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Ductile iron, also known as ductile cast iron, nodular cast iron, spheroidal graphite iron, spherulitic graphite cast iron and SG iron, is a type of cast iron invented in 1943 by Keith Millis. While most varieties of cast iron are brittle, ductile iron has much more impact and fatigue resistance, due to its nodular graphite inclusions.
On October 25, 1949, Keith Dwight Millis, Albert Paul Gagnebin and Norman Boden Pilling received US patent 2,485,760 on a Cast Ferrous Alloy for ductile iron production via magnesium treatment.
Ductile iron is not a single material but is part of a group of materials which can be produced to have a wide range of properties through control of the microstructure. The common defining characteristic of this group of materials is the shape of the graphite. In ductile irons, the graphite is in the form of nodules rather than flakes as it is in grey iron. The sharp shape of the flakes of graphite create stress concentration points within the metal matrix and the rounded shape of the nodules less so, thus inhibiting the creation of cracks and providing the enhanced ductility that gives the alloy its name. The formation of nodules is achieved by the addition of nodulizing elements, most commonly magnesium (note magnesium boils at 1100°C and iron melts at 1500°C) and, less often now, cerium (usually in the form of Mischmetal). Tellurium has also been used. Yttrium, often a component of Misch metal, has also been studied as a possible nodulizer.
"Austempered Ductile Iron" (ADI) was invented in the 1950s but was commercialized and achieved success only some years later. In ADI, the metallurgical structure is manipulated through a sophisticated heat treating process. The "aus" portion of the name refers to austenite.
A typical chemical analysis of this material:
- Carbon 3.2 to 3.6%
- Silicon 2.2 to 2.8%
- Manganese 0.1 to 0.5%
- Magnesium 0.03 to 0.05%
- Phosphorus 0.005 to 0.04%
- Sulfur 0.005 to 0.02%
- Copper <0.40%
- Iron balance
Other elements such as copper or tin may be added to increase tensile and yield strength while simultaneously reducing ductility. Improved corrosion resistance can be achieved by replacing 15% to 30% of the iron in the alloy with varying amounts of nickel, copper, or chromium.
Much of the annual production of ductile iron is in the form of ductile iron pipe, used for water and sewer lines. It competes with polymeric materials such as PVC, HDPE, LDPE and polypropylene, which are all much lighter than steel or ductile iron, but which, being flexible, require more careful installation and protection from physical damage.
Ductile iron is specifically useful in many automotive components, where strength needs surpass that of aluminum but do not necessarily require steel. Other major industrial applications include off-highway diesel trucks, Class 8 trucks, agricultural tractors, and oil well pumps.
- Smith & Hashemi 2006, p. 432.
- Modern Casting, Inc
- US patent 2485760, Keith Millis, "Cast Ferrous Alloy", issued 1949-10-25
- Asst. Prof. Yaqub, Ejaz, Asst. Prof. Arshad, Rizwan (2009). "ME-140 Workshop Technology - Slide 25" (IMAGES). Air University. Retrieved 2011-10-30.
- Gillespie, LaRoux K. (1988), Troubleshooting manufacturing processes (4th ed.), SME, p. 4-4, ISBN 978-0-87263-326-1.
- "ADI the Material". ADI Treatments Ltd. Retrieved 2010-01-24.
- Smith, William F.; Hashemi, Javad (2006), Foundations of Materials Science and Engineering (4th ed.), McGraw-Hill, ISBN 0-07-295358-6.