Ion trap

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This article is about gas phase ions. For ions in cells, see ion trapping.
Ion trap used with a quantum computer.

An ion trap is a combination of electric or magnetic fields used to capture charged particles in a vacuum. Ion traps have a number of scientific uses such as mass spectrometery, basic physics research, and controlling quantum states. The two most common types of ion trap are the Penning trap and the Paul trap (quadrupole ion trap).

Penning traps can be used for precise magnetic measurements in spectroscopy. Studies of quantum state manipulation most often use the Paul trap. This may lead to a trapped ion quantum computer[1] and has already been used to create the world's most accurate atomic clocks.[2] Electron guns (a device emitting high-speed electrons, used in CRTs) can use an ion trap to prevent degradation of the cathode by positive ions.

Ion trap mass spectrometers[edit]

A linear ion trap component of a mass spectrometer.

An ion trap mass spectrometer may incorporate a Penning trap (Fourier transform ion cyclotron resonance),[3] Paul trap[4] or the Kingdon trap.[5] The Orbitrap, introduced in 2005, is based on the Kingdon trap.[6] Other types of mass spectrometers may also use a linear quadrupole ion trap as a selective mass filter.

Penning ion trap[edit]

FTICR mass spectrometer - an example of a Penning trap instrument.

A Penning trap stores charged particles using a strong homogeneous axial magnetic field to confine particles radially and a quadrupole electric field to confine the particles axially.[7] The Penning Trap was named after Frans Michel Penning by Hans Georg Dehmelt who built the first trap.[8] Penning traps are well suited for measurements of the properties of ions and stable charged subatomic particles. Precision studies of the electron magnetic moment by Dehmelt and others are an important topic in modern physics.

Penning traps can be used in quantum computation and quantum information processing[9] and are used at CERN to store antimatter. Penning traps form the basis of Fourier transform ion cyclotron resonance mass spectrometry for determining the mass-to-charge ratio of ions.[10]

Paul ion trap[edit]

Schematic diagram of ion trap mass spectrometer with an electrospray ionization (ESI) source and Paul ion trap.

A Paul trap is a type of quadrupole ion trap that uses static direct current (DC) and radio frequency (RF) oscillating electric fields to trap ions. Paul traps are commonly used as a components of a mass spectrometer. The invention of the 3D quadrupole ion trap itself is attributed to Wolfgang Paul who shared the Nobel Prize in Physics in 1989 for this work.[11][12] The trap consists of two hyperbolic metal electrodes with their foci facing each other and a hyperbolic ring electrode halfway between the other two electrodes. Ions are trapped in the space between these three electrodes by the oscillating and static electric fields.

Kingdon trap and orbitrap[edit]

Partial cross-section of Orbitrap mass analyzer - an example of a Kingdon trap.

A Kingdon trap consists of a thin central wire and an outer cylindrical electrode. A static applied voltage results in a radial logarithmic potential between the electrodes.[13] In a Kingdon trap there is no potential minimum to store the ions; however, they are stored with a finite angular momentum about the central wire and the applied electric field in the device allows for the stability of the ion trajectories.[14] It consists of a thin central wire, an outer cylindrical electrode and isolated end cap electrodes at both ends. A static applied voltage results in a radial logarithmic potential between the electrodes. In 1981, Knight introduced a modified outer electrode that included an axial quadrupole term that confines the ions on the trap axis.[15] The dynamic Kingdon trap has an additional AC voltage that uses strong defocusing to permanently store charged particles.[16] The dynamic Kingdon trap does not require the trapped ions to have angular momentum with respect to the filament. An Orbitrap is a modified Kingdon trap has been used for mass spectrometry. Though the idea has been suggested and computer simulations performed[17] neither the Kingdon nor the Knight configurations were reported to produce mass spectra, as the simulations indicated mass resolving power would be problematic.

Cathode ray tubes[edit]

Main article: Cathode ray tube

Ion traps were used in television receivers prior to the introduction of aluminized CRT faces around 1958, to protect the phosphor screen from ions.[18] The ion trap must be delicately adjusted for maximum brightness.[19][20]

Trapped ion quantum computer[edit]

Quantum computers using trapped ions in a Paul trap have been researched. Units of quantum information called qubits are stored in stable electronic states of each ion, and quantum information can be processed and transferred through the collective quantized motion of the ions, interacting by the Coulomb force. Lasers are applied to induce coupling between the qubit states (for single qubit operations) or between the internal qubit states and external motional states (for entanglement between qubits).

See also[edit]

References[edit]

  1. ^ R. Blatt and D. J. Wineland (2008). "Entangled states of trapped atomic ions". Nature 453 (7198): 1008–1014. Bibcode:2008Natur.453.1008B. doi:10.1038/nature07125. PMID 18563151. 
  2. ^ T. Rosenband, D. B. Hume, P. O. Schmidt, C. W. Chou, A. Brusch, L. Lorini, W. H. Oskay, R. E. Drullinger, T. M. Fortier, J. E. Stalnaker, S. A. Diddams, W. C. Swann, N. R. Newbury, W. M. Itano, D. J. Wineland, and J. C. Bergquist (2008). "Frequency Ratio of Al+ and Hg+ Single-Ion Optical Clocks; Metrology at the 17th Decimal Place". Science 319 (5871): 1808–1812. Bibcode:2008Sci...319.1808R. doi:10.1126/science.1154622. PMID 18323415. 
  3. ^ Blaum, Klaus (2006). "High-accuracy mass spectrometry with stored ions". Physics Reports 425 (1): 1–78. Bibcode:2006PhR...425....1B. doi:10.1016/j.physrep.2005.10.011. 
  4. ^ Douglas, D.J.; Frank, AJ; Mao, DM (2005). "Linear ion traps in mass spectrometry". Mass Spectrometry Reviews 24 (1): 1–29. doi:10.1002/mas.20004. PMID 15389865. 
  5. ^ Kingdon KH (1923). "A Method for the Neutralization of Electron Space Charge by Positive Ionization at Very Low Gas Pressures". Physical Review 21 (4): 408–418. Bibcode:1923PhRv...21..408K. doi:10.1103/PhysRev.21.408. 
  6. ^ Hu, QZ; Noll, RJ; Li, HY; Makarov, A; Hardman, M; Cooks, RG (2005). "The Orbitrap: a new mass spectrometer". Journal of Mass Spectrometry 40 (4): 430–443. doi:10.1002/jms.856. PMID 15838939. 
  7. ^ Brown, L.S.; Gabrielse, G. (1986). "Geonium theory: Physics of a single electron or ion in a Penning trap". Reviews of Modern Physics 58: 233. Bibcode:1986RvMP...58..233B. doi:10.1103/RevModPhys.58.233. 
  8. ^ "Hans G. Dehmelt - Biographical". Nobel Prize. 1989. Retrieved June 1, 2014. 
  9. ^ Häffner, Hartmut, Christian F. Roos, and Rainer Blatt. "Quantum computing with trapped ions." Physics Reports 469.4 (2008): 155-203.
  10. ^ Marshall, A. G.; Hendrickson, C. L.; Jackson, G. S., Fourier transform ion cyclotron resonance mass spectrometry: a primer. Mass Spectrom Rev 17, 1-35.
  11. ^ Paul W., Steinwedel H. (1953). "Ein neues Massenspektrometer ohne Magnetfeld". RZeitschrift für Naturforschung A 8 (7): 448-450
  12. ^ DE 944900  "Verfahren zur Trennung bzw. zum getrennten Nachweis von Ionen verschiedener spezifischer Ladung", W. Paul and H. Steinwedel, filed on December 24, 1953, priority December 23, 1953
  13. ^ Kingdon KH (1923). "A Method for the Neutralization of Electron Space Charge by Positive Ionization at Very Low Gas Pressures" (subscription required). Physical Review 21 (4): 408. Bibcode:1923PhRv...21..408K. doi:10.1103/PhysRev.21.408. 
  14. ^ Major, Fouad G (2005). Charged particle traps: physics and techniques of charged particle field. Springer. ISBN 3-540-22043-7. 
  15. ^ Knight, R. D. (1981). "Storage of ions from laser-produced plasmas". Applied Physics Letters 38 (4): 221–223. Bibcode:1981ApPhL..38..221K. doi:10.1063/1.92315. 
  16. ^ Blümel, R (1995). "Dynamic Kingdon trap". Physical Review A 51 (1): R30–R33. Bibcode:1995PhRvA..51...30B. doi:10.1103/PhysRevA.51.R30. PMID 9911663. 
  17. ^ Oksman, Pentti (1995-01-10). "A Fourier transform time-of-flight mass spectrometer. A SIMION calculation approach". International Journal of Mass Spectrometry and Ion Processes 141 (1): 67–76. Bibcode:1995IJMSI.141...67O. doi:10.1016/0168-1176(94)04086-M. 
  18. ^ Hartson, Ted (2004). "How the World Changed Television". Retrieved 2008-10-13. 
  19. ^ Magnet for cathode-ray tube ion traps
  20. ^ Ion Trap for a Cathode Ray Tube

External links[edit]