Hafnium(IV) carbide
| Hafnium(IV) carbide | |
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| Identifiers | |
| CAS number | 12069-85-1  |
| PubChem | 16212551 |
| ChemSpider | 17340381 |
| Jmol-3D images | Image 1 |
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| Properties | |
| Molecular formula | HfC |
| Molar mass | 190.50 g/mol |
| Appearance | black odorless powder |
| Density | 12.2 g/cm3[1] |
| Melting point |
3900 °C[2] |
| Solubility in water | insoluble |
| Structure | |
| Crystal structure | cubic, cF8 |
| Space group | Fm3m, No. 225 |
| Hazards | |
| EU classification | not listed |
| NFPA 704 |
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 (verify) (what is:  / ?)Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) |
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| Infobox references | |
Hafnium carbide (HfC) is a chemical compound of hafnium and carbon. With a melting point of about 3900 °C it is one of the most refractory binary compounds known.[2] However, it has a low oxidation resistance, with the oxidation starting at temperatures as low as 430 °C.[3]
Hafnium carbide is usually carbon deficient and therefore its composition is often expressed as HfCx (x = 0.5 to 1.0). It has a cubic (rock-salt) crystal structure at any value of x.[4]
Hafnium carbide powder is obtained by the reduction of hafnium(IV) oxide with carbon at 1800 to 2000 °C. A long processing time is required to remove all oxygen. Alternatively, high-purity HfC coatings can be obtained by chemical vapor deposition from a gas mixture of methane, hydrogen, and vaporized hafnium(IV) chloride. Because of the technical complexity and high cost of the synthesis, HfC has a very limited use, despite its favorable properties such as high hardness (>9 Mohs[5]) and melting point.[2]
The magnetic properties of HfCx change from paramagnetic for x ≤ 0.8 to diamagnetic at larger x. An inverse behavior (dia-paramagnetic transition with increasing x) is observed for TaCx, despite its having the same crystal structure as HfCx.[6]
References [edit]
- ^ Physical Constants of Inorganic Compounds in Lide, D. R., ed. (2005). CRC Handbook of Chemistry and Physics (86th ed.). Boca Raton (FL): CRC Press. pp. 4–44 ff. ISBN 0-8493-0486-5.
- ^ a b c Harry Julius Emeléus (1968). Advances in Inorganic Chemistry and Radiochemistry. Academic Press. pp. 169–170. ISBN 978-0-12-023611-4. Retrieved 3 May 2011.
- ^ . doi:10.1111/j.1151-2916.1992.tb05487.x. Missing or empty
|title=(help) - ^ Lavrentyev, A; Gabrelian, B; Vorzhev, V; Nikiforov, I; Khyzhun, O; Rehr, J (2008). "Electronic structure of cubic HfxTa1–xCy carbides from X-ray spectroscopy studies and cluster self-consistent calculations". Journal of Alloys and Compounds 462: 4–10. doi:10.1016/j.jallcom.2007.08.018.
- ^ CRC Materials Science and Engineering Handbook (2001).
- ^ Aleksandr Ivanovich Gusev; Andreĭ Andreevich Rempel; Andreas J. Magerl (2001). Disorder and order in strongly nonstoichiometric compounds: transition metal carbides, nitrides, and oxides. Springer. pp. 513–516. ISBN 978-3-540-41817-7. Retrieved 3 May 2011.
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