The triangle illustrates the three elements a fire needs to ignite: heat, fuel, and an oxidizing agent (usually oxygen). A fire naturally occurs when the elements are present and combined in the right mixture, and a fire can be prevented or extinguished by removing any one of the elements in the fire triangle. For example, covering a fire with a fire blanket removes the "oxygen" part of the triangle and can extinguish a fire.
The fire tetrahedron represents the addition of a component, the chemical chain reaction, to the three already present in the fire triangle. Once a fire has started, the resulting exothermic chain reaction sustains the fire and allows it to continue until or unless at least one of the elements of the fire is blocked. Foam can be used to deny the fire the oxygen it needs. Water can be used to lower the temperature of the fuel below the ignition point or to remove or disperse the fuel. Halon can be used to remove free radicals and create a barrier of inert gas in a direct attack on the chemical reaction responsible for the fire.
Combustion is the chemical reaction that feeds a fire more heat and allows it to continue. When the fire involves burning metals like lithium, magnesium, titanium, etc. (known as a class-D fire), it becomes even more important to consider the energy release. The metals react faster with water than with oxygen and thereby more energy is released. Putting water on such a fire results in the fire getting hotter or even exploding. Carbon dioxide extinguishers are ineffective against certain metals such as titanium. Therefore, inert agents (e.g. dry sand) must be used to break the chain reaction of metallic combustion.
In the same way, as soon as one of the four elements of the tetrahedron is removed, combustion stops.
The oxidizer is the other reactive of the chemical reaction. In most cases, it is the ambient air, and in particular one of its components, Oxygen (O2). By depriving a fire of air, it can be extinguished; for example, when covering the flame of a small candle with an empty glass, fire stops; to the contrary, if air is blown over a wood fire with bellows, the fire is activated by the introduction of more air. In certain torches, dioxygen is introduced to improve combustion.
In certain cases such as some explosives, the oxidizer and combustible are the same (e.g., nitroglycerin, an unstable molecule that has oxidizing parts in the same molecule as the oxidizeable parts).
Reaction is initiated by an activating energy, in most cases, it is heat. Several examples include friction, as in case of matches, heating an electrical wire, a flame (propagation of fire), or a spark (from a lighter or from any starting electrical device). There are also many other ways to bring sufficient activation energy including electricity, radiation, and pressure, all of which will lead to a temperature rise. In most cases, heat production enables self-sustainability of the reaction, and enables a chain reaction to grow. The temperature at which a liquid produces sufficient vapor to get a flammable mix with self-sustainable combustion is called its flash-point.
Extinction of the fire
To stop a combustion reaction, one of the three elements of the fire-triangle has to be removed.
Without sufficient heat, a fire cannot begin, and it cannot continue. Heat can be removed by the application of a substance which reduces the amount of heat available to the fire reaction. This is often water, which requires heat for phase change from water to steam. Introducing sufficient quantities and types of powder or gas in the flame reduces the amount of heat available for the fire reaction in the same manner. Scraping embers from a burning structure also removes the heat source. Turning off the electricity in an electrical fire removes the ignition source.
Without fuel, a fire will stop. Fuel can be removed naturally, as where the fire has consumed all the burnable fuel, or manually, by mechanically or chemically removing the fuel from the fire. Fuel separation is an important factor in wildland fire suppression, and is the basis for most major tactics, such as controlled burns. The fire stops because a lower concentration of fuel vapor in the flame leads to a decrease in energy release and a lower temperature. Removing the fuel thereby decreases the heat.
Without sufficient oxygen, a fire cannot begin, and it cannot continue. With a decreased oxygen concentration, the combustion process slows. Oxygen can be denied to a fire using a carbon dioxide fire extinguisher or a fire blanket.
Role of water in fire-fighting
Water can have two different roles. In the case of a solid combustible, the solid fuel produce pyrolyzing products under the influence of heat, commonly radiation. This process is halted by the application of water, since water is more easily evaporated than the fuel is pyrolyzed. Thereby energy is removed from the fuel surface and it is cooled and the pyrolyze is stopped, removing the fuel supply to the flames. In fire fighting, this is referred to as surface cooling
In the gas phase, i.e. in the flames or in the smoke, the combustible can not be separated from the oxidizer, and the only possible action consists of cooling down. In this case, water droplets are evaporated in the gas phase, thereby lowering the temperature and adding water vapour making the gas mixture non combustible. This requires droplets of a size less than about 0.2 mm. In fire fighting, this is referred to as gas cooling or smoke cooling.
There also exist cases where the ignition factor is not the activation energy. For example, smoke explosion is a very violent combustion of unburned gases contained in the smoke created by a sudden fresh air input (oxidizer input). The interval in which an air/gas mix can burn is limited by the explosive limits of the air. This interval can be very small (kerosene) or large (acetylene).
Water cannot be used on certain type of fires:
- Fires where live electricity is present — as water conducts electricity it presents an electrocution hazard.
- Hydrocarbon fires — as it will only spread the fire because of the difference in density.
- Metal fires — as these fires produce huge amounts of energy (up to 7.550 calories/kg for aluminum) and water can also create violent chemical reactions with burning metal (by oxidization) .
- Fat fires — as vapour will carry and spread burning oil everywhere.
Since these reactions are well-understood, it has been possible to create specific water-additives which will allow:
- A better heat absorption with a higher density than water.
- Carrying free radical catchers on the fire.
- Carrying foaming agents to enable water to stay on the surface of a liquid fire and prevent gas release.
- Carrying specific reactives which will react and change the nature of the burning material.
Water-additives are generally designed to be effective on several categories of fires (class A + class B or even class A + class B + class F), meaning a better global performance and usability of a single extinguisher on many different types of fires (or fires that involve several different classes of materials).
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- IFSTA (2008). "Essentials of Fire Fighting and Fire Department Operations 5th Edition"