|Jmol-3D images||Image 1|
|Molar mass||28.05 g/mol|
|Density||1.178 kg/m3 at 15 °C, gas|
−169.2 °C (104.0 K, -272.6 °F)
−103.7 °C (169.5 K, -154.7 °F)
|Solubility in water||3.5 mg/100 mL (17 °C) ; 2.9 mg/L|
|Solubility in ethanol||4.22 mg/L|
|Solubility in diethyl ether||good|
|Std enthalpy of
|EU classification||Extremely flammable (F+)|
|Flash point||-136 °C|
|Supplementary data page|
|n, εr, etc.|
Solid, liquid, gas
|Spectral data||UV, IR, NMR, MS|
| (what is: / ?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Ethylene (IUPAC name: ethene) is a hydrocarbon with the formula C
4 or H2C=CH2. It is a colorless flammable gas with a faint "sweet and musky" odor when pure. It is the simplest alkene (a hydrocarbon with carbon-carbon double bonds), and the simplest unsaturated hydrocarbon after acetylene (C
Ethylene is widely used in chemical industry, and its worldwide production (over 109 million tonnes in 2006) exceeds that of any other organic compound. Ethylene is also an important natural plant hormone, used in agriculture to force the ripening of fruits.
Structure and properties
This hydrocarbon has four hydrogen atoms bound to a pair of carbon atoms that are connected by a double bond. All six atoms that comprise ethylene are coplanar. The H-C-H angle is 119°, close to the 120° for ideal sp² hybridized carbon. The molecule is also relatively rigid: rotation about the C-C bond is a high energy process that requires breaking the π-bond.
The π-bond in the ethylene molecule is responsible for its useful reactivity. The double bond is a region of high electron density, thus it is susceptible to attack by electrophiles. Many reactions of ethylene are catalyzed by transition metals, which bind transiently to the ethylene using both the π and π* orbitals.
Major industrial reactions of ethylene include in order of scale: 1) polymerization, 2) oxidation, 3) halogenation and hydrohalogenation, 4) alkylation, 5) hydration, 6) oligomerization, and 7) hydroformylation. In the United States and Europe, approximately 90% of ethylene is used to produce three chemical compounds—ethylene oxide, ethylene dichloride, and ethylbenzene—and a variety of kinds of polyethylene.
Polyethylenes of various types consume more than half of world ethylene supply. Polyethylene, also called polythene, is the world's most widely used plastic, being primarily used to make films used in packaging, carrier bags and trash liners. Linear alpha-olefins, produced by oligomerization (formation of short polymers) are used as precursors, detergents, plasticisers, synthetic lubricants, additives, and also as co-monomers in the production of polyethylenes.
Ethylene is oxidized to produce ethylene oxide, a key raw material in the production of surfactants and detergents by ethoxylation. Ethylene oxide is also hydrolyzed to produce ethylene glycol, widely used as an automotive antifreeze as well as higher molecular weight glycols, glycol ethers and polyethylene terephthalate.
Ethylene undergoes oxidation by palladium to give acetaldehyde. This conversion remains a major industrial process (10M kg/y). The process proceeds via the initial complexation of ethylene to a Pd(II) center.
Halogenation and hydrohalogenation
Major intermediates from the halogenation and hydrohalogenation of ethylene include ethylene dichloride, ethyl chloride and ethylene dibromide. The addition of chlorine entails "oxychlorination," i.e. chlorine itself is not used. Some products derived from this group are polyvinyl chloride, trichloroethylene, perchloroethylene, methyl chloroform, polyvinylidene chloride and copolymers, and ethyl bromide.
Major chemical intermediates from the alkylation with ethylene is ethylbenzene, precursor to styrene. Styrene is used principally in polystyrene for packaging and insulation, as well as in styrene-butadiene rubber for tires and footwear. On a smaller scale, ethyltoluene, ethylanilines, 1,4-hexadiene, and aluminium alkyls. Products of these intermediates include polystyrene, unsaturated polyesters and ethylene-propylene terpolymers.
Ethylene has long represented the major nonfermentative precursor to ethanol. The original method entailed its conversion to diethyl sulfate, followed by hydrolysis. The main method practiced since the mid-1990s is the direct hydration of ethylene catalyzed by solid acid catalysts:
- C2H4 + H2O → CH3CH2OH
Dimerization to n-Butenes
Global ethylene production was 107 million tonnes in 2005, 109 million tonnes in 2006. NNFCC Renewable Chemicals Factsheet: Ethanol, 138 million tonnes in 2010 and 141 million tonnes in 2011. By 2010 ethylene was produced by at least 117 companies in 55 countries. To meet the ever increasing demand for ethylene, sharp increases in production facilities are added globally, particularly in the Mideast and in China.
Ethylene is produced in the petrochemical industry by steam cracking. In this process, gaseous or light liquid hydrocarbons are heated to 750–950 °C, inducing numerous free radical reactions followed by immediate quench to stop these reactions. This process converts large hydrocarbons into smaller ones and introduces unsaturation. Ethylene is separated from the resulting complex mixture by repeated compression and distillation. In a related process used in oil refineries, high molecular weight hydrocarbons are cracked over zeolite catalysts. Heavier feedstocks, such as naphtha and gas oils require at least two "quench towers" downstream of the cracking furnaces to recirculate pyrolysis-derived gasoline and process water. When cracking a mixture of ethane and propane, only one water quench tower is required.
The areas of an ethylene plant are:
- steam cracking furnaces:
- primary and secondary heat recovery with quench;
- a dilution steam recycle system between the furnaces and the quench system;
- primary compression of the cracked gas (3 stages of compression);
- hydrogen sulfide and carbon dioxide removal (acid gas removal);
- secondary compression (1 or 2 stages);
- drying of the cracked gas;
- cryogenic treatment;
- all of the cold cracked gas stream goes to the demethanizer tower. The overhead stream from the demethanizer tower consists of all the hydrogen and methane that was in the cracked gas stream. Cryogenically (−250 °F (−157 °C)) treating this overhead stream separates hydrogen from methane. Methane recovery is critical to the economical operation of an ethylene plant.
- the bottom stream from the demethanizer tower goes to the deethanizer tower. The overhead stream from the deethanizer tower consists of all the C
2,'s that were in the cracked gas stream. The C
2 stream contains acetylene, which is explosive above 200 kPa (29 psi). If the partial pressure of acetylene is expected to exceed these values, the C
2 stream is partially hydrogenated. The C
2's then proceed to a C
2 splitter. The product ethylene is taken from the overhead of the tower and the ethane coming from the bottom of the splitter is recycled to the furnaces to be cracked again;
- the bottom stream from the de-ethanizer tower goes to the depropanizer tower. The overhead stream from the depropanizer tower consists of all the C
3's that were in the cracked gas stream. Before feeding the C
3's to the C
3 splitter, the stream is hydrogenated to convert the methylacetylene and propadiene (allene) mix. This stream is then sent to the C
3 splitter. The overhead stream from the C
3 splitter is product propylene and the bottom stream is propane which is sent back to the furnaces for cracking or used as fuel.
- The bottom stream from the depropanizer tower is fed to the debutanizer tower. The overhead stream from the debutanizer is all of the C
4's that were in the cracked gas stream. The bottom stream from the debutanizer (light pyrolysis gasoline) consists of everything in the cracked gas stream that is C
5 or heavier.
Since ethylene production is energy intensive, much effort has been dedicated to recovering heat from the gas leaving the furnaces. Most of the energy recovered from the cracked gas is used to make high pressure (1200 psig) steam. This steam is in turn used to drive the turbines for compressing cracked gas, the propylene refrigeration compressor, and the ethylene refrigeration compressor. An ethylene plant, once running, does not need to import steam to drive its steam turbines. A typical world scale ethylene plant (about 1.5 billion pounds of ethylene per year) uses a 45,000 horsepower (34,000 kW) cracked gas compressor, a 30,000 hp (22,000 kW) propylene compressor, and a 15,000 hp (11,000 kW) ethylene compressor.
Although of great value industrially, ethylene is rarely used in the laboratory and is ordinarily purchased. It can be produced via dehydration of ethanol with sulfuric acid or in the gas phase with aluminum oxide.
Ethylene as a plant hormone
Ethylene serves as a hormone in plants. It acts at trace levels throughout the life of the plant by stimulating or regulating the ripening of fruit, the opening of flowers, and the abscission (or shedding) of leaves. Commercial ripening rooms use "catalytic generators" to make ethylene gas from a liquid supply of ethanol. Typically, a gassing level of 500 to 2,000 ppm is used, for 24 to 48 hours. Care must be taken to control carbon dioxide levels in ripening rooms when gassing, as high temperature ripening (68F) has been seen to produce CO2 levels of 10% in 24 hours.
History of ethylene in plant biology
Ethylene has been used since the ancient Egyptians, who would gash figs in order to stimulate ripening (wounding stimulates ethylene production by plant tissues). The ancient Chinese would burn incense in closed rooms to enhance the ripening of pears. In 1864, it was discovered that gas leaks from street lights led to stunting of growth, twisting of plants, and abnormal thickening of stems. In 1901, a Russian scientist named Dimitry Neljubow showed that the active component was ethylene. Doubt discovered that ethylene stimulated abscission in 1917. It wasn't until 1934 that Gane reported that plants synthesize ethylene. In 1935, Crocker proposed that ethylene was the plant hormone responsible for fruit ripening as well as senescence of vegetative tissues.
Ethylene biosynthesis in plants
Ethylene is produced from essentially all parts of higher plants, including leaves, stems, roots, flowers, fruits, tubers, and seedlings.
"Ethylene production is regulated by a variety of developmental and environmental factors. During the life of the plant, ethylene production is induced during certain stages of growth such as germination, ripening of fruits, abscission of leaves, and senescence of flowers. Ethylene production can also be induced by a variety of external aspects such as mechanical wounding, environmental stresses, and certain chemicals including auxin and other regulators".
Ethylene is biosynthesized from the amino acid methionine to S-adenosyl-L-methionine (SAM, also called Adomet) by the enzyme Met Adenosyltransferase. SAM is then converted to 1-aminocyclopropane-1-carboxylic acid (ACC) by the enzyme ACC synthase (ACS). The activity of ACS determines the rate of ethylene production, therefore regulation of this enzyme is key for the ethylene biosynthesis. The final step requires oxygen and involves the action of the enzyme ACC-oxidase (ACO), formerly known as the ethylene forming enzyme (EFE). Ethylene biosynthesis can be induced by endogenous or exogenous ethylene. ACC synthesis increases with high levels of auxins, especially indole acetic acid (IAA) and cytokinins. ACC synthase is inhibited by abscisic acid.
Ethylene perception in plants
Ethylene could be perceived by a transmembrane protein dimer complex. The gene encoding an ethylene receptor has been cloned in Arabidopsis thaliana and then in tomato. Ethylene receptors are encoded by multiple genes in the Arabidopsis and tomato genomes. The gene family comprises five receptors in Arabidopsis and at least six in tomato, most of which have been shown to bind ethylene. DNA sequences for ethylene receptors have also been identified in many other plant species and an ethylene binding protein has even been identified in Cyanobacteria.
Environmental and biological triggers of ethylene
Environmental cues such as flooding, drought, chilling, wounding, and pathogen attack can induce ethylene formation in plants. In flooding, roots suffer from lack of oxygen, or anoxia, which leads to the synthesis of 1-aminocyclopropane-1-carboxylic acid (ACC). ACC is transported upwards in the plant and then oxidized in leaves. The ethylene produced causes nastic movements of the leaves.
Physiological responses of plants
Like the other plant hormones, ethene is considered to have pleiotropic effects. This essentially means that it is thought that at least some of the effects of the hormone are unrelated. What is actually caused by the gas may depend on the tissue affected as well as environmental conditions. In the evolution of plants, ethene would simply be a message that was coopted for unrelated uses by plants during different periods of the evolutionary development.
List of plant responses to ethene
- Seedling triple response, thickening and shortening of hypocotyl with pronounced apical hook.
- In pollination, when the pollen reaches the stigma, the precursor of the ethene, ACC, is secreted to the petal, the ACC releases ethylene with ACC oxidase.
- Stimulates leaf and flower senescence
- Stimulates senescence of mature xylem cells in preparation for plant use
- Induces leaf abscission
- Induces seed germination
- Induces root hair growth — increasing the efficiency of water and mineral absorption
- Induces the growth of adventitious roots during flooding
- Stimulates epinasty — leaf petiole grows out, leaf hangs down and curls into itself
- Stimulates fruit ripening
- Induces a climacteric rise in respiration in some fruit which causes a release of additional ethylene.
- Affects gravitropism
- Stimulates nutational bending
- Inhibits stem growth and stimulates stem and cell broadening and lateral branch growth outside of seedling stage (see Hyponastic response)
- Interference with auxin transport (with high auxin concentrations)
- Inhibits shoot growth and stomatal closing except in some water plants or habitually flooded ones such as some rice varieties, where the opposite occurs (conserving CO
2 and O
- Induces flowering in pineapples
- Inhibits short day induced flower initiation in Pharbitus nil and Chrysanthemum morifolium
Ethene shortens the shelf life of many fruits by hastening fruit ripening and floral senescence. Ethene will shorten the shelf life of cut flowers and potted plants by accelerating floral senescence and floral abscission. Flowers and plants which are subjected to stress during shipping, handling, or storage produce ethene causing a significant reduction in floral display. Flowers affected by ethene include carnation, geranium, petunia, rose, and many others.
Ethene can cause significant economic losses for florists, markets, suppliers, and growers. Researchers have developed several ways to inhibit ethene, including inhibiting ethene synthesis and inhibiting ethene perception. Aminoethoxyvinylglycine (AVG), Aminooxyacetic acid (AOA), and silver salts are ethylene inhibitors. Inhibiting ethene synthesis is less effective for reducing post-harvest losses since ethene from other sources can still have an effect. By inhibiting ethene perception, fruits, plants and flowers don't respond to ethene produced endogenously or from exogenous sources. Inhibitors of ethene perception include compounds that have a similar shape to ethene, but do not elicit the ethene response. One example of an ethene perception inhibitor is 1-methylcyclopropene (1-MCP).
Commercial growers of bromeliads, including pineapple plants, use ethene to induce flowering. Plants can be induced to flower either by treatment with the gas in a chamber, or by placing a banana peel next to the plant in an enclosed area.
Chrysanthemum flowering is delayed by ethene gas and growers have found that carbon dioxide 'burners' and the exhaust fumes from inefficient glasshouse heaters can raise the ethene concentration to 0.05 vpm causing delay in flowering of commercial crops.
Ethylene is a ligand in organometallic chemistry. One of the first organometallic compounds, Zeise's salt is a complex of ethylene. Useful reagents containing ethylene include Pt(PPh3)2(C2H4) and Rh2Cl2(C2H4)4. The Rh-catalysed hydroformylation of ethylene is conducted on industrial scale to provide propionaldehyde.
Ethylene appears to have been discovered by Johann Joachim Becher, who obtained it by heating ethanol with sulfuric acid; he mentioned the gas in his Physica Subterranea (1669). Joseph Priestley also mentions the gas in his Experiments and observations relating to the various branches of natural philosophy: with a continuation of the observations on air (1779), where he reports that Jan Ingenhousz saw ethylene synthesized in the same way by a Mr. Enée in Amsterdam in 1777 and that Ingenhousz subsequently produced the gas himself. The properties of ethylene were studied in 1795 by four Dutch chemists, Johann Rudolph Deimann, Adrien Paets van Troostwyck, Anthoni Lauwerenburgh and Nicolas Bondt, who found that it differed from hydrogen gas and that it contained both carbon and hydrogen. This group also discovered that ethylene could be combined with chlorine to produce the oil of the Dutch chemists, 1,2-dichloroethane; this discovery gave ethylene the name used for it at that time, olefiant gas (oil-making gas.)
In the mid-19th century, the suffix -ene (an Ancient Greek root added to the end of female names meaning "daughter of") was widely used to refer to a molecule or part thereof that contained one fewer hydrogen atoms than the molecule being modified. Thus, ethylene (C
4) was the "daughter of ethyl" (C
5). The name ethylene was used in this sense as early as 1852.
In 1866, the German chemist August Wilhelm von Hofmann proposed a system of hydrocarbon nomenclature in which the suffixes -ane, -ene, -ine, -one, and -une were used to denote the hydrocarbons with 0, 2, 4, 6, and 8 fewer hydrogens than their parent alkane. In this system, ethylene became ethene. Hofmann's system eventually became the basis for the Geneva nomenclature approved by the International Congress of Chemists in 1892, which remains at the core of the IUPAC nomenclature. However, by that time, the name ethylene was deeply entrenched, and it remains in wide use today, especially in the chemical industry.
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|Wikimedia Commons has media related to: Ethylene|
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