Diisopropyl tartrate

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Diisopropyl tartrate
Diisopropyl tartrate.png
Diisopropyl tartrate-3D-balls.png
Identifiers
CAS number 2217-15-4 YesY
PubChem 112972 (-)-isomer
ChemSpider 101254 (-)-isomer
EC number 218-709-0
Jmol-3D images Image 1
Properties
Molecular formula C10H18O6
Molar mass 234.25 g/mol
Boiling point 152 °C (425.2 K) at 16 kPa
Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
 YesY (verify) (what is: YesY/N?)
Infobox references

Diisopropyl tartrate (DIPT) is a diester of tartaric acid. It has a two chiral carbon atoms giving rise to three stereoisomeric variants. It is commonly used in asymmetric synthesis as a catalyst and as chiral building block for pharmaceuticals and agrochemicals. Its main application is in Sharpless epoxidation, where it serves as a chiral ligand to titanium after reaction with titanium isopropoxide.[1]

References[edit]

  1. ^ Katsuki, Tsutomu; Sharpless, K. Barry (1980). "The first practical method for asymmetric epoxidation". J. Am. Chem. Soc. 102 (18): 5974. doi:10.1021/ja00538a077.