Dichloro(cycloocta-1,5-diene)platinum(II)
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| Dichloro(cycloocta-1,5-diene)platinum(II) | |
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platinum(II)-from-xtal-3D-balls-A.png) |
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| Identifiers | |
| CAS number | 12080-32-9  |
| PubChem | 5702648 |
| ChemSpider | 4642949 |
| Jmol-3D images | Image 1 |
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| Properties | |
| Molecular formula | C8H12Cl2Pt |
| Molar mass | 374.17 g mol−1 |
| Melting point |
285 °C, 558 K, 545 °F |
| Hazards | |
| EU classification |  Xi |
| R-phrases | R36/37/38 |
| S-phrases | S26-S37/39 |
 (verify) (what is:  / ?)Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) |
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| Infobox references | |
Dichloro(1,5-cyclooctadiene)platinum(II) (Pt(cod)Cl2) is an organometallic compound of platinum. This colourless solid, which is a commercially available, is an entry point to other platinum compounds through the displacement of the cod and/or chloride ligands. It is prepared from potassium tetrachloroplatinate and the diene:[1]
- K2PtCl4 + C8H12 → PtCl2C8H12 + 2 KCl
References [edit]
- ^ E. Costa, P. G. Pringle, M. Ravetz (1997). "[(1,2,5,6-N)-1,5-Cyclooctadiene]Dimethyl-Platinum(II)". Inorg. Synth. Inorganic Syntheses 31: 284–286. doi:10.1002/9780470132623.ch49. ISBN 978-0-470-13262-3.
Further reading [edit]
- Ashfaquzzaman Syed, Edwin D. Stevens, Sandra G. Cruz (1984). "Reexamination of the π bonding in dichloro(cycloocta-1,5-diene)platinum". Inorg. Chem. 23 (22): 3673–3674. doi:10.1021/ic00190a053.
- J. L. Butikofer, E. W. Kalberer, W. C. Schuster, and D. M. Roddick, “The Crystal Structure of Dichloro(norbornadiene)platinum(II): A Comparison to Dichloro(cyclooctadiene)platinum(II),” Acta Cryst. C. 2004, m353-m354.
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