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Green's first identity
This identity is derived from the divergence theorem applied to the vector field F = ψ∇φ: Let φ and ψ be scalar functions defined on some region U ⊂ R3, and suppose that φ is twice continuously differentiable, and ψ is once continuously differentiable. Then
where is the Laplace operator, ∂U is the boundary of region U, n is the outward pointing unit normal of surface element dS and dS is the oriented surface element. This theorem is essentially the higher dimensional equivalent of integration by parts with ψ and the gradient of φ replacing u and v.
Note that Green's first identity above is a special case of the more general identity derived from the divergence theorem by substituting F = ψΓ:
Green's second identity
If φ and ψ are both twice continuously differentiable on U ⊂ R3, and ε is once continuously differentiable, we can choose F = ψε∇φ − φε∇ψ and obtain:
For the special case of ε = 1 all across U ⊂ R3 then:
In the equation above ∂φ/∂n is the directional derivative of φ in the direction of the outward pointing normal n to the surface element dS:
In particular, this demonstrates that the Laplacian is self-adjoint in the L2 inner product for functions vanishing on the boundary.
Green's third identity
For example in R3, a solution has the form:
Green's third identity states that if ψ is a function that is twice continuously differentiable on U, then
This form is used to construct solutions to Dirichlet boundary condition problems. To find solutions for Neumann boundary condition problems, the Green's function with vanishing normal gradient on the boundary is used instead.
It can be further verified that the above identity also applies when ψ is a solution to the Helmholtz equation or wave equation and G is the appropriate Green's function. In such a context, this identity is the mathematical expression of the Huygens Principle.
Green's identities hold on a Riemannian manifold, In this setting, the first two are
where u and v are smooth real-valued functions on M, dV is the volume form compatible with the metric, is the induced volume form on the boundary of M, N is oriented unit vector field normal to the boundary, and ∇2u = div(grad u) is the Laplacian.
Green's vector identity
Green’s second identity establishes a relationship between second and (the divergence of) first order derivatives of two scalar functions. In differential form
where pm and qm are two arbitrary twice continuously differentiable scalar fields. This identity is of great importance in physics because continuity equations can thus be established for scalar fields such as mass or energy. Although the second Green’s identity is always presented in vector analysis, only a scalar version is found on textbooks. Even in the specialized literature, a vector version is not easily found. In vector diffraction theory, two versions of Green’s second identity are introduced. One variant invokes the divergence of a cross product  and states a relationship in terms of the curl-curl of the field
This equation can be written in terms of the Laplacians:
However, the terms
could not be readily written in terms of a divergence. The other approach introduces bi-vectors, this formulation requires a dyadic Green function. The derivation presented here avoids these problems.
Consider that the scalar fields in Green's second identity are the Cartesian components of vector fields, i.e.
Summing up the equation for each component, we obtain
The LHS according to the definition of the dot product may be written in vector form as
The RHS is a bit more awkward to express in terms of vector operators. Due to the distributivity of the divergence operator over addition, the sum of the divergence is equal to the divergence of the sum, i.e.
Recall the vector identity for the gradient of a dot product
which, written out in vector components is given by
This result is similar to what we wish to evince in vector terms 'except' for the minus sign. Since the differential operators in each term act either over one vector (say ’s) or the other (’s), the contribution to each term must be
These results can be rigorously proven to be correct through evaluation of the vector components. Therefore, the RHS can be written in vector form as
Putting together these two results, a result analogous to Green’s theorem for scalar fields is obtained:
- Theorem for vector fields.
The curl of a cross product can be written as
Green’s vector identity can then be rewritten as
Since the divergence of a curl is zero, the third term vanishes and we obtain:
- Green's vector identity.
With a similar procedure, the Laplacian of the dot product can be expressed in terms of the Laplacians of the factors
As a corollary, the awkward terms can now be written in terms of a divergence by comparison with the vector Green equation
This result can be verified by expanding the divergence of a scalar times a vector on the RHS.
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