|Jmol-3D images||Image 1|
|Molar mass||46.07 g mol−1|
|Density||2.1146 kg/m³ (gas, 0 °C, 1013 mbar)
0.735 g/mL (liquid, -25 °C)
|Melting point||−141 °C; −222 °F; 132 K|
|Boiling point||−24 °C; −11 °F; 249 K|
|Solubility in water||71 g dm−3 (at 20 °C)|
|Vapor pressure||>100 kPa|
|Dipole moment||1.30 D|
heat capacity C
|65.57 J K−1 mol−1|
|Std enthalpy of
|−184.1 kJ mol−1|
|Std enthalpy of
|−1.4604 MJ mol−1|
|GHS signal word||Danger|
|GHS hazard statements||H220|
|GHS precautionary statements||P210, P410+403|
|S-phrases||(S2), S9, S16, S33|
|Flash point||−41 °C; −42 °F; 232 K|
|Autoignition temperature||350 °C; 662 °F; 623 K|
|Related ethers||Diethyl ether
|Supplementary data page|
|n, εr, etc.|
Solid, liquid, gas
|Spectral data||UV, IR, NMR, MS|
| (what is: / ?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
Dimethyl ether (DME), also known as methoxymethane, is the organic compound with the formula CH
3. The simplest ether, it is a colourless gas that is a useful precursor to other organic compounds and an aerosol propellant.
- 2 CH3OH → (CH3)2O + H2O
The required methanol is obtained from synthesis gas (syngas). In principle, the methanol could be obtained from organic waste or biomass. Other possible improvements call for a dual catalyst system that permits both methanol synthesis and dehydration in the same process unit, with no methanol isolation and purification.
Both the one-step and two-step processes above are commercially available. Currently, there is more widespread application of the two-step process since it is relatively simple and start-up costs are relatively low. It is worth mentioning that there is a developing one-step liquid-phase process.
3 + SO
3 → (CH
This application consumes several thousand tons of DME annually.
2O + 2 CO + H2O → 2 CH3COOH
Laboratory reagent and solvent
DME is a low-temperature solvent and extraction agent, applicable to specialised laboratory procedures. Its usefulness is limited by its low boiling point (−23 °C), but the same property facilitates its removal from reaction mixtures. DME is the precursor to the useful alkylating agent, trimethyloxonium tetrafluoroborate.
DME is the main constituent of freezer spray, used as a low temperature source in field testing of electronic components.
It is also a promising fuel in diesel engines, petrol engines (30% DME / 70% LPG), and gas turbines owing to its high cetane number, which is 55, compared to diesel's, which is 40–53. Only moderate modifications are needed to convert a diesel engine to burn DME. The simplicity of this short carbon chain compound leads during combustion to very low emissions of particulate matter, NOx, and CO. For these reasons as well as being sulfur-free, DME meets even the most stringent emission regulations in Europe (EURO5), U.S. (U.S. 2010), and Japan (2009 Japan). Mobil uses DME in their methanol to gasoline process.
DME is being developed as a synthetic second generation biofuel (BioDME), which can be manufactured from lignocellulosic biomass. Currently the EU is considering BioDME in its potential biofuel mix in 2030; the Volvo Group is the coordinator for the European Community Seventh Framework Programme project BioDME where Chemrec's BioDME pilot plant based on black liquor gasification is nearing completion in Piteå, Sweden.
The image below illustrates some of processes from various raw materials to DME.
In 2009 a team of university students from Denmark won the Urban Concept/Internal Combustion class at the European Shell Eco Marathon (The Shell Eco Marathon is an unofficial World Championship for mileage) with a vehicle running on 100% DME. The vehicle drove 589 km/liter, fuel equivalent to gasoline with a 50 ccm 2-stroke engine operating by the Diesel principle. As well as winning they beat the old standing record of 306 km/liter, set by the same team in 2007 
Unlike other alkyl ethers, DME resists autoxidation. DME is also relatively non-toxic, although it is highly flammable.
- "dimethyl ether - PubChem Public Chemical Database". The PubChem Project. USA: National Center for Biotechnology Information.
- Record in the GESTIS Substance Database from the IFA
- Manfred Müller, Ute Hübsch, “Dimethyl Ether” in Ullmann’s Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2005. doi:10.1002/14356007.a08_541
- Dimethyl Ether Technology and Markets 07/08-S3 Report, ChemSystems, December 2008.
- P.S. Sai Prasad et al., Fuel Processing Technology, 2008, 89, 1281.
- Air Products Technology Offerings
- T. J. Curphey (1988), "Trimethyloxonium tetrafluoroborate", Org. Synth.; Coll. Vol. 6: 1019
- "A Pharmacist's Guide to OTC Therapy: OTC Treatments for Warts". July 2006.
- IDA Fact Sheet DME/LPG Blends 2010 v1
- nycomb.se, Nycomb Chemicals company
- http://www.topsoe.com/site.nsf/all/BBNN-5PNJ3F?OpenDocument topsoe.com
- http://www.japantransport.com/conferences/2006/03/dme_detailed_information.pdf, Conference on the Development and Promotion of Environmentally Friendly Heavy Duty Vehicles such as DME Trucks, Washington DC, March 17, 2006
- Biofuels in the European Union, 2006
- Chemrec press release September 9, 2010
- The Danish Ecocar Team - List of achievements
- http://www.mecanica.pub.ro/frigo-eco/R404A_DME.pdf 101110
- http://www.ashrae.org/technology/page/1933#et ASHRAE list of refrigerants