Hemispherical combustion chambers, which had been used for centuries in mortars and cannons, were introduced on some of the earliest automotive engines, shortly after proving the concept of internal combustion engines themselves.
Hemispherical cylinder heads have been used since at least 1901; they were used by the Belgian car maker Pipe in 1905 and the 1907 Fiat 130 HP Grand Prix racer. The Peugeot Grand Prix Car of 1912 and the Alfa Romeo Grand Prix car of 1914 both were four valve engines also, Daimler, and Riley were also using hemispherical combustion chambers. Stutz, beginning in 1912, used four-valve engines, conceptually anticipating modern car engines. The BMW double push rod design, taken over by Bristol Cars, the Peugeot 403, the Toyota T engine and Miller racing engines are other examples.
Technology and implementation 
With the hemispherical combustion chamber design, the intake and exhaust valves are on opposite sides of the chamber, sending the combustion mixture flowing directly across the chamber. This design is commonly referred to as a "cross-flow" head. Significant challenges in the commercialization of engines utilizing hemispherical chambers revolved around the design of the valve actuation, and how to make it effective, efficient, and reliable at an acceptable cost. This complexity was referenced early in Chrysler's development of their 1950s hemi engine: the head was referred to in company advertising as the Double Rocker head.
Benefits and drawbacks 
Although a wedge-head design offers simplified valve actuation, it usually does so by placing the valves side by side within the chamber. This can restrict the flow of the air/fuel mixture into and out of the chamber without a compensating design (including designs utilizing overhead cams). With a hemispherical chamber, a straighter flow path is provided for the air/fuel mixture across the chamber. Engineers have learned though, that just passing fuel through a chamber quickly does not provide the best combustion event from an emissions, efficiency, or power perspective.
Drawbacks of the hemispherical chamber include increased production cost, high relative weight (25% heavier than a comparable wedge head per Chrysler's engineers), poor low-rpm performance due to the large port size's turgid flow characteristics, and difficulty meeting emissions standards. These have pushed the hemi head out of favor in the modern era.
Perhaps the most widely known proponent of the hemispherical chamber design is the Chrysler Corporation. Chrysler became identified primarily by trademarking the "Hemi" name and then using it extensively in their advertising campaigns beginning in the 1960s. Chrysler has produced three generations of such engines: the first (the Chrysler FirePower engine) in the 1950s, the second (the 426 Hemi), developed for NASCAR in 1964 and produced through the early 1970s, and finally the "new HEMI" in the early 2000s. The "Hemi" engine introduced in 2002 by DaimlerChrysler had a combustion chamber featuring valve and twin spark plug locations markedly different from the second generation 426ci version. The current-production "Hemi" V8, with its pinched chamber, does not have true hemispherical combustion chambers despite the name; rather, it bears a closer resemblance to the mid-1950s polyspherical chamber, which Chrysler engineers developed as a lower-cost alternative head for their V8 engines. The polyspherical head needed less metal and was narrower due to using only one rocker shaft. This saved costs in material, space, and warranty claims and allowed it to be used in smaller vehicles. Chrysler's Australian-market Hemi-6 of 1970-80 had partial-spherical hemi chambers, though they were only 35% of a sphere.
Ardun heads for the Ford flathead were perhaps the first use of a hemispherical head on a readily available American V8. First offered in 1947 as an aftermarket product, these heads converted the Ford flathead to overhead valves operating in a hemispherical chamber. Zora Arkus-Duntov, who later worked for GM and was a major force behind the development of the Chevrolet Corvette, and his brother Yura, were the "AR" "DUN" of "Ardun."
Ford produced an engine with two overhead cams (one cam per head) and hemispherical chambers in the mid-1960s. The engine, displacing 425 cubic inches and belonging to the FE family of Ford engines, was known as the "427 SOHC"; it was also known as the Cammer. It was basically a set of SOHC hemi heads that bolted onto Ford's FE engine block. The 1964 engine was designed in 90 days of intensive engineering effort for use in racing. The 427 SOHC used the side oiler engine block modified slightly to deal with the missing in-block cam among other OHC issues. Because of their power levels, and the fact that Chrysler had showed Bill France that a DOHC 426 Hemi was in the works, it was banned from NASCAR races, though allowed in certain drag racing classes. After the NASCAR ban, Ford continued to produce the SOHC, selling it over the counter to racers and others who used it to power many altered-wheelbase A/FX Mustangs and supercharged Top Fuel dragsters. Connie Kalitta, Pete Robinson, and "Snake" Prudhomme all used the engine in their Top Fuel racers. In 1967 Connie Kalitta's SOHC-powered "Bounty Hunter" won Top Fuel honors at AHRA, NHRA and NASCAR winter meets, becoming the only "triple crown" winner in drag racing history. Dynamometer results of the day showed the SOHC Hemi producing almost 700 hp (522 kW) in crate form (100 hp per liter). The overhead cams meant that it was not as rpm-limited as the Chrysler Hemis were with their pushrods and heavy and complex valvetrains.
Later Ford engine designs with hemispherical chambers included the Calliope, which used two in-block cams, arranged one over the other, to drive 3 valves per hemispherical chamber. The pushrods activating the valves from the top camshaft were almost horizontal. In 1968, Ford brought out a completely new engine family called the 385-series. This engine's heads used a modified form of the hemispherical chamber called Semi-Hemi.
In the 1970s, Ford designed and produced a small-block engine with hemispherical heads to address the growing concerns about fuel economy. Unfortunately, even with an ahead-of-its-time direct fuel injection system feeding a stratified charge chamber, the hemi's emissions could not be made clean enough for compliance with regulations. This plus the cost of the valve actuation systems, along with the cost of the high pressure pump needed to deliver fuel directly into the chamber, as well as the gilmer belt drive system needed to drive the pump, made further development pointless at the time. Most 1980s 4-cylinder Fords used the Ford CVH engine, CVH meaning "Compound Valve, Hemispherical (Head)". In 2007, taking advantage of the improvements in equipment, computer controls, and chamber design during the intervening years, Ford introduced its non-hemi Ecoboost line of direct-injected engines.
Aston Martin 
Aston Martin's famous DOHC (4 cams) V8 used a hemispherical chamber during the late 1960s through the late 1980s. Each cam controlled one set of valves, either a bank of intake valves or a bank of exhaust valves. The Aston Martin V8 5.3 L (5340 cc/325 in3) produced 315 hp (235 kW).
Alfa Romeo 
Alfa Romeo has produced many successful hemi-head engines throughout the years. Arguably one of their most beloved examples is Giuseppe Busso's original 2.5-liter V6, which has been cited by some as one of the best and most distinctive sounding production engines (even in its latter 24v forms) of all time. Part of this praise is likely because the hemispherical heads on the original 2-valve engine allowed for an almost completely straight exhaust port, resulting in a less diluted or muddied engine sound, allowing Alfa Romeo to use quieter stock exhausts without losing much of their distinct and beloved race-bred engine noise.
Porsche has made extensive use of hemi-head engines, including the air-cooled flat-6 engine in Porsche 911 models from 1963 to 1999. The 1973 2.7 L version generated 56 hp per naturally aspirated litre of piston displacement.
Lotus, along with many many other manufacturers, some of which are listed above, many others which are not, used hemispherical chambers in some of their engines (see photo to right). The relatively large valves possible in such a chamber allowed large volumes of air-fuel mixture to enter and exit the chamber quickly; not always completely combusted. In the modern emissions-era, the hemi chamber has begun to fade away from continuing development. The hemispherical combustion chamber is the simplest, and easiest design to understand. As such, it has served for more than a century as the basic design in combustion engines, from which all other improvements and engineering developments derive. As the engineering involved in new engines has improved and evolved, the true hemispherical chamber has morphed and twisted into more sophisticated and complex designs that are meant to extract more power, with lower emissions, from any given combustion event.
SOHC Cutaway showing cross-flow design,
The hemi engine requires parts
Design evolution in modern engines 
Many of today's engines use active combustion chambers designed to tumble and swirl the fuel/air mix within the chamber for the most efficient combustion event possible. These active chambers usually look like kidney beans or two merged small 'hemi' areas surrounded by flat quenching areas over the pistons. By the end of the 1970s, development of engines utilizing true hemispherical chambers had ceased around the world; it had been gradually displaced by dramatically improved newer engine designs. Today,"hemi" is more of a trademark than a description of a combustion chamber.
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