Pauson, P.L. “Dicarbonyl(cyclopentadienyl)cobalt(I).” Encyclopedia of Reagents for Organic Synthesis. 2001. doi:10.1002/047084289X.rd078