Formal charge

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Formal charge in ozone and the nitrate anion

Where V is the number of valence electrons of the atom in isolation (atom in ground state); N is the number of non-bonding valence electrons on this atom in the molecule; and B is the total number of electrons shared in covalent bonds with other atoms in the molecule. There are two electrons shared per single covalent bond.

When determining the correct Lewis structure (or predominant resonance structure) for a molecule, the structure is chosen such that the formal charge (without sign) on each of the atoms is minimized.

An alternative method for assigning charge to an atom taking into account electronegativity is by oxidation number. Other related concepts are valence, which counts the number of electrons that an atom uses in bonding, and coordination number, the number of atoms bonded to the atom of interest.

Examples[edit]

Ammonium

Ammonium NH4+ is a cationic species. By using the vertical groups of the atoms on the periodic table it is possible to determine that each hydrogen contributes 1 electron, the nitrogen contributes 5 valence electrons, and the charge of +1 means that 1 electron is absent. The final total is 8 total electrons (1 × 4 + 5 − 1). Drawing the Lewis structure gives an sp3 (4 bonds) hybridized nitrogen atom surrounded by hydrogen. There are no lone pairs of electrons left. Thus, using the definition of formal charge, hydrogen has a formal charge of zero (1- (0 + ½ × 2)) and nitrogen has a formal charge of +1 (5− (0 + ½ × 8)). After adding up all the formal charges throughout the molecule the result is a total formal charge of +1, consistent with the charge of the molecule given in the first place.

Note: The total formal charge in a molecule should be as close to zero as possible, with as few charges on the molecule as possible

  • Example: CO2 is a neutral molecule with 16 total valence electrons. There are three different ways to draw the Lewis structure
    • Carbon single bonded to both oxygen atoms (carbon = +2, oxygens = -1 each, total formal charge = 0)
    • Carbon single bonded to one oxygen and double bonded to another (carbon = +1, oxygendouble = 0, oxygensingle = −1, total formal charge = 0)
    • Carbon double bonded to both oxygen atoms (carbon = 0, oxygens = 0, total formal charge =0)

Even though all three structures gave us a total charge of zero, the final structure is the superior one because there are no charges in the molecule at all.

Alternative method[edit]

The following is equivalent:

  • Draw a circle around the atom for which the formal charge is requested (as with carbon dioxide, below)
Ls1.png
  • Count up the number of electrons in the atom's "circle." Since the circle cuts the covalent bond "in half," each covalent bond counts as one electron instead of two.
  • Subtract the number of electrons in the circle from the group number of the element (the Roman numeral from the older system of group numbering, NOT the IUPAC 1-18 system) to determine the formal charge.
Ls3a.png
  • The formal charges computed for the remaining atoms in this Lewis structure of carbon dioxide are shown below.
Ls4.png

It is important to keep in mind that formal charges are just that-formal, in the sense that this system is a formalism. The formal charge system is just a method to keep track of all of the valence electrons that each atom brings with it when the molecule is formed.

Formal charge compared to oxidation state[edit]

The concept of oxidation states constitutes a competing method to assess the distribution of electrons in molecules. If the formal charges and oxidation states of the atoms in carbon dioxide are compared, the following values are arrived at:

Co2comp.png

The reason for the difference between these values is that formal charges and oxidation states represent fundamentally different ways of looking at the distribution of electrons amongst the atoms in the molecule. With formal charge, the electrons in each covalent bond are assumed to be split exactly evenly between the two atoms in the bond (hence the dividing by two in the method described above). The formal charge view of the CO2 molecule is essentially shown below:

Co2-1.png

The covalent (sharing) aspect of the bonding is overemphasized in the use of formal charges, since in reality there is a higher electron density around the oxygen atoms due to their higher electronegativity compared to the carbon atom. This can be most effectively visualized in an electrostatic potential map.

With the oxidation state formalism, the electrons in the bonds are "awarded" to the atom with the greater electronegativity. The oxidation state view of the CO2 molecule is shown below:

Co2-2.png

Oxidation states overemphasize the ionic nature of the bonding; most chemists agree that the difference in electronegativity between carbon and oxygen is insufficient to regard the bonds as being ionic in nature.

In reality, the distribution of electrons in the molecule lies somewhere between these two extremes. The inadequacy of the simple Lewis structure view of molecules led to the development of the more generally applicable and accurate valence bond theory of Slater, Pauling, et al., and henceforth the molecular orbital theory developed by Mulliken and Hund.

External links[edit]

  • Formal charge @ Georgia Southern University Link
  • Formal charge exercise @ Michigan State University Link
  • Even more formal charge exercises @ the University of Southern Maine Link