Fiberglass

From Wikipedia, the free encyclopedia
  (Redirected from Glass-fibre)
Jump to: navigation, search
This article is about the plastic composite. For the insulation material, see glass wool. For the fiber itself, see glass fiber.

Fiberglass (or fibreglass) is the common name for glass-reinforced plastic (GRP)[1] or alternatively glass-fiber reinforced plastic (GFRP)[2] Fiberglass is also known as GFK, for German: Glasfaserverstärkter Kunststoff.

Fiberglass is a fiber reinforced polymer made of plastic reinforced by glass fibers, commonly woven into a mat. The plastic may be a thermosetting plastic- most often epoxy, polyester- or vinylester or a thermoplastic.

Fiberglass is a strong lightweight material and is used for many products. Although it's not as strong and stiff as carbon fiber it is less brittle, and its raw materials are much cheaper. Its bulk strength and weight are also better than many metals, and it can be more readily molded into complex shapes. Applications of fiberglass include, aircraft, boats, automobiles, bath tubs and enclosures, hot tubs, septic tanks, water tanks, roofing, pipes, cladding, casts, surfboards, and external door skins.

Fiber[edit]

Glass reinforcements used for fiberglass are supplied in different physical forms, microspheres, chopped or woven.

Unlike glass fibers used for insulation, for the final structure to be strong, the fiber's surfaces must be almost entirely free of defects, as this permits the fibers to reach gigapascal tensile strengths. If a bulk piece of glass were defect-free, it would be equally as strong as glass fibers; however, it is generally impractical to produce bulk material in a defect-free state outside of laboratory conditions.[3]

Production[edit]

The process of manufacturing fibreglass is called pultrusion. The manufacturing process for glass fibers suitable for reinforcement uses large furnaces to gradually melt the silica sand, limestone, kaolin clay, fluorspar, colemanite, dolomite and other minerals to liquid form. It is then extruded through bushings, which are bundles of very small orifices (typically 5–25 micrometres in diameter for E-Glass, 9 micrometres for S-Glass). These filaments are then sized (coated) with a chemical solution. The individual filaments are now bundled in large numbers to provide a roving. The diameter of the filaments, and the number of filaments in the roving, determine its weight, typically expressed in one of two measurement systems:

  • yield, or yards per pound (the number of yards of fiber in one pound of material; thus a smaller number means a heavier roving). Examples of standard yields are 225yield, 450yield, 675yield.
  • tex, or grams per km (how many grams 1 km of roving weighs, inverted from yield; thus a smaller number means a lighter roving). Examples of standard tex are 750tex, 1100tex, 2200tex.

These rovings are then either used directly in a composite application such as pultrusion, filament winding (pipe), gun roving (where an automated gun chops the glass into short lengths and drops it into a jet of resin, projected onto the surface of a mold), or in an intermediary step, to manufacture fabrics such as chopped strand mat (CSM) (made of randomly oriented small cut lengths of fiber all bonded together), woven fabrics, knit fabrics or uni-directional fabrics.

Sizing[edit]

A coating or primer is applied to the roving to:

  • Help protect the glass filaments for processing and manipulation.
  • Ensure proper bonding to the resin matrix, thus allowing for transfer of shear loads from the glass fibers to the thermoset plastic. Without this bonding, the fibers can 'slip' in the matrix, causing localised failure.[citation needed].

Properties[edit]

An individual structural glass fiber is both stiff and strong in tension and compression—that is, along its axis. Although it might be assumed that the fiber is weak in compression, it is actually only the long aspect ratio of the fiber which makes it seem so; i.e., because a typical fiber is long and narrow, it buckles easily.[3] On the other hand, the glass fiber is weak in shear—that is, across its axis. Therefore, if a collection of fibers can be arranged permanently in a preferred direction within a material, and if they can be prevented from buckling in compression, the material will be preferentially strong in that direction.

Furthermore, by laying multiple layers of fiber on top of one another, with each layer oriented in various preferred directions, the material's overall stiffness and strength can be efficiently controlled. In fiberglass, it is the plastic matrix which permanently constrains the structural glass fibers to directions chosen by the designer. With chopped strand mat, this directionality is essentially an entire two dimensional plane; with woven fabrics or unidirectional layers, directionality of stiffness and strength can be more precisely controlled within the plane.

A fiberglass component is typically of a thin "shell" construction, sometimes filled on the inside with structural foam, as in the case of surfboards. The component may be of nearly arbitrary shape, limited only by the complexity and tolerances of the mold used for manufacturing the shell.

Material Specific gravity Tensile strength MPa (ksi) Compressive strength MPa (ksi)
Polyester resin (Not reinforced)[4] 1.28 55 (7.98) 140 (20.3)
Polyester and Chopped Strand Mat Laminate 30% E-glass[4] 1.4 100 (14.5) 150 (21.8)
Polyester and Woven Rovings Laminate 45% E-glass[4] 1.6 250 (36.3) 150 (21.8)
Polyester and Satin Weave Cloth Laminate 55% E-glass[4] 1.7 300 (43.5) 250 (36.3)
Polyester and Continuous Rovings Laminate 70% E-glass[4] 1.9 800 (116) 350 (50.8)
E-Glass Epoxy composite[5] 1.99 1,770 (257)
S-Glass Epoxy composite[5] 1.95 2,358 (342)

Applications[edit]

Fiberglass is an immensely versatile material due to its light weight, inherent strength, weather-resistant finish and variety of surface textures.

The development of fiber-reinforced plastic for commercial use was extensively researched in the 1930s. It was of particular interest to the aviation industry. A means of mass production of glass strands was accidentally discovered in 1932 when a researcher at Owens-Illinois directed a jet of compressed air at a stream of molten glass and produced fibers. After Owens merged with the Corning company in 1935, Owens Corning adapted the method to produce its patented "Fiberglas" (one "s"). A suitable resin for combining the "Fiberglas" with a plastic was developed in 1936 by du Pont. The first ancestor of modern polyester resins is Cyanamid's of 1942. Peroxide curing systems were used by then.

During World War II, fiberglass was developed as a replacement for the molded plywood used in aircraft radomes (fiberglass being transparent to microwaves). Its first main civilian application was for the building of boats and sportscar bodies, where it gained acceptance in the 1950s. Its use has broadened to the automotive and sport equipment sectors. In some aircraft production, fiberglass is now yielding to carbon fiber, which weighs less and is stronger by volume and weight.

Advanced manufacturing techniques such as pre-pregs and fiber rovings extend fiberglass's applications and the tensile strength possible with fiber-reinforced plastics.

Fiberglass is also used in the telecommunications industry for shrouding antennas, due to its RF permeability and low signal attenuation properties. It may also be used to conceal other equipment where no signal permeability is required, such as equipment cabinets and steel support structures, due to the ease with which it can be molded and painted to blend with existing structures and surfaces. Other uses include sheet-form electrical insulators and structural components commonly found in power-industry products.

Because of fiberglass's light weight and durability, it is often used in protective equipment such as helmets. Many sports use fiberglass protective gear, such as goaltenders' and catchers' masks.

Storage tanks[edit]

Several large fiberglass tanks at an airport

Storage tanks can be made of fiberglass with capacities up to about 300 tonnes. Smaller tanks can be made with chopped strand mat cast over a thermoplastic inner tank which acts as a preform during construction. Much more reliable tanks are made using woven mat or filament wound fibre, with the fibre orientation at right angles to the hoop stress imposed in the side wall by the contents. Such tanks tend to be used for chemical storage because the plastic liner (often polypropylene) is resistant to a wide range of corrosive chemicals. Fiberglass is also used for septic tanks.

House building[edit]

A fiberglass dome house in Davis, California

Glass-reinforced plastics are also used to produce house building components such as roofing laminate, door surrounds, over-door canopies, window canopies and dormers, chimneys, coping systems, and heads with keystones and sills. The material's reduced weight and easier handling, compared to wood or metal, allows faster installation. Mass-produced fiberglass brick-effect panels can be used in the construction of composite housing, and can include insulation to reduce heat loss.

Piping[edit]

GRP and GRE pipe can be used in a variety of above- and below-ground systems, including those for:

  • Firewater
  • Cooling water
  • Drinking water
  • Wastewater/sewage
  • Natural gas

Construction methods[edit]

Fiberglass hand lay-up operation[edit]

A release agent, usually in either wax or liquid form, is applied to the chosen mold to allow finished product to be cleanly removed from the mold. Resin—typically a 2-part polyester, vinyl or epoxy—is mixed with its hardener and applied to the surface. Sheets of fibreglass matting are laid into the mold, then more resin mixture is added using a brush or roller. The material must conform to the mold, and air must not be trapped between the fiberglass and the mold. Additional resin is applied and possibly additional sheets of fiberglass. Hand pressure, vacuum or rollers are used to be sure the resin saturates and fully wets all layers, and that any air pockets are removed. The work must be done quickly, before the resin starts to cure, unless high temperature resins are used which will not cure until the part is warmed in an oven.[6] In some cases, the work is covered with plastic sheets and vacuum is drawn on the work to remove air bubbles and press the fiberglass to the shape of the mold.[7]

Fiberglass spray lay-up operation[edit]

The fiberglass spray lay-up process is similar to the hand lay-up process, but differs in the application of the fiber and resin to the mold. Spray-up is an open-molding composites fabrication process where resin and reinforcements are sprayed onto a mold. The resin and glass may be applied separately or simultaneously "chopped" in a combined stream from a chopper gun. Workers roll out the spray-up to compact the laminate. Wood, foam or other core material may then be added, and a secondary spray-up layer imbeds the core between the laminates. The part is then cured, cooled and removed from the reusable mold.

Pultrusion operation[edit]

Diagram of the pultrusion process.

Pultrusion is a manufacturing method used to make strong, lightweight composite materials. In pultrusion, material is pulled through forming machinery using either a hand-over-hand method or a continuous-roller method (as opposed to extrusion, where the material is pushed through dies). In fiberglass pultrusion, fibers (the glass material) are pulled from spools through a device that coats them with a resin. They are then typically heat-treated and cut to length. Fiberglass produced this way can be made in a variety of shapes and cross-sections, such as W or S cross-sections.

Chopped strand mat[edit]

Chopped strand mat or CSM is a form of reinforcement used in fiberglass. It consists of glass fibers laid randomly across each other and held together by a binder.

It is typically processed using the hand lay-up technique, where sheets of material are placed in a mold and brushed with resin. Because the binder dissolves in resin, the material easily conforms to different shapes when wetted out. After the resin cures, the hardened product can be taken from the mold and finished.

Using chopped strand mat gives a fiberglass with isotropic in-plane material properties.

Warping[edit]

One notable feature of fiberglass is that the resins used are subject to contraction during the curing process. For polyester this contraction is often 5–6%; for epoxy, about 2%. Because the fibers don't contract, this differential can create changes in the part's shape during curing. Distortions can appear hours, days or weeks after the resin has set.

While this distortion can be minimised by symmetric use of the fibers in the design, a certain amount of internal stress is created; and if they become too great, cracks form.

Health problems[edit]

Air flow test for the extraction and filtration of styrene vapors in a production hall for GRP yachts

In June 2011, the National Toxicology Program (NTP) removed from its Report on Carcinogens all biosoluble glass wool used in home and building insulation and for non-insulation products.[8] However, NTP considers fibrous glass dust to be "reasonably anticipated [as] a human carcinogen (Certain Glass Wool Fibers (Inhalable))".[9] Similarly, California's Office of Environmental Health Hazard Assessment ("OEHHA") published a November, 2011 modification to its Proposition 65 listing to include only "Glass wool fibers (inhalable and biopersistent)."[10] The actions of U.S. NTP and California's OEHHA mean that a cancer warning label for biosoluble fiber glass home and building insulation is no longer required under federal or California law. All fiberglass wools commonly used for thermal and acoustical insulation were reclassified by the International Agency for Research on Cancer ("IARC") in October 2001 as Not Classifiable as to carcinogenicity to humans (Group 3).[11]

The European Union and Germany classify synthetic vitreous fibers as possibly or probably carcinogenic, but fibers can be exempt from this classification if they pass specific tests. Evidence for these classifications is primarily from studies on experimental animals and mechanisms of carcinogenesis. The glass wool epidemiology studies have been reviewed by a panel of international experts convened by the International Agency for Research on Cancer ("IARC"). These experts concluded: "Epidemiologic studies published during the 15 years since the previous IARC monographs review of these fibres in 1988 provide no evidence of increased risks of lung cancer or mesothelioma (cancer of the lining of the body cavities) from occupational exposures during the manufacture of these materials, and inadequate evidence overall of any cancer risk."[11] Similar reviews of the epidemiology studies have been conducted by the Agency for Toxic Substances and Disease Registry ("ATSDR"),[12] the National Toxicology Program,[13] the National Academy of Sciences[14] and Harvard's Medical and Public Health Schools[15] which reached the same conclusion as IARC that there is no evidence of increased risk from occupational exposure to glass wool fibers.

Fiberglass will irritate the eyes, skin, and the respiratory system. Potential symptoms include irritation of eyes, skin, nose, throat, dyspnea (breathing difficulty); sore throat, hoarseness and cough.[16] Scientific evidence demonstrates that fiber glass is safe to manufacture, install and use when recommended work practices are followed to reduce temporary mechanical irritation.[17]

Fiberglass is resistant to mold but growth can occur if fiberglass becomes wet and contaminated with organic material. Fiberglass insulation that has become wet should be inspected for evidence of residual moisture and contamination. Contaminated fiberglass insulation should be promptly removed.[18]

While the resins are cured, styrene vapors are released. These are irritating to mucous membranes and respiratory tract. Therefore, the Hazardous Substances Ordinance in Germany dictates a maximum occupational exposure limit of 86 mg/m³. In certain concentrations may even occur a potentially explosive mixture. Further manufacture of GRP components (grinding, cutting, sawing) creates fine dusts and chips containing glass filaments, as well as tacky dust, in quantities substantial enough to affect people's health and the functionality of machines and equipment. The installation of effective extraction and filtration equipment is required to ensure safety and efficiency.[19]

Examples of fiberglass use[edit]

Kayaks made of fiberglass

See also[edit]

References[edit]

  1. ^ Mayer, Rayner M. (1993), Design with reinforced plastics, Springer, p. 7, ISBN 978-0-85072-294-9 
  2. ^ Nawy, Edward G. (2001), Fundamentals of high-performance concrete (2 ed.), John Wiley and Sons, p. 310, ISBN 978-0-471-38555-4 
  3. ^ a b J E Gordon (28 March 1991). The New Science of Strong Materials: Or Why You Don't Fall Through the Floor. Penguin Books Limited. ISBN 978-0-14-192770-1. Retrieved 12 June 2012. 
  4. ^ a b c d e East Coast Fibreglass Supplies: Guide to Glass Reinforced Plastics
  5. ^ a b Tube Properties
  6. ^ Forbes Aird (1 April 1996). Fiberglass & Composite Materials: An Enthusiast's Guide to High Performance Non-Metallic Materials for Automotive Racing and Marine Use. Penguin. pp. 86–. ISBN 978-1-55788-239-4. Retrieved 12 June 2012. 
  7. ^ An Introduction to Vacuum Bagging Composites, NextCraft.
  8. ^ Department of Health and Human Services (2011), National Institute of Environmental Health Sciences, National toxicology Program, Fact Sheet, "The Report on Carcinogens," June 2011, retrieved 2013-02-05 
  9. ^ https://www.osha.gov/dts/chemicalsampling/data/CH_242120.html
  10. ^ 46-Z California Regulatory Notice Register, P.1878 (November 18, 2011).
  11. ^ a b IARC Press Release, 24 October 2001 (http://www.iarc.fr/en/media-centre/pr/2001/pr137.html)
  12. ^ Toxicological Profile for SynthethicVitreous Fibers (U.S. Department of Health and Human Services, Public Health Services, Agency for Toxic Substances and Disease Registry), September 2004, pp. 5, 18
  13. ^ Charles William Jameson, "Comments on the National Toxicology Program's Actions In Removing Biosoluble Glass Wool Fibers From The Report On Carcinogens," September 9, 2011.
  14. ^ NRC Subcommittee on Manufactured Vitreous Fibers. 2000. Review of the U.S. Navy's Exposure Standard for Manufactured Vitreous Fibers. National Academy of Sciences, National Research Council, Washington, D.C.: National Academy Press.
  15. ^ Lee, I-Min, et al, "Man-made Vitreous Fibers and Risk of Respiratory System Cancer: A Review of the Epidemiologic Evidence" 37 J. Occup. & Env. Med. 725 (1995).
  16. ^ Labor, United States Department of (2005), Occupational Safety & Health Administration, Chemical Sampling Information, CAS Registry Number: 65997-17-3 (Fibrous Glass)
  17. ^ North American Insulation Manufacturers Association ("NAIMA"), Insulation Facts #62 "Health and Safety Facts for Fiber Glass", Pub. No. N040, May 2012.
  18. ^ Corning, Owens (2007), Fiberglass Thermal Batt, Product Data Sheet, retrieved 2012-02-23 
  19. ^ Türschmann/Jakschik/Rother: White Paper, Topic: "Clean Air in the Manufacture of Glass Fibre Reinforced Plastic (GRP) Parts", March 2011
  20. ^ "Flexible Pavement Preservation Ch. 12 Interlayers". Caltrans Division of Maintenance. January 27, 2009. 
  21. ^ Staheli, Lynn T. (2006), Practice of Pediatric Orthopedics (2nd ed.), Lippincott Williams & Wilkins, p. 68, ISBN 9781582558189