In the United States, all brake fluids must meet Standard No. 116; Motor vehicle brake fluids. Under this standard there are three Department of Transportation (DOT) minimum specifications for brake fluid. They are DOT 3, DOT 4, and DOT 5.1.
DOT 4, like DOT 3 and DOT 5.1, is a polyglycol ether-based fluid (contrasted with DOT 5 which is silicone-based). Fluids such as DOT 3, 4, and 5.1 are hygroscopic and will absorb water from the atmosphere. This degrades the fluid's performance, and if allowed to accumulate over a period of time, can drastically reduce its boiling point. In a passenger car this is usually not much of an issue as the brakes are generally not used so hard, but can be of serious concerns in racecars or motorcycles due to the higher heat generated during their much more aggressive braking.
While a vehicle that uses DOT 3 may also use DOT 4 or 5.1 if the elastomers in the system accept the borate compounds that raise the boiling point, (a temperature upgrade) a vehicle that requires DOT 4 might boil the brake fluid if a DOT 3 (a temperature downgrade,) is used. Additionally, these polyglycol ether based fluids cannot be mixed with DOT 5.0, which is silicone based.
As of 2006[update], most cars produced in the U.S. use DOT 4 brake fluid.
Minimal boiling points for these specifications are as follows (wet boiling point defined as 3.7% water by volume):
|Dry boiling point||Wet boiling point|
|DOT 3||205 °C (401 °F)||140 °C (284 °F)|
|DOT 4||230 °C (446 °F)||155 °C (311 °F)|
|DOT 5||260 °C (500 °F)||180 °C (356 °F)|
|DOT 5.1||260 °C (500 °F)||180 °C (356 °F)|
One particular brand of DOT 4 brake fluid lists the following ingredients on its MSDS:
|Tetraethylene glycol diethyl ether||4353-28-0||10-50|
|DOT 3||Brake fluids||DOT 5|
- Code of Federal Regulations, Title 49 - Transportation, Chapter V - Part 571 - Federal Motor Vehicle Safety Standards (49CFR571), Subpart B, Sec. 571.116 Standard No. 116; Motor vehicle brake fluids
- FMVSS 116 - Brake Fluid Standards